METHOD FOR PREPARING METAL HESPERIDIN AND HESPERITIN COMPLEXES, METAL COMPLEXES AND INSECTICIDE COMPOSITIONS FOR CONTROLLING INSECT PESTS IN CITIES, AGRICULTURE AND SILVICULTURE
A method is described for preparing metal hesperidin and hesperitin complexes, which comprises the steps of providing the [Mn(L'- L')m] complexes, in which "n" and "m" are 1 or 2, M comprises a metal selected from Ru(ll), Mg(ll), Co(ll/lll), Cu(ll/lll), Mn(ll/lll), Fe(l...
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| creator | BUENO, ODAIR CORRÊA RAMIRES, EDUARDO NOVAES SILVA, MARIA FÁTIMA DAS GRAÇAS FERNANDES DA FORIM, MOACIR ROSSI PAGNOCCA, FERNANDO CARLOS TEREZAN, ANA PAULA FERNANDES, JOÃO BATISTA CARLOS, ROSE MARIA OLIVEIRA, REGINA MARIA MENDES MATOS, ANDRÉIA PEREIRA VIEIRA, PAULO CESAR SILVA, MARIO ANTONIO NAVARRO DA SOUZA, LÍGIA MORAES BARIZON DE NEBO, LILIANE MARQUES, FRANCISCO DE ASSIS CORREA, ARLENE GONÇALVES SARRIA, ANDRÉ LÚCIO FRANCESCHINI ANNIES, VINICIUS |
| description | A method is described for preparing metal hesperidin and hesperitin complexes, which comprises the steps of providing the [Mn(L'- L')m] complexes, in which "n" and "m" are 1 or 2, M comprises a metal selected from Ru(ll), Mg(ll), Co(ll/lll), Cu(ll/lll), Mn(ll/lll), Fe(ll/lll), Zn(ll) and Ca(ll), and (L'-L') is a polypyridine binder, providing a flavanone (L) selected from deprotonated hesperidin and hesperitin; combining the [Mn(L'-L')m] complex with the deprotonated flavanone in reaction conditions suitable for producing the [Mn(L)k(L'-L')m]2+ metal complexes, where "k" is 1 or 2, precipitating the addition complexes of compounds selected from NH4PF6, Na(CH3COO) and NaCl, separating and washing, producing the [Mn(L)k(L'-L')m](PF6)x, [Mn(L)k(L'-L')m][AcO]- and [Mn(L)k(L'-L')m] (Cl)x metal complexes. Also described are the thus produced complexes and the insecticide compositions based on the metal complexes of the invention.
L'invention concerne un procédé de préparation de complexes métalliques d'hespéridine et d'hespéritine, consistant à utiliser les complexes [Mn(L'- L')m], où "n" et "m" sont 1 ou 2, M comprend un métal choisi parmi Ru(ll), Mg(ll), Co(ll/lll), Cu(ll/lll), Mn(ll/lll), Fe(ll/lll), Zn(ll) et Ca(ll) et (L'-L') est un ligand polypyridinique, à utiliser une flavanone (L) choisie parmi l'hespéridine et l'hespéritine déprotonée, à combiner le complexe [Mn(L'-L')m] et la flavanone déprotonée dans des conditions réactionnelles pour obtenir les complexes à métaux [Mn(L)k(L'-L')m]2+, où "k" est 1 ou 2, à précipiter les complexes par addition de composés choisis parmi NH4PF6, Na(CH3COO) et Na Cl, à réaliser une séparation et un lavage, de manière à obtenir les complexes métalliques [Mn(L)k(L'-L')m](PF6)x, [Mn(L)k(L'-L')m][AcO]- et [Mn(L)k(L'-L')m] (Cl)x. L'invention concerne également les complexes obtenus et les compositions insecticides à base des complexes métalliques de l'invention.
É descrito um processo de preparação de complexos metálicos de hesperidina e hesperitina, que compreende prover os complexos [Mn(L'- L')m], onde "n" e "m" são 1 ou 2, M compreende um metal selecionado dentre Ru(ll), Mg(ll), Co(ll/lll), Cu(ll/lll), Mn(ll/lll), Fe(ll/lll), Zn(ll) e Ca(ll) e (L'-L') é um ligante polipiridínico, prover uma flavanona (L) selecionada dentre hesperidina e hesperitina desprotonada; combinar o complexo [Mn(L'-L')m] e a flavanona desprotonada sob condições reacionais para obter os complexos a metais [Mn(L)k(L'-L')m]2+, onde "k" é 1 ou 2, precip |
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| fullrecord | <record><control><sourceid>epo_EVB</sourceid><recordid>TN_cdi_epo_espacenet_WO2015089596A1</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>WO2015089596A1</sourcerecordid><originalsourceid>FETCH-epo_espacenet_WO2015089596A13</originalsourceid><addsrcrecordid>eNqNjbEKwjAYhLs4iPoOAVeFVqnYMSR_20CahCRVt1IkTqKF-mK-oWlsnZ1-7u777-bRuwJbSopyqZHSoLBmokDexByVYBRoRplAWNBJWi-JrBSHC5jNiP6MQDJhgFhGGIWQSOO_pDBhhUhhteR82PmCSIGxBg29nhtKcaEZqbmtNYRCw_hpMpbR7Nbee7ca7yJa52BJuXXds3F9117dw72as9zFSRofszQ74GT_H_UBqt5LKw</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>patent</recordtype></control><display><type>patent</type><title>METHOD FOR PREPARING METAL HESPERIDIN AND HESPERITIN COMPLEXES, METAL COMPLEXES AND INSECTICIDE COMPOSITIONS FOR CONTROLLING INSECT PESTS IN CITIES, AGRICULTURE AND SILVICULTURE</title><source>esp@cenet</source><creator>BUENO, ODAIR CORRÊA ; RAMIRES, EDUARDO NOVAES ; SILVA, MARIA FÁTIMA DAS GRAÇAS FERNANDES DA ; FORIM, MOACIR ROSSI ; PAGNOCCA, FERNANDO CARLOS ; TEREZAN, ANA PAULA ; FERNANDES, JOÃO BATISTA ; CARLOS, ROSE MARIA ; OLIVEIRA, REGINA MARIA MENDES ; MATOS, ANDRÉIA PEREIRA ; VIEIRA, PAULO CESAR ; SILVA, MARIO ANTONIO NAVARRO DA ; SOUZA, LÍGIA MORAES BARIZON DE ; NEBO, LILIANE ; MARQUES, FRANCISCO DE ASSIS ; CORREA, ARLENE GONÇALVES ; SARRIA, ANDRÉ LÚCIO FRANCESCHINI ; ANNIES, VINICIUS</creator><creatorcontrib>BUENO, ODAIR CORRÊA ; RAMIRES, EDUARDO NOVAES ; SILVA, MARIA FÁTIMA DAS GRAÇAS FERNANDES DA ; FORIM, MOACIR ROSSI ; PAGNOCCA, FERNANDO CARLOS ; TEREZAN, ANA PAULA ; FERNANDES, JOÃO BATISTA ; CARLOS, ROSE MARIA ; OLIVEIRA, REGINA MARIA MENDES ; MATOS, ANDRÉIA PEREIRA ; VIEIRA, PAULO CESAR ; SILVA, MARIO ANTONIO NAVARRO DA ; SOUZA, LÍGIA MORAES BARIZON DE ; NEBO, LILIANE ; MARQUES, FRANCISCO DE ASSIS ; CORREA, ARLENE GONÇALVES ; SARRIA, ANDRÉ LÚCIO FRANCESCHINI ; ANNIES, VINICIUS</creatorcontrib><description>A method is described for preparing metal hesperidin and hesperitin complexes, which comprises the steps of providing the [Mn(L'- L')m] complexes, in which "n" and "m" are 1 or 2, M comprises a metal selected from Ru(ll), Mg(ll), Co(ll/lll), Cu(ll/lll), Mn(ll/lll), Fe(ll/lll), Zn(ll) and Ca(ll), and (L'-L') is a polypyridine binder, providing a flavanone (L) selected from deprotonated hesperidin and hesperitin; combining the [Mn(L'-L')m] complex with the deprotonated flavanone in reaction conditions suitable for producing the [Mn(L)k(L'-L')m]2+ metal complexes, where "k" is 1 or 2, precipitating the addition complexes of compounds selected from NH4PF6, Na(CH3COO) and NaCl, separating and washing, producing the [Mn(L)k(L'-L')m](PF6)x, [Mn(L)k(L'-L')m][AcO]- and [Mn(L)k(L'-L')m] (Cl)x metal complexes. Also described are the thus produced complexes and the insecticide compositions based on the metal complexes of the invention.
L'invention concerne un procédé de préparation de complexes métalliques d'hespéridine et d'hespéritine, consistant à utiliser les complexes [Mn(L'- L')m], où "n" et "m" sont 1 ou 2, M comprend un métal choisi parmi Ru(ll), Mg(ll), Co(ll/lll), Cu(ll/lll), Mn(ll/lll), Fe(ll/lll), Zn(ll) et Ca(ll) et (L'-L') est un ligand polypyridinique, à utiliser une flavanone (L) choisie parmi l'hespéridine et l'hespéritine déprotonée, à combiner le complexe [Mn(L'-L')m] et la flavanone déprotonée dans des conditions réactionnelles pour obtenir les complexes à métaux [Mn(L)k(L'-L')m]2+, où "k" est 1 ou 2, à précipiter les complexes par addition de composés choisis parmi NH4PF6, Na(CH3COO) et Na Cl, à réaliser une séparation et un lavage, de manière à obtenir les complexes métalliques [Mn(L)k(L'-L')m](PF6)x, [Mn(L)k(L'-L')m][AcO]- et [Mn(L)k(L'-L')m] (Cl)x. L'invention concerne également les complexes obtenus et les compositions insecticides à base des complexes métalliques de l'invention.
É descrito um processo de preparação de complexos metálicos de hesperidina e hesperitina, que compreende prover os complexos [Mn(L'- L')m], onde "n" e "m" são 1 ou 2, M compreende um metal selecionado dentre Ru(ll), Mg(ll), Co(ll/lll), Cu(ll/lll), Mn(ll/lll), Fe(ll/lll), Zn(ll) e Ca(ll) e (L'-L') é um ligante polipiridínico, prover uma flavanona (L) selecionada dentre hesperidina e hesperitina desprotonada; combinar o complexo [Mn(L'-L')m] e a flavanona desprotonada sob condições reacionais para obter os complexos a metais [Mn(L)k(L'-L')m]2+, onde "k" é 1 ou 2, precipitar os complexos por adição de compostos selecionados dentre NH4PF6, Na(CH3COO) e NaCI, separar e lavar, obtendo os complexos metálicos [Mn(L)k(L'-L')m](PF6)x, [Mn(L)k(L'-L')m][AcO]- e [Mn(L)k(L'-L')m] (Cl)x. São também descritos os complexos obtidos e as composições inseticidas à base dos complexos metálicos da invenção.</description><language>eng ; fre ; por</language><subject>AGRICULTURE ; ANIMAL HUSBANDRY ; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES, AS HERBICIDES ; FISHING ; FORESTRY ; HUMAN NECESSITIES ; HUNTING ; PEST REPELLANTS OR ATTRACTANTS ; PLANT GROWTH REGULATORS ; PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTSTHEREOF ; TRAPPING</subject><creationdate>2015</creationdate><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=20150625&DB=EPODOC&CC=WO&NR=2015089596A1$$EHTML$$P50$$Gepo$$Hfree_for_read</linktohtml><link.rule.ids>230,308,776,881,25542,76290</link.rule.ids><linktorsrc>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=20150625&DB=EPODOC&CC=WO&NR=2015089596A1$$EView_record_in_European_Patent_Office$$FView_record_in_$$GEuropean_Patent_Office$$Hfree_for_read</linktorsrc></links><search><creatorcontrib>BUENO, ODAIR CORRÊA</creatorcontrib><creatorcontrib>RAMIRES, EDUARDO NOVAES</creatorcontrib><creatorcontrib>SILVA, MARIA FÁTIMA DAS GRAÇAS FERNANDES DA</creatorcontrib><creatorcontrib>FORIM, MOACIR ROSSI</creatorcontrib><creatorcontrib>PAGNOCCA, FERNANDO CARLOS</creatorcontrib><creatorcontrib>TEREZAN, ANA PAULA</creatorcontrib><creatorcontrib>FERNANDES, JOÃO BATISTA</creatorcontrib><creatorcontrib>CARLOS, ROSE MARIA</creatorcontrib><creatorcontrib>OLIVEIRA, REGINA MARIA MENDES</creatorcontrib><creatorcontrib>MATOS, ANDRÉIA PEREIRA</creatorcontrib><creatorcontrib>VIEIRA, PAULO CESAR</creatorcontrib><creatorcontrib>SILVA, MARIO ANTONIO NAVARRO DA</creatorcontrib><creatorcontrib>SOUZA, LÍGIA MORAES BARIZON DE</creatorcontrib><creatorcontrib>NEBO, LILIANE</creatorcontrib><creatorcontrib>MARQUES, FRANCISCO DE ASSIS</creatorcontrib><creatorcontrib>CORREA, ARLENE GONÇALVES</creatorcontrib><creatorcontrib>SARRIA, ANDRÉ LÚCIO FRANCESCHINI</creatorcontrib><creatorcontrib>ANNIES, VINICIUS</creatorcontrib><title>METHOD FOR PREPARING METAL HESPERIDIN AND HESPERITIN COMPLEXES, METAL COMPLEXES AND INSECTICIDE COMPOSITIONS FOR CONTROLLING INSECT PESTS IN CITIES, AGRICULTURE AND SILVICULTURE</title><description>A method is described for preparing metal hesperidin and hesperitin complexes, which comprises the steps of providing the [Mn(L'- L')m] complexes, in which "n" and "m" are 1 or 2, M comprises a metal selected from Ru(ll), Mg(ll), Co(ll/lll), Cu(ll/lll), Mn(ll/lll), Fe(ll/lll), Zn(ll) and Ca(ll), and (L'-L') is a polypyridine binder, providing a flavanone (L) selected from deprotonated hesperidin and hesperitin; combining the [Mn(L'-L')m] complex with the deprotonated flavanone in reaction conditions suitable for producing the [Mn(L)k(L'-L')m]2+ metal complexes, where "k" is 1 or 2, precipitating the addition complexes of compounds selected from NH4PF6, Na(CH3COO) and NaCl, separating and washing, producing the [Mn(L)k(L'-L')m](PF6)x, [Mn(L)k(L'-L')m][AcO]- and [Mn(L)k(L'-L')m] (Cl)x metal complexes. Also described are the thus produced complexes and the insecticide compositions based on the metal complexes of the invention.
L'invention concerne un procédé de préparation de complexes métalliques d'hespéridine et d'hespéritine, consistant à utiliser les complexes [Mn(L'- L')m], où "n" et "m" sont 1 ou 2, M comprend un métal choisi parmi Ru(ll), Mg(ll), Co(ll/lll), Cu(ll/lll), Mn(ll/lll), Fe(ll/lll), Zn(ll) et Ca(ll) et (L'-L') est un ligand polypyridinique, à utiliser une flavanone (L) choisie parmi l'hespéridine et l'hespéritine déprotonée, à combiner le complexe [Mn(L'-L')m] et la flavanone déprotonée dans des conditions réactionnelles pour obtenir les complexes à métaux [Mn(L)k(L'-L')m]2+, où "k" est 1 ou 2, à précipiter les complexes par addition de composés choisis parmi NH4PF6, Na(CH3COO) et Na Cl, à réaliser une séparation et un lavage, de manière à obtenir les complexes métalliques [Mn(L)k(L'-L')m](PF6)x, [Mn(L)k(L'-L')m][AcO]- et [Mn(L)k(L'-L')m] (Cl)x. L'invention concerne également les complexes obtenus et les compositions insecticides à base des complexes métalliques de l'invention.
É descrito um processo de preparação de complexos metálicos de hesperidina e hesperitina, que compreende prover os complexos [Mn(L'- L')m], onde "n" e "m" são 1 ou 2, M compreende um metal selecionado dentre Ru(ll), Mg(ll), Co(ll/lll), Cu(ll/lll), Mn(ll/lll), Fe(ll/lll), Zn(ll) e Ca(ll) e (L'-L') é um ligante polipiridínico, prover uma flavanona (L) selecionada dentre hesperidina e hesperitina desprotonada; combinar o complexo [Mn(L'-L')m] e a flavanona desprotonada sob condições reacionais para obter os complexos a metais [Mn(L)k(L'-L')m]2+, onde "k" é 1 ou 2, precipitar os complexos por adição de compostos selecionados dentre NH4PF6, Na(CH3COO) e NaCI, separar e lavar, obtendo os complexos metálicos [Mn(L)k(L'-L')m](PF6)x, [Mn(L)k(L'-L')m][AcO]- e [Mn(L)k(L'-L')m] (Cl)x. São também descritos os complexos obtidos e as composições inseticidas à base dos complexos metálicos da invenção.</description><subject>AGRICULTURE</subject><subject>ANIMAL HUSBANDRY</subject><subject>BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES, AS HERBICIDES</subject><subject>FISHING</subject><subject>FORESTRY</subject><subject>HUMAN NECESSITIES</subject><subject>HUNTING</subject><subject>PEST REPELLANTS OR ATTRACTANTS</subject><subject>PLANT GROWTH REGULATORS</subject><subject>PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTSTHEREOF</subject><subject>TRAPPING</subject><fulltext>true</fulltext><rsrctype>patent</rsrctype><creationdate>2015</creationdate><recordtype>patent</recordtype><sourceid>EVB</sourceid><recordid>eNqNjbEKwjAYhLs4iPoOAVeFVqnYMSR_20CahCRVt1IkTqKF-mK-oWlsnZ1-7u777-bRuwJbSopyqZHSoLBmokDexByVYBRoRplAWNBJWi-JrBSHC5jNiP6MQDJhgFhGGIWQSOO_pDBhhUhhteR82PmCSIGxBg29nhtKcaEZqbmtNYRCw_hpMpbR7Nbee7ca7yJa52BJuXXds3F9117dw72as9zFSRofszQ74GT_H_UBqt5LKw</recordid><startdate>20150625</startdate><enddate>20150625</enddate><creator>BUENO, ODAIR CORRÊA</creator><creator>RAMIRES, EDUARDO NOVAES</creator><creator>SILVA, MARIA FÁTIMA DAS GRAÇAS FERNANDES DA</creator><creator>FORIM, MOACIR ROSSI</creator><creator>PAGNOCCA, FERNANDO CARLOS</creator><creator>TEREZAN, ANA PAULA</creator><creator>FERNANDES, JOÃO BATISTA</creator><creator>CARLOS, ROSE MARIA</creator><creator>OLIVEIRA, REGINA MARIA MENDES</creator><creator>MATOS, ANDRÉIA PEREIRA</creator><creator>VIEIRA, PAULO CESAR</creator><creator>SILVA, MARIO ANTONIO NAVARRO DA</creator><creator>SOUZA, LÍGIA MORAES BARIZON DE</creator><creator>NEBO, LILIANE</creator><creator>MARQUES, FRANCISCO DE ASSIS</creator><creator>CORREA, ARLENE GONÇALVES</creator><creator>SARRIA, ANDRÉ LÚCIO FRANCESCHINI</creator><creator>ANNIES, VINICIUS</creator><scope>EVB</scope></search><sort><creationdate>20150625</creationdate><title>METHOD FOR PREPARING METAL HESPERIDIN AND HESPERITIN COMPLEXES, METAL COMPLEXES AND INSECTICIDE COMPOSITIONS FOR CONTROLLING INSECT PESTS IN CITIES, AGRICULTURE AND SILVICULTURE</title><author>BUENO, ODAIR CORRÊA ; RAMIRES, EDUARDO NOVAES ; SILVA, MARIA FÁTIMA DAS GRAÇAS FERNANDES DA ; FORIM, MOACIR ROSSI ; PAGNOCCA, FERNANDO CARLOS ; TEREZAN, ANA PAULA ; FERNANDES, JOÃO BATISTA ; CARLOS, ROSE MARIA ; OLIVEIRA, REGINA MARIA MENDES ; MATOS, ANDRÉIA PEREIRA ; VIEIRA, PAULO CESAR ; SILVA, MARIO ANTONIO NAVARRO DA ; SOUZA, LÍGIA MORAES BARIZON DE ; NEBO, LILIANE ; MARQUES, FRANCISCO DE ASSIS ; CORREA, ARLENE GONÇALVES ; SARRIA, ANDRÉ LÚCIO FRANCESCHINI ; ANNIES, VINICIUS</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-epo_espacenet_WO2015089596A13</frbrgroupid><rsrctype>patents</rsrctype><prefilter>patents</prefilter><language>eng ; fre ; por</language><creationdate>2015</creationdate><topic>AGRICULTURE</topic><topic>ANIMAL HUSBANDRY</topic><topic>BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES, AS HERBICIDES</topic><topic>FISHING</topic><topic>FORESTRY</topic><topic>HUMAN NECESSITIES</topic><topic>HUNTING</topic><topic>PEST REPELLANTS OR ATTRACTANTS</topic><topic>PLANT GROWTH REGULATORS</topic><topic>PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTSTHEREOF</topic><topic>TRAPPING</topic><toplevel>online_resources</toplevel><creatorcontrib>BUENO, ODAIR CORRÊA</creatorcontrib><creatorcontrib>RAMIRES, EDUARDO NOVAES</creatorcontrib><creatorcontrib>SILVA, MARIA FÁTIMA DAS GRAÇAS FERNANDES DA</creatorcontrib><creatorcontrib>FORIM, MOACIR ROSSI</creatorcontrib><creatorcontrib>PAGNOCCA, FERNANDO CARLOS</creatorcontrib><creatorcontrib>TEREZAN, ANA PAULA</creatorcontrib><creatorcontrib>FERNANDES, JOÃO BATISTA</creatorcontrib><creatorcontrib>CARLOS, ROSE MARIA</creatorcontrib><creatorcontrib>OLIVEIRA, REGINA MARIA MENDES</creatorcontrib><creatorcontrib>MATOS, ANDRÉIA PEREIRA</creatorcontrib><creatorcontrib>VIEIRA, PAULO CESAR</creatorcontrib><creatorcontrib>SILVA, MARIO ANTONIO NAVARRO DA</creatorcontrib><creatorcontrib>SOUZA, LÍGIA MORAES BARIZON DE</creatorcontrib><creatorcontrib>NEBO, LILIANE</creatorcontrib><creatorcontrib>MARQUES, FRANCISCO DE ASSIS</creatorcontrib><creatorcontrib>CORREA, ARLENE GONÇALVES</creatorcontrib><creatorcontrib>SARRIA, ANDRÉ LÚCIO FRANCESCHINI</creatorcontrib><creatorcontrib>ANNIES, VINICIUS</creatorcontrib><collection>esp@cenet</collection></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext_linktorsrc</fulltext></delivery><addata><au>BUENO, ODAIR CORRÊA</au><au>RAMIRES, EDUARDO NOVAES</au><au>SILVA, MARIA FÁTIMA DAS GRAÇAS FERNANDES DA</au><au>FORIM, MOACIR ROSSI</au><au>PAGNOCCA, FERNANDO CARLOS</au><au>TEREZAN, ANA PAULA</au><au>FERNANDES, JOÃO BATISTA</au><au>CARLOS, ROSE MARIA</au><au>OLIVEIRA, REGINA MARIA MENDES</au><au>MATOS, ANDRÉIA PEREIRA</au><au>VIEIRA, PAULO CESAR</au><au>SILVA, MARIO ANTONIO NAVARRO DA</au><au>SOUZA, LÍGIA MORAES BARIZON DE</au><au>NEBO, LILIANE</au><au>MARQUES, FRANCISCO DE ASSIS</au><au>CORREA, ARLENE GONÇALVES</au><au>SARRIA, ANDRÉ LÚCIO FRANCESCHINI</au><au>ANNIES, VINICIUS</au><format>patent</format><genre>patent</genre><ristype>GEN</ristype><title>METHOD FOR PREPARING METAL HESPERIDIN AND HESPERITIN COMPLEXES, METAL COMPLEXES AND INSECTICIDE COMPOSITIONS FOR CONTROLLING INSECT PESTS IN CITIES, AGRICULTURE AND SILVICULTURE</title><date>2015-06-25</date><risdate>2015</risdate><abstract>A method is described for preparing metal hesperidin and hesperitin complexes, which comprises the steps of providing the [Mn(L'- L')m] complexes, in which "n" and "m" are 1 or 2, M comprises a metal selected from Ru(ll), Mg(ll), Co(ll/lll), Cu(ll/lll), Mn(ll/lll), Fe(ll/lll), Zn(ll) and Ca(ll), and (L'-L') is a polypyridine binder, providing a flavanone (L) selected from deprotonated hesperidin and hesperitin; combining the [Mn(L'-L')m] complex with the deprotonated flavanone in reaction conditions suitable for producing the [Mn(L)k(L'-L')m]2+ metal complexes, where "k" is 1 or 2, precipitating the addition complexes of compounds selected from NH4PF6, Na(CH3COO) and NaCl, separating and washing, producing the [Mn(L)k(L'-L')m](PF6)x, [Mn(L)k(L'-L')m][AcO]- and [Mn(L)k(L'-L')m] (Cl)x metal complexes. Also described are the thus produced complexes and the insecticide compositions based on the metal complexes of the invention.
L'invention concerne un procédé de préparation de complexes métalliques d'hespéridine et d'hespéritine, consistant à utiliser les complexes [Mn(L'- L')m], où "n" et "m" sont 1 ou 2, M comprend un métal choisi parmi Ru(ll), Mg(ll), Co(ll/lll), Cu(ll/lll), Mn(ll/lll), Fe(ll/lll), Zn(ll) et Ca(ll) et (L'-L') est un ligand polypyridinique, à utiliser une flavanone (L) choisie parmi l'hespéridine et l'hespéritine déprotonée, à combiner le complexe [Mn(L'-L')m] et la flavanone déprotonée dans des conditions réactionnelles pour obtenir les complexes à métaux [Mn(L)k(L'-L')m]2+, où "k" est 1 ou 2, à précipiter les complexes par addition de composés choisis parmi NH4PF6, Na(CH3COO) et Na Cl, à réaliser une séparation et un lavage, de manière à obtenir les complexes métalliques [Mn(L)k(L'-L')m](PF6)x, [Mn(L)k(L'-L')m][AcO]- et [Mn(L)k(L'-L')m] (Cl)x. L'invention concerne également les complexes obtenus et les compositions insecticides à base des complexes métalliques de l'invention.
É descrito um processo de preparação de complexos metálicos de hesperidina e hesperitina, que compreende prover os complexos [Mn(L'- L')m], onde "n" e "m" são 1 ou 2, M compreende um metal selecionado dentre Ru(ll), Mg(ll), Co(ll/lll), Cu(ll/lll), Mn(ll/lll), Fe(ll/lll), Zn(ll) e Ca(ll) e (L'-L') é um ligante polipiridínico, prover uma flavanona (L) selecionada dentre hesperidina e hesperitina desprotonada; combinar o complexo [Mn(L'-L')m] e a flavanona desprotonada sob condições reacionais para obter os complexos a metais [Mn(L)k(L'-L')m]2+, onde "k" é 1 ou 2, precipitar os complexos por adição de compostos selecionados dentre NH4PF6, Na(CH3COO) e NaCI, separar e lavar, obtendo os complexos metálicos [Mn(L)k(L'-L')m](PF6)x, [Mn(L)k(L'-L')m][AcO]- e [Mn(L)k(L'-L')m] (Cl)x. São também descritos os complexos obtidos e as composições inseticidas à base dos complexos metálicos da invenção.</abstract><oa>free_for_read</oa></addata></record> |
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| language | eng ; fre ; por |
| recordid | cdi_epo_espacenet_WO2015089596A1 |
| source | esp@cenet |
| subjects | AGRICULTURE ANIMAL HUSBANDRY BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES, AS HERBICIDES FISHING FORESTRY HUMAN NECESSITIES HUNTING PEST REPELLANTS OR ATTRACTANTS PLANT GROWTH REGULATORS PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTSTHEREOF TRAPPING |
| title | METHOD FOR PREPARING METAL HESPERIDIN AND HESPERITIN COMPLEXES, METAL COMPLEXES AND INSECTICIDE COMPOSITIONS FOR CONTROLLING INSECT PESTS IN CITIES, AGRICULTURE AND SILVICULTURE |
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