HETEROGENEOUS RUTHENIUM CATALYST, NUCLEUS-HYDROGENATED DIGLYCIDYL ETHER OF BISPHENOLS A AND F, AND METHOD FOR THE PRODUCTION THEREOF
Ruthenium-Heterogenkatalysator enthaltend Siliziumdioxid als Trägermaterial, wobei im Siliziumdioxid das mittels Si-Festkörper-NMR bestimmte prozentuale Verhältnis der Q2 - und Q3 - Strukturen Q2/Q3 kleiner als 25 ist, Verfahren zur Herstellung eines Bisglycidylethers der Formel (I), in der R CH3 od...
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| creator | BECKER, MICHAEL ARNDT, JAN-DIRK VAN LAAR, FREDERIK HERWIG, STEPHAN |
| description | Ruthenium-Heterogenkatalysator enthaltend Siliziumdioxid als Trägermaterial, wobei im Siliziumdioxid das mittels Si-Festkörper-NMR bestimmte prozentuale Verhältnis der Q2 - und Q3 - Strukturen Q2/Q3 kleiner als 25 ist, Verfahren zur Herstellung eines Bisglycidylethers der Formel (I), in der R CH3 oder H bedeutet, durch Kernhydrierung des entsprechenden aromatischen Bisglycidylethers der Formel (II), in dem man den o.g. Ruthenium-Heterogenkatalysator einsetzt, und Bisglycidylether der Formel (I), herstellbar durch das o.g. Verfahren.
Disclosed are a heterogeneous ruthenium catalyst containing silicon oxide as a carrier material, the ratio Q2/Q3 between Q2 structures and Q3 structures in the silicon oxide, which is determined using Si solid-state NMR, being less than 25, a method for the production of a diglycidyl ether of formula (I), wherein R represents CH3 or H, by hydrogenating the nucleus of the corresponding aromatic diglycidyl ether of formula (II) using the inventive heterogeneous ruthenium catalyst, as well as diglycidyl ether of formula (I) produced according to said method.
L'invention concerne un catalyseur hétérogène à base de ruthénium qui contient du dioxyde de silicium comme matériau support, le rapport Q2/Q3 en pourcentage, déterminé par résonance magnétique nucléaire en phase solide du silicium 29, des structures Q2 et Q3 dans le dioxyde de silicium étant inférieur à 25. L'invention concerne également un procédé pour produire un éther diglycidylique de formule (I), dans laquelle R représente CH3 ou H, par hydrogénation du noyau de l'éther diglycidylique aromatique correspondant de formule (II) en utilisant le catalyseur hétérogène à base de ruthénium selon l'invention. L'invention concerne en outre des éthers diglycidyliques de formule (I) produits selon le procédé de l'invention. |
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Disclosed are a heterogeneous ruthenium catalyst containing silicon oxide as a carrier material, the ratio Q2/Q3 between Q2 structures and Q3 structures in the silicon oxide, which is determined using Si solid-state NMR, being less than 25, a method for the production of a diglycidyl ether of formula (I), wherein R represents CH3 or H, by hydrogenating the nucleus of the corresponding aromatic diglycidyl ether of formula (II) using the inventive heterogeneous ruthenium catalyst, as well as diglycidyl ether of formula (I) produced according to said method.
L'invention concerne un catalyseur hétérogène à base de ruthénium qui contient du dioxyde de silicium comme matériau support, le rapport Q2/Q3 en pourcentage, déterminé par résonance magnétique nucléaire en phase solide du silicium 29, des structures Q2 et Q3 dans le dioxyde de silicium étant inférieur à 25. L'invention concerne également un procédé pour produire un éther diglycidylique de formule (I), dans laquelle R représente CH3 ou H, par hydrogénation du noyau de l'éther diglycidylique aromatique correspondant de formule (II) en utilisant le catalyseur hétérogène à base de ruthénium selon l'invention. L'invention concerne en outre des éthers diglycidyliques de formule (I) produits selon le procédé de l'invention.</description><edition>7</edition><language>eng ; fre ; ger</language><subject>CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY ; CHEMISTRY ; COMPOSITIONS BASED THEREON ; HETEROCYCLIC COMPOUNDS ; MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONSONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS ; METALLURGY ; ORGANIC CHEMISTRY ; ORGANIC MACROMOLECULAR COMPOUNDS ; PERFORMING OPERATIONS ; PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL ; THEIR PREPARATION OR CHEMICAL WORKING-UP ; THEIR RELEVANT APPARATUS ; TRANSPORTING</subject><creationdate>2005</creationdate><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=20050707&DB=EPODOC&CC=WO&NR=2005061105A1$$EHTML$$P50$$Gepo$$Hfree_for_read</linktohtml><link.rule.ids>230,308,780,885,25564,76419</link.rule.ids><linktorsrc>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=20050707&DB=EPODOC&CC=WO&NR=2005061105A1$$EView_record_in_European_Patent_Office$$FView_record_in_$$GEuropean_Patent_Office$$Hfree_for_read</linktorsrc></links><search><creatorcontrib>BECKER, MICHAEL</creatorcontrib><creatorcontrib>ARNDT, JAN-DIRK</creatorcontrib><creatorcontrib>VAN LAAR, FREDERIK</creatorcontrib><creatorcontrib>HERWIG, STEPHAN</creatorcontrib><title>HETEROGENEOUS RUTHENIUM CATALYST, NUCLEUS-HYDROGENATED DIGLYCIDYL ETHER OF BISPHENOLS A AND F, AND METHOD FOR THE PRODUCTION THEREOF</title><description>Ruthenium-Heterogenkatalysator enthaltend Siliziumdioxid als Trägermaterial, wobei im Siliziumdioxid das mittels Si-Festkörper-NMR bestimmte prozentuale Verhältnis der Q2 - und Q3 - Strukturen Q2/Q3 kleiner als 25 ist, Verfahren zur Herstellung eines Bisglycidylethers der Formel (I), in der R CH3 oder H bedeutet, durch Kernhydrierung des entsprechenden aromatischen Bisglycidylethers der Formel (II), in dem man den o.g. Ruthenium-Heterogenkatalysator einsetzt, und Bisglycidylether der Formel (I), herstellbar durch das o.g. Verfahren.
Disclosed are a heterogeneous ruthenium catalyst containing silicon oxide as a carrier material, the ratio Q2/Q3 between Q2 structures and Q3 structures in the silicon oxide, which is determined using Si solid-state NMR, being less than 25, a method for the production of a diglycidyl ether of formula (I), wherein R represents CH3 or H, by hydrogenating the nucleus of the corresponding aromatic diglycidyl ether of formula (II) using the inventive heterogeneous ruthenium catalyst, as well as diglycidyl ether of formula (I) produced according to said method.
L'invention concerne un catalyseur hétérogène à base de ruthénium qui contient du dioxyde de silicium comme matériau support, le rapport Q2/Q3 en pourcentage, déterminé par résonance magnétique nucléaire en phase solide du silicium 29, des structures Q2 et Q3 dans le dioxyde de silicium étant inférieur à 25. L'invention concerne également un procédé pour produire un éther diglycidylique de formule (I), dans laquelle R représente CH3 ou H, par hydrogénation du noyau de l'éther diglycidylique aromatique correspondant de formule (II) en utilisant le catalyseur hétérogène à base de ruthénium selon l'invention. L'invention concerne en outre des éthers diglycidyliques de formule (I) produits selon le procédé de l'invention.</description><subject>CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY</subject><subject>CHEMISTRY</subject><subject>COMPOSITIONS BASED THEREON</subject><subject>HETEROCYCLIC COMPOUNDS</subject><subject>MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONSONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS</subject><subject>METALLURGY</subject><subject>ORGANIC CHEMISTRY</subject><subject>ORGANIC MACROMOLECULAR COMPOUNDS</subject><subject>PERFORMING OPERATIONS</subject><subject>PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL</subject><subject>THEIR PREPARATION OR CHEMICAL WORKING-UP</subject><subject>THEIR RELEVANT APPARATUS</subject><subject>TRANSPORTING</subject><fulltext>true</fulltext><rsrctype>patent</rsrctype><creationdate>2005</creationdate><recordtype>patent</recordtype><sourceid>EVB</sourceid><recordid>eNqNi0sKwjAUALtxIeodHrhtoVXqPiavbSDNK_kgXZUicSVaqEfw4MbiAVwNAzPr5N2gQ0M1aiRvwXjXoJa-Bc4cU711KWjPFXqbNb1YQuZQgJC16rkUvQKMiwGq4CxtF29SFhgwLaBKF7SxoGhkIKbQGRKeO0n6qwap2iar23ifw-7HTbKv0PEmC9NzCPM0XsMjvIYLHfK8zE9FkZesOP5XfQB_3z4k</recordid><startdate>20050707</startdate><enddate>20050707</enddate><creator>BECKER, MICHAEL</creator><creator>ARNDT, JAN-DIRK</creator><creator>VAN LAAR, FREDERIK</creator><creator>HERWIG, STEPHAN</creator><scope>EVB</scope></search><sort><creationdate>20050707</creationdate><title>HETEROGENEOUS RUTHENIUM CATALYST, NUCLEUS-HYDROGENATED DIGLYCIDYL ETHER OF BISPHENOLS A AND F, AND METHOD FOR THE PRODUCTION THEREOF</title><author>BECKER, MICHAEL ; ARNDT, JAN-DIRK ; VAN LAAR, FREDERIK ; HERWIG, STEPHAN</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-epo_espacenet_WO2005061105A13</frbrgroupid><rsrctype>patents</rsrctype><prefilter>patents</prefilter><language>eng ; fre ; ger</language><creationdate>2005</creationdate><topic>CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY</topic><topic>CHEMISTRY</topic><topic>COMPOSITIONS BASED THEREON</topic><topic>HETEROCYCLIC COMPOUNDS</topic><topic>MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONSONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS</topic><topic>METALLURGY</topic><topic>ORGANIC CHEMISTRY</topic><topic>ORGANIC MACROMOLECULAR COMPOUNDS</topic><topic>PERFORMING OPERATIONS</topic><topic>PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL</topic><topic>THEIR PREPARATION OR CHEMICAL WORKING-UP</topic><topic>THEIR RELEVANT APPARATUS</topic><topic>TRANSPORTING</topic><toplevel>online_resources</toplevel><creatorcontrib>BECKER, MICHAEL</creatorcontrib><creatorcontrib>ARNDT, JAN-DIRK</creatorcontrib><creatorcontrib>VAN LAAR, FREDERIK</creatorcontrib><creatorcontrib>HERWIG, STEPHAN</creatorcontrib><collection>esp@cenet</collection></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext_linktorsrc</fulltext></delivery><addata><au>BECKER, MICHAEL</au><au>ARNDT, JAN-DIRK</au><au>VAN LAAR, FREDERIK</au><au>HERWIG, STEPHAN</au><format>patent</format><genre>patent</genre><ristype>GEN</ristype><title>HETEROGENEOUS RUTHENIUM CATALYST, NUCLEUS-HYDROGENATED DIGLYCIDYL ETHER OF BISPHENOLS A AND F, AND METHOD FOR THE PRODUCTION THEREOF</title><date>2005-07-07</date><risdate>2005</risdate><abstract>Ruthenium-Heterogenkatalysator enthaltend Siliziumdioxid als Trägermaterial, wobei im Siliziumdioxid das mittels Si-Festkörper-NMR bestimmte prozentuale Verhältnis der Q2 - und Q3 - Strukturen Q2/Q3 kleiner als 25 ist, Verfahren zur Herstellung eines Bisglycidylethers der Formel (I), in der R CH3 oder H bedeutet, durch Kernhydrierung des entsprechenden aromatischen Bisglycidylethers der Formel (II), in dem man den o.g. Ruthenium-Heterogenkatalysator einsetzt, und Bisglycidylether der Formel (I), herstellbar durch das o.g. Verfahren.
Disclosed are a heterogeneous ruthenium catalyst containing silicon oxide as a carrier material, the ratio Q2/Q3 between Q2 structures and Q3 structures in the silicon oxide, which is determined using Si solid-state NMR, being less than 25, a method for the production of a diglycidyl ether of formula (I), wherein R represents CH3 or H, by hydrogenating the nucleus of the corresponding aromatic diglycidyl ether of formula (II) using the inventive heterogeneous ruthenium catalyst, as well as diglycidyl ether of formula (I) produced according to said method.
L'invention concerne un catalyseur hétérogène à base de ruthénium qui contient du dioxyde de silicium comme matériau support, le rapport Q2/Q3 en pourcentage, déterminé par résonance magnétique nucléaire en phase solide du silicium 29, des structures Q2 et Q3 dans le dioxyde de silicium étant inférieur à 25. L'invention concerne également un procédé pour produire un éther diglycidylique de formule (I), dans laquelle R représente CH3 ou H, par hydrogénation du noyau de l'éther diglycidylique aromatique correspondant de formule (II) en utilisant le catalyseur hétérogène à base de ruthénium selon l'invention. L'invention concerne en outre des éthers diglycidyliques de formule (I) produits selon le procédé de l'invention.</abstract><edition>7</edition><oa>free_for_read</oa></addata></record> |
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| subjects | CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY CHEMISTRY COMPOSITIONS BASED THEREON HETEROCYCLIC COMPOUNDS MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONSONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS METALLURGY ORGANIC CHEMISTRY ORGANIC MACROMOLECULAR COMPOUNDS PERFORMING OPERATIONS PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL THEIR PREPARATION OR CHEMICAL WORKING-UP THEIR RELEVANT APPARATUS TRANSPORTING |
| title | HETEROGENEOUS RUTHENIUM CATALYST, NUCLEUS-HYDROGENATED DIGLYCIDYL ETHER OF BISPHENOLS A AND F, AND METHOD FOR THE PRODUCTION THEREOF |
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