TRANSITION METAL COMPOUND, LIGAND SYSTEM, CATALYST SYSTEM AND PROCESS FOR PREPARING POLYOLEFINS
The present invention relates to transition metal compounds of the formula (I); where M is an element of group 3, 4, 5, 6, 7, 8, 9 or 10 of the Periodic Table of the Elements or the lanthanide's, the radicals X are identical or different and are each an organic or inorganic radical, with two ra...
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creator | BILDSTEIN, BENNO MIHAN, SHAHRAM SOLCHINGER, ALEXANDER KOELLING, LARS |
description | The present invention relates to transition metal compounds of the formula (I); where M is an element of group 3, 4, 5, 6, 7, 8, 9 or 10 of the Periodic Table of the Elements or the lanthanide's, the radicals X are identical or different and are each an organic or inorganic radical, with two radicals X also being able to be joined to one another to form a divalent radical, is 1 , 2, 3 or 4, L1 is an organic or inorganic uncharged ligand, is an integer from 0 to 4, R1 is an organic radical having from 1 to 40 carbon atoms, R2 is hydrogen or an organic radical having from 1 to 40 carbon atoms, or R1 and R2 together form a divalent organic group T1 which has from 2 to 40 carbon atoms and together with the atoms connecting its ends forms a monocyclic or polycyclic ring system which may in turn be substituted and may comprise one or more further heteroatoms selected from the group consisting of the elements O, S, Se, Te, N, P and As in the ring system, R3 is hydrogen or an organic radical having from 1 to 40 carbon atoms, R4 is hydrogen or an organic radical having from 1 to 40 carbon atoms, or R3 and R4 together form a divalent organic group T2 which has from 2 to 40 carbon atoms and together with the atoms connecting its ends forms a monocyclic or polycyclic ring system which may in turn be substituted and may comprise one or more heteroatoms selected from the group consisting of the elements O, S, Se, Te, N, P and As in the ring system, R5 is an uncharged or negatively charged organic radical which has from 1 to 40 carbon atoms and may comprise a heteroatom selected from the group consisting of the elements N, O, P, S, As and Sb, and m is an integer from 1 to 10, ligand systems having such a substitution pattern, ligand systems comprising at least one of the transition metal compounds according to the invention, a process for preparing polyolefins by polymerization or copolymerization of at least one olefin in the presence of at least one of the catalyst systems according to the invention and the use of the ligand systems according to the invention for preparing transition metal compounds.
La présente invention a trait à des composés à base de métaux de transition de formule (I), dans laquelle: M est un élément de groupe 3, 4, 5, 6, 7, 8, 9 ou 10 du tableau périodique des éléments ou des lanthanides; les radicaux X sont identiques ou différents et représentent chacun un radical organique ou inorganique, deux radicaux X pouvant être mutuellement assemblés pou |
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La présente invention a trait à des composés à base de métaux de transition de formule (I), dans laquelle: M est un élément de groupe 3, 4, 5, 6, 7, 8, 9 ou 10 du tableau périodique des éléments ou des lanthanides; les radicaux X sont identiques ou différents et représentent chacun un radical organique ou inorganique, deux radicaux X pouvant être mutuellement assemblés pour former un radical divalent; n est 1, 2, 3 ou 4; L1 est un ligand organique ou inorganique non chargé; h est un nombre entier de 0 à 4; R1 est un radical organique ayant 1 à 40 atomes de carbone; R2 est hydrogène ou un radical organique ayant 1 à 40 atomes de carbone; ou R1 et R2 ensemble forment un groupe organique divalent T1 qui a 2 à 40 atomes de carbone et ensemble avec les atomes reliant ses extrémités forme un système monocyclique ou polycyclique qui peut à son tour être substitué et peut comporter un ou des hétéroatomes choisis parmi le groupe constitué des éléments O, S, Se, Te, N, P et As dans le système cyclique; R3 est hydrogène ou un radical organique ayant 1 à 40 atomes de carbone; R4 est hydrogène ou un radical organique ayant 1 à 40 atomes de carbone; ou R3 et R4 ensemble forment un groupe organique divalent T2 qui a 2 à 40 atomes de carbone et ensemble avec les atomes reliant ses extrémités forme un système monocyclique ou polycyclique qui peut à son tour être substitué et peut comporter un ou des hétéroatomes choisis parmi le groupe constitué des éléments O, S, Se, Te, N, P et As dans le système cyclique; R5 est un radical organique non chargé ou négativement chargé qui a 1 à 40 atomes de carbone et peut comporter un hétéroatome choisi parmi le groupe constitué des éléments N, O, P, S, As et Sb; et m est un nombre entier de 1 à 10. L'invention a également trait à des systèmes de ligand présentant une configuration de substitution, des systèmes de ligand comportant au moins un des composés à base de métaux de transition selon l'invention, à un procédé pour la préparation de polyoléfines par la polymérisation ou la copolymérisation d'au moins une oléfine en présence d'au moins un des système catalyseurs de l'invention et à l'utilisation des systèmes de ligand de l'invention pour la préparation de composés à base de métaux de transition.</description><language>eng ; fre</language><subject>ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM ; CHEMISTRY ; COMPOSITIONS BASED THEREON ; HETEROCYCLIC COMPOUNDS ; MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS ; METALLURGY ; ORGANIC CHEMISTRY ; ORGANIC MACROMOLECULAR COMPOUNDS ; THEIR PREPARATION OR CHEMICAL WORKING-UP</subject><creationdate>2007</creationdate><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=20070607&DB=EPODOC&CC=WO&NR=2007062790A2$$EHTML$$P50$$Gepo$$Hfree_for_read</linktohtml><link.rule.ids>230,308,780,885,25564,76547</link.rule.ids><linktorsrc>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=20070607&DB=EPODOC&CC=WO&NR=2007062790A2$$EView_record_in_European_Patent_Office$$FView_record_in_$$GEuropean_Patent_Office$$Hfree_for_read</linktorsrc></links><search><creatorcontrib>BILDSTEIN, BENNO</creatorcontrib><creatorcontrib>MIHAN, SHAHRAM</creatorcontrib><creatorcontrib>SOLCHINGER, ALEXANDER</creatorcontrib><creatorcontrib>KOELLING, LARS</creatorcontrib><title>TRANSITION METAL COMPOUND, LIGAND SYSTEM, CATALYST SYSTEM AND PROCESS FOR PREPARING POLYOLEFINS</title><description>The present invention relates to transition metal compounds of the formula (I); where M is an element of group 3, 4, 5, 6, 7, 8, 9 or 10 of the Periodic Table of the Elements or the lanthanide's, the radicals X are identical or different and are each an organic or inorganic radical, with two radicals X also being able to be joined to one another to form a divalent radical, is 1 , 2, 3 or 4, L1 is an organic or inorganic uncharged ligand, is an integer from 0 to 4, R1 is an organic radical having from 1 to 40 carbon atoms, R2 is hydrogen or an organic radical having from 1 to 40 carbon atoms, or R1 and R2 together form a divalent organic group T1 which has from 2 to 40 carbon atoms and together with the atoms connecting its ends forms a monocyclic or polycyclic ring system which may in turn be substituted and may comprise one or more further heteroatoms selected from the group consisting of the elements O, S, Se, Te, N, P and As in the ring system, R3 is hydrogen or an organic radical having from 1 to 40 carbon atoms, R4 is hydrogen or an organic radical having from 1 to 40 carbon atoms, or R3 and R4 together form a divalent organic group T2 which has from 2 to 40 carbon atoms and together with the atoms connecting its ends forms a monocyclic or polycyclic ring system which may in turn be substituted and may comprise one or more heteroatoms selected from the group consisting of the elements O, S, Se, Te, N, P and As in the ring system, R5 is an uncharged or negatively charged organic radical which has from 1 to 40 carbon atoms and may comprise a heteroatom selected from the group consisting of the elements N, O, P, S, As and Sb, and m is an integer from 1 to 10, ligand systems having such a substitution pattern, ligand systems comprising at least one of the transition metal compounds according to the invention, a process for preparing polyolefins by polymerization or copolymerization of at least one olefin in the presence of at least one of the catalyst systems according to the invention and the use of the ligand systems according to the invention for preparing transition metal compounds.
La présente invention a trait à des composés à base de métaux de transition de formule (I), dans laquelle: M est un élément de groupe 3, 4, 5, 6, 7, 8, 9 ou 10 du tableau périodique des éléments ou des lanthanides; les radicaux X sont identiques ou différents et représentent chacun un radical organique ou inorganique, deux radicaux X pouvant être mutuellement assemblés pour former un radical divalent; n est 1, 2, 3 ou 4; L1 est un ligand organique ou inorganique non chargé; h est un nombre entier de 0 à 4; R1 est un radical organique ayant 1 à 40 atomes de carbone; R2 est hydrogène ou un radical organique ayant 1 à 40 atomes de carbone; ou R1 et R2 ensemble forment un groupe organique divalent T1 qui a 2 à 40 atomes de carbone et ensemble avec les atomes reliant ses extrémités forme un système monocyclique ou polycyclique qui peut à son tour être substitué et peut comporter un ou des hétéroatomes choisis parmi le groupe constitué des éléments O, S, Se, Te, N, P et As dans le système cyclique; R3 est hydrogène ou un radical organique ayant 1 à 40 atomes de carbone; R4 est hydrogène ou un radical organique ayant 1 à 40 atomes de carbone; ou R3 et R4 ensemble forment un groupe organique divalent T2 qui a 2 à 40 atomes de carbone et ensemble avec les atomes reliant ses extrémités forme un système monocyclique ou polycyclique qui peut à son tour être substitué et peut comporter un ou des hétéroatomes choisis parmi le groupe constitué des éléments O, S, Se, Te, N, P et As dans le système cyclique; R5 est un radical organique non chargé ou négativement chargé qui a 1 à 40 atomes de carbone et peut comporter un hétéroatome choisi parmi le groupe constitué des éléments N, O, P, S, As et Sb; et m est un nombre entier de 1 à 10. L'invention a également trait à des systèmes de ligand présentant une configuration de substitution, des systèmes de ligand comportant au moins un des composés à base de métaux de transition selon l'invention, à un procédé pour la préparation de polyoléfines par la polymérisation ou la copolymérisation d'au moins une oléfine en présence d'au moins un des système catalyseurs de l'invention et à l'utilisation des systèmes de ligand de l'invention pour la préparation de composés à base de métaux de transition.</description><subject>ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM</subject><subject>CHEMISTRY</subject><subject>COMPOSITIONS BASED THEREON</subject><subject>HETEROCYCLIC COMPOUNDS</subject><subject>MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS</subject><subject>METALLURGY</subject><subject>ORGANIC CHEMISTRY</subject><subject>ORGANIC MACROMOLECULAR COMPOUNDS</subject><subject>THEIR PREPARATION OR CHEMICAL WORKING-UP</subject><fulltext>true</fulltext><rsrctype>patent</rsrctype><creationdate>2007</creationdate><recordtype>patent</recordtype><sourceid>EVB</sourceid><recordid>eNqNisEKAiEURd20iOofHrSdQAwaWoqjk6A-USNmJUPYKmpg-n8ymA9odQ_3nDXJKXAXddLowMrEDQi0Hq-ua8DonrsO4hCTtA0IXnXl5YCf8wGFjBEUhsrS86BdDx7NgEYq7eKWrB7jcy67ZTdkr2QSl0OZ3rnM03gvr_LJN2SUtvTE2jPl7Phf9QVUTzSI</recordid><startdate>20070607</startdate><enddate>20070607</enddate><creator>BILDSTEIN, BENNO</creator><creator>MIHAN, SHAHRAM</creator><creator>SOLCHINGER, ALEXANDER</creator><creator>KOELLING, LARS</creator><scope>EVB</scope></search><sort><creationdate>20070607</creationdate><title>TRANSITION METAL COMPOUND, LIGAND SYSTEM, CATALYST SYSTEM AND PROCESS FOR PREPARING POLYOLEFINS</title><author>BILDSTEIN, BENNO ; MIHAN, SHAHRAM ; SOLCHINGER, ALEXANDER ; KOELLING, LARS</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-epo_espacenet_WO2007062790A23</frbrgroupid><rsrctype>patents</rsrctype><prefilter>patents</prefilter><language>eng ; fre</language><creationdate>2007</creationdate><topic>ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM</topic><topic>CHEMISTRY</topic><topic>COMPOSITIONS BASED THEREON</topic><topic>HETEROCYCLIC COMPOUNDS</topic><topic>MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS</topic><topic>METALLURGY</topic><topic>ORGANIC CHEMISTRY</topic><topic>ORGANIC MACROMOLECULAR COMPOUNDS</topic><topic>THEIR PREPARATION OR CHEMICAL WORKING-UP</topic><toplevel>online_resources</toplevel><creatorcontrib>BILDSTEIN, BENNO</creatorcontrib><creatorcontrib>MIHAN, SHAHRAM</creatorcontrib><creatorcontrib>SOLCHINGER, ALEXANDER</creatorcontrib><creatorcontrib>KOELLING, LARS</creatorcontrib><collection>esp@cenet</collection></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext_linktorsrc</fulltext></delivery><addata><au>BILDSTEIN, BENNO</au><au>MIHAN, SHAHRAM</au><au>SOLCHINGER, ALEXANDER</au><au>KOELLING, LARS</au><format>patent</format><genre>patent</genre><ristype>GEN</ristype><title>TRANSITION METAL COMPOUND, LIGAND SYSTEM, CATALYST SYSTEM AND PROCESS FOR PREPARING POLYOLEFINS</title><date>2007-06-07</date><risdate>2007</risdate><abstract>The present invention relates to transition metal compounds of the formula (I); where M is an element of group 3, 4, 5, 6, 7, 8, 9 or 10 of the Periodic Table of the Elements or the lanthanide's, the radicals X are identical or different and are each an organic or inorganic radical, with two radicals X also being able to be joined to one another to form a divalent radical, is 1 , 2, 3 or 4, L1 is an organic or inorganic uncharged ligand, is an integer from 0 to 4, R1 is an organic radical having from 1 to 40 carbon atoms, R2 is hydrogen or an organic radical having from 1 to 40 carbon atoms, or R1 and R2 together form a divalent organic group T1 which has from 2 to 40 carbon atoms and together with the atoms connecting its ends forms a monocyclic or polycyclic ring system which may in turn be substituted and may comprise one or more further heteroatoms selected from the group consisting of the elements O, S, Se, Te, N, P and As in the ring system, R3 is hydrogen or an organic radical having from 1 to 40 carbon atoms, R4 is hydrogen or an organic radical having from 1 to 40 carbon atoms, or R3 and R4 together form a divalent organic group T2 which has from 2 to 40 carbon atoms and together with the atoms connecting its ends forms a monocyclic or polycyclic ring system which may in turn be substituted and may comprise one or more heteroatoms selected from the group consisting of the elements O, S, Se, Te, N, P and As in the ring system, R5 is an uncharged or negatively charged organic radical which has from 1 to 40 carbon atoms and may comprise a heteroatom selected from the group consisting of the elements N, O, P, S, As and Sb, and m is an integer from 1 to 10, ligand systems having such a substitution pattern, ligand systems comprising at least one of the transition metal compounds according to the invention, a process for preparing polyolefins by polymerization or copolymerization of at least one olefin in the presence of at least one of the catalyst systems according to the invention and the use of the ligand systems according to the invention for preparing transition metal compounds.
La présente invention a trait à des composés à base de métaux de transition de formule (I), dans laquelle: M est un élément de groupe 3, 4, 5, 6, 7, 8, 9 ou 10 du tableau périodique des éléments ou des lanthanides; les radicaux X sont identiques ou différents et représentent chacun un radical organique ou inorganique, deux radicaux X pouvant être mutuellement assemblés pour former un radical divalent; n est 1, 2, 3 ou 4; L1 est un ligand organique ou inorganique non chargé; h est un nombre entier de 0 à 4; R1 est un radical organique ayant 1 à 40 atomes de carbone; R2 est hydrogène ou un radical organique ayant 1 à 40 atomes de carbone; ou R1 et R2 ensemble forment un groupe organique divalent T1 qui a 2 à 40 atomes de carbone et ensemble avec les atomes reliant ses extrémités forme un système monocyclique ou polycyclique qui peut à son tour être substitué et peut comporter un ou des hétéroatomes choisis parmi le groupe constitué des éléments O, S, Se, Te, N, P et As dans le système cyclique; R3 est hydrogène ou un radical organique ayant 1 à 40 atomes de carbone; R4 est hydrogène ou un radical organique ayant 1 à 40 atomes de carbone; ou R3 et R4 ensemble forment un groupe organique divalent T2 qui a 2 à 40 atomes de carbone et ensemble avec les atomes reliant ses extrémités forme un système monocyclique ou polycyclique qui peut à son tour être substitué et peut comporter un ou des hétéroatomes choisis parmi le groupe constitué des éléments O, S, Se, Te, N, P et As dans le système cyclique; R5 est un radical organique non chargé ou négativement chargé qui a 1 à 40 atomes de carbone et peut comporter un hétéroatome choisi parmi le groupe constitué des éléments N, O, P, S, As et Sb; et m est un nombre entier de 1 à 10. L'invention a également trait à des systèmes de ligand présentant une configuration de substitution, des systèmes de ligand comportant au moins un des composés à base de métaux de transition selon l'invention, à un procédé pour la préparation de polyoléfines par la polymérisation ou la copolymérisation d'au moins une oléfine en présence d'au moins un des système catalyseurs de l'invention et à l'utilisation des systèmes de ligand de l'invention pour la préparation de composés à base de métaux de transition.</abstract><oa>free_for_read</oa></addata></record> |
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subjects | ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM CHEMISTRY COMPOSITIONS BASED THEREON HETEROCYCLIC COMPOUNDS MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS METALLURGY ORGANIC CHEMISTRY ORGANIC MACROMOLECULAR COMPOUNDS THEIR PREPARATION OR CHEMICAL WORKING-UP |
title | TRANSITION METAL COMPOUND, LIGAND SYSTEM, CATALYST SYSTEM AND PROCESS FOR PREPARING POLYOLEFINS |
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