PROCESS FOR THE CARBONYLATION OF ETHYLENICALLY OR ACETYLENICALLY UNSATURATED COMPOUNDS

A process for the carbonylation of unsaturated compounds by contacting the unsaturated compound with carbon monoxide in the presence of a catalyst system comprising: (a) a source of palladium and/or platinum; and (e) an unsymmetrical bidentate diphosphine ligand of formula (I), R R > P - R - P &l...

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Hauptverfasser: JAGER, WILLEM WABE, PUGH, ROBERT IAN, DRENT, EIT, ERNST, RENE
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creator JAGER, WILLEM WABE
PUGH, ROBERT IAN
DRENT, EIT
ERNST, RENE
description A process for the carbonylation of unsaturated compounds by contacting the unsaturated compound with carbon monoxide in the presence of a catalyst system comprising: (a) a source of palladium and/or platinum; and (e) an unsymmetrical bidentate diphosphine ligand of formula (I), R R > P - R - P < R R (I) wherein P andp P represent phosphorus atoms; R represents a divalent organic bridging group; and R , R , R and R each individually, or R and R jointly, and/or R and R jointly represent organic groups that are covalently linked to the phosphorus; and wherein R , R , R and R are chosen in such way, that the phosphino group R R > P differs from the phosphino group P < R R . Cette invention concerne un procédé de carbonylation de composés insaturés, lequel procédé consiste à mettre le composé insaturé en contact avec un monoxyde de carbone en présence d'un système catalyseur comprenant: (a) une source de palladium et/ou de platinium; et (e) un ligand disphosphine bidenté asymétrique représenté par la formule R R > P - R - P < R R (I) dans laquelle P et P désignent des atomes de phosphore; R désigne un groupe de pontage organique divalent; et R , R , R et R désignent chacun individuellement, ou R et R ensemble et/ou R et R ensemble désignent des groupes organiques qui sont liés par covalence à l'atome de phosphore et dans laquelle R , R , R et R sont sélectionnés de façon que le groupe phosphino R R > P soit différent du groupe phosphino P < R R .
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Cette invention concerne un procédé de carbonylation de composés insaturés, lequel procédé consiste à mettre le composé insaturé en contact avec un monoxyde de carbone en présence d'un système catalyseur comprenant: (a) une source de palladium et/ou de platinium; et (e) un ligand disphosphine bidenté asymétrique représenté par la formule R R &gt; P - R - P &lt; R R (I) dans laquelle P et P désignent des atomes de phosphore; R désigne un groupe de pontage organique divalent; et R , R , R et R désignent chacun individuellement, ou R et R ensemble et/ou R et R ensemble désignent des groupes organiques qui sont liés par covalence à l'atome de phosphore et dans laquelle R , R , R et R sont sélectionnés de façon que le groupe phosphino R R &gt; P soit différent du groupe phosphino P &lt; R R .</abstract><edition>7</edition><oa>free_for_read</oa></addata></record>
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subjects ACYCLIC OR CARBOCYCLIC COMPOUNDS
ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY
CHEMISTRY
METALLURGY
ORGANIC CHEMISTRY
PERFORMING OPERATIONS
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
THEIR RELEVANT APPARATUS
TRANSPORTING
title PROCESS FOR THE CARBONYLATION OF ETHYLENICALLY OR ACETYLENICALLY UNSATURATED COMPOUNDS
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