SULFOXIDATION CATALYSTS AND METHODS AND SYSTEMS OF USING SAME

Catalysts amenable to oxidizing sulfur compounds and systems and methods of using these catalysts to effect the removal of sulfur from crude oil and crude oil distillates are disclosed. The catalyst is disposed with a titanyl moiety which serves to selectively coordinate sulfur compounds and affect...

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Hauptverfasser: JORDAN, TRACEY, M, VREELAND, JENNIFER, L, LITZ, KYLE, E, ROSSETTI, MARK, N, LOUGHRAN, ANTHONY, J
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VREELAND, JENNIFER, L
LITZ, KYLE, E
ROSSETTI, MARK, N
LOUGHRAN, ANTHONY, J
description Catalysts amenable to oxidizing sulfur compounds and systems and methods of using these catalysts to effect the removal of sulfur from crude oil and crude oil distillates are disclosed. The catalyst is disposed with a titanyl moiety which serves to selectively coordinate sulfur compounds and affect their oxidation. The titanyl may be bound within a polymer or on the surface of a polymer or on the surface or in the pores of an inorganic support. The resulting oxidized sulfur compounds are readily separated from the initial crude oil or crude oil distillate streams by traditional separation techniques arrayed as described in the systems and methods disclosed. La présente invention concerne des catalyseurs permettant l'oxydation de composés de soufre et des systèmes et des procédés permettant d'utiliser ces catalyseurs pour effectuer l'élimination du soufre du pétrole brut et des distillats de pétrole brut. Le catalyseur est placé avec une fraction de titanyle qui sert à coordonner sélectivement les composés de soufre et à influencer leur oxydation. Le titanyle peut être lié au sein d'un polymère ou à la surface d'un polymère ou à la surface ou dans les pores d'un support inorganique. Les composés de soufre oxydés obtenus sont faciles à séparer du pétrole brut initial ou des flux de distillats de pétrole brut par des techniques de séparation décrites dans les systèmes et procédés présentés.
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subjects CHEMISTRY
CRACKING HYDROCARBON OILS
FUELS
LUBRICANTS
METALLURGY
MINERAL WAXES
PEAT
PETROLEUM, GAS OR COKE INDUSTRIES
PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVEHYDROGENATION, OLIGOMERISATION, POLYMERISATION
RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, ORGASES
REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS
REFORMING OF NAPHTHA
TECHNICAL GASES CONTAINING CARBON MONOXIDE
title SULFOXIDATION CATALYSTS AND METHODS AND SYSTEMS OF USING SAME
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