FLUOROUS TELOMERIC COMPOUNDS AND POLYMERS CONTAINING SAME

Claimed are fluorous telomeric co mpounds of the formula: RF - A - [CH2]cCR2R3 - Z where RF is a perfluoroalkyl radical o f 1 to 20 carbon atoms, A is a group of the formulae (I) or (II). R1 is CF3 OR4, Cl, Br or I, R2 and R3 are H, alkyl or aryl R4 is perfluoromethyl, perfluoropropyl or perfluoropr...

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Hauptverfasser: PROBST, ANTON, GOETZ, HANS, AHOLLINGER, CHRISTIAN, KNAUP, WOLFGANG
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GOETZ, HANS
AHOLLINGER, CHRISTIAN
KNAUP, WOLFGANG
description Claimed are fluorous telomeric co mpounds of the formula: RF - A - [CH2]cCR2R3 - Z where RF is a perfluoroalkyl radical o f 1 to 20 carbon atoms, A is a group of the formulae (I) or (II). R1 is CF3 OR4, Cl, Br or I, R2 and R3 are H, alkyl or aryl R4 is perfluoromethyl, perfluoropropyl or perfluoropropyloxypropyl X and Y are H, Cl or F Z is -OH, -OCOCH=CH2 or -OCOCCH3=CH2 a is fro m 0 to 10, b is fro m 1 to 30 and c is fro m 1 to 30. These co mpounds are copolymerized wit h further mo no mers. The copolymers thus obtained are useful for water-, oil- and soil-repellent finishing of fibrous substrates. L'invention concerne des composés télomères fluorés de formule : RF - A - [CH2]cCR2R3 - Z où RF est un radical perfluoroalkyle de 1 à 20 atomes de carbone, A est un groupe de formule [formule]:; R1 est CF3, OR4, Cl, Br ou I; R2 et R3 sont chacun H, un alkyle ou un aryle; R4 est un groupe perfluorométhyle, perfluoropropyle ou perfluoropropyloxypropyle; X et Y sont chacun H, Cl ou F; Z est -OH, -OCOCH=CH2 ou -OCOCCH3=CH2; a vaut de 0 à 10, b vaut de 1 à 30 et c vaut de 1 à 30. Ces composés sont copolymérisés avec d'autres monomères. Les copolymères ainsi obtenus sont utiles pour la finition hydrofuge, oléofuge et anti-salissures de substrats fibreux.
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R1 is CF3 OR4, Cl, Br or I, R2 and R3 are H, alkyl or aryl R4 is perfluoromethyl, perfluoropropyl or perfluoropropyloxypropyl X and Y are H, Cl or F Z is -OH, -OCOCH=CH2 or -OCOCCH3=CH2 a is fro m 0 to 10, b is fro m 1 to 30 and c is fro m 1 to 30. These co mpounds are copolymerized wit h further mo no mers. The copolymers thus obtained are useful for water-, oil- and soil-repellent finishing of fibrous substrates. L'invention concerne des composés télomères fluorés de formule : RF - A - [CH2]cCR2R3 - Z où RF est un radical perfluoroalkyle de 1 à 20 atomes de carbone, A est un groupe de formule [formule]:; R1 est CF3, OR4, Cl, Br ou I; R2 et R3 sont chacun H, un alkyle ou un aryle; R4 est un groupe perfluorométhyle, perfluoropropyle ou perfluoropropyloxypropyle; X et Y sont chacun H, Cl ou F; Z est -OH, -OCOCH=CH2 ou -OCOCCH3=CH2; a vaut de 0 à 10, b vaut de 1 à 30 et c vaut de 1 à 30. Ces composés sont copolymérisés avec d'autres monomères. Les copolymères ainsi obtenus sont utiles pour la finition hydrofuge, oléofuge et anti-salissures de substrats fibreux.</abstract><oa>free_for_read</oa></addata></record>
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subjects ACYCLIC OR CARBOCYCLIC COMPOUNDS
CHEMISTRY
COMPOSITIONS BASED THEREON
FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
LAUNDERING
MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS
METALLURGY
ORGANIC CHEMISTRY
ORGANIC MACROMOLECULAR COMPOUNDS
TEXTILES
THEIR PREPARATION OR CHEMICAL WORKING-UP
TREATMENT OF TEXTILES OR THE LIKE
TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS,FABRICS, FEATHERS, OR FIBROUS GOODS MADE FROM SUCH MATERIALS
title FLUOROUS TELOMERIC COMPOUNDS AND POLYMERS CONTAINING SAME
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