MESOPOROUS AND MICROPOROUS ALUMINOSILICATES WITH HIGH CATALYTIC ACTIVITY IN ACID CATALYTIC REACTION AND METHOD FOR THE PRODUCTION THEREOF

The invention relates to novel microporous and mesoporous materials having a chemical composition of the following formula (in oxide moles): Al O : m SiO : n M O, wherein the value of m is between 2 and 50, preferably between 4 and 10; M represents cations Na or H, and the value of n is between 0.01...

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Hauptverfasser: AGUNDEZ RODRIGUEZ, JAVIER, PEREZ PARIENTE, JOAQUIN, SASTRE DE ANDRES, ENRIQUE, MARQUEZ ALVAREZ, CARLOS, DIAZ CARRETERO, ISABEL
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creator AGUNDEZ RODRIGUEZ, JAVIER
PEREZ PARIENTE, JOAQUIN
SASTRE DE ANDRES, ENRIQUE
MARQUEZ ALVAREZ, CARLOS
DIAZ CARRETERO, ISABEL
description The invention relates to novel microporous and mesoporous materials having a chemical composition of the following formula (in oxide moles): Al O : m SiO : n M O, wherein the value of m is between 2 and 50, preferably between 4 and 10; M represents cations Na or H, and the value of n is between 0.01 and 2, preferably between 0.1 and 1. Said materials have a regular distribution of the pores, the average diameter of which is between 1.0 nm and 15 nm. Said materials show a high catalytic activity in acid catalytic reactions. The invention also relates to the method for the production of said materials and to their use as catalysts in reactions for the transformation of hydrocarbons such as cracking, isomerization, transalkylation, alkylation, dimerization and polymerization. Esta invención se refiere a nuevos materiales de tipo aluminosilicatos microporosos y mesoporosos con una composición química expresada por la siguiente fórmula (en moles de óxidos): Al O : m SiO : n M O en donde el valor de m está comprendido entre 2 y 50, preferentemente entre 4 y 10; M representa los cationes Nao H, y el valor de n está comprendido entre 0,01 y 2, preferentemente entre 0,1 y 1. Estos materiales poseen una distribución regular de poros cuyo diámetro promedio está comprendido entre 1,0 nm y 15 nm. Presentan asimismo una elevada actividad catalítica en reacciones de catálisis ácida. Se describe su procedimiento de preparación y su uso como catalizadores de reacciones de transformación de hidrocarburos, tales como craqueo, isomerización, transalquilación, alquilación, dimerización y polimerización. L'invention se rapporte à de nouveaux matériaux de type aluminosilicates micropores et mésopores présentant une composition chimique exprimée par la formule suivante (en moles d'oxydes): Al2O3 : m SiO2 : n M2O où la valeur de m est comprise entre 2 et 50, de préférence entre 4 et 10; où M représente les cations Na+ o H+, et où la valeur de n est comprise entre 0,01 et 2, de préférence entre 0,1 et 1. Ces matériaux possèdent une distribution régulière de pores dont le diamètre moyen est compris entre 1,0 nm et 15 nm. Ces matériaux présentent également une activité catalytique élevée dans des réactions de catalyse acide. L'invention concerne le procédé de préparation et d'utilisation en tant que catalyseurs de réactions de transformation d'hydrocarbures, tels que le craquage, l'isomérisation, la transalquilation, l'alquilation, la dimérisation et la polymérisation.
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Said materials have a regular distribution of the pores, the average diameter of which is between 1.0 nm and 15 nm. Said materials show a high catalytic activity in acid catalytic reactions. The invention also relates to the method for the production of said materials and to their use as catalysts in reactions for the transformation of hydrocarbons such as cracking, isomerization, transalkylation, alkylation, dimerization and polymerization. Esta invención se refiere a nuevos materiales de tipo aluminosilicatos microporosos y mesoporosos con una composición química expresada por la siguiente fórmula (en moles de óxidos): Al O : m SiO : n M O en donde el valor de m está comprendido entre 2 y 50, preferentemente entre 4 y 10; M representa los cationes Na&lt;+&gt;o H&lt;+&gt;, y el valor de n está comprendido entre 0,01 y 2, preferentemente entre 0,1 y 1. Estos materiales poseen una distribución regular de poros cuyo diámetro promedio está comprendido entre 1,0 nm y 15 nm. Presentan asimismo una elevada actividad catalítica en reacciones de catálisis ácida. Se describe su procedimiento de preparación y su uso como catalizadores de reacciones de transformación de hidrocarburos, tales como craqueo, isomerización, transalquilación, alquilación, dimerización y polimerización. L'invention se rapporte à de nouveaux matériaux de type aluminosilicates micropores et mésopores présentant une composition chimique exprimée par la formule suivante (en moles d'oxydes): Al2O3 : m SiO2 : n M2O où la valeur de m est comprise entre 2 et 50, de préférence entre 4 et 10; où M représente les cations Na+ o H+, et où la valeur de n est comprise entre 0,01 et 2, de préférence entre 0,1 et 1. Ces matériaux possèdent une distribution régulière de pores dont le diamètre moyen est compris entre 1,0 nm et 15 nm. Ces matériaux présentent également une activité catalytique élevée dans des réactions de catalyse acide. L'invention concerne le procédé de préparation et d'utilisation en tant que catalyseurs de réactions de transformation d'hydrocarbures, tels que le craquage, l'isomérisation, la transalquilation, l'alquilation, la dimérisation et la polymérisation.</description><edition>7</edition><language>eng ; fre ; spa</language><subject>CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY ; CHEMISTRY ; COMPOUNDS THEREOF ; CRACKING HYDROCARBON OILS ; FUELS ; INORGANIC CHEMISTRY ; LUBRICANTS ; METALLURGY ; MINERAL WAXES ; NON-METALLIC ELEMENTS ; PEAT ; PERFORMING OPERATIONS ; PETROLEUM, GAS OR COKE INDUSTRIES ; PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL ; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVEHYDROGENATION, OLIGOMERISATION, POLYMERISATION ; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, ORGASES ; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS ; REFORMING OF NAPHTHA ; TECHNICAL GASES CONTAINING CARBON MONOXIDE ; THEIR RELEVANT APPARATUS ; TRANSPORTING</subject><creationdate>2004</creationdate><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&amp;date=20040219&amp;DB=EPODOC&amp;CC=WO&amp;NR=2004014798A1$$EHTML$$P50$$Gepo$$Hfree_for_read</linktohtml><link.rule.ids>230,308,776,881,25542,76290</link.rule.ids><linktorsrc>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&amp;date=20040219&amp;DB=EPODOC&amp;CC=WO&amp;NR=2004014798A1$$EView_record_in_European_Patent_Office$$FView_record_in_$$GEuropean_Patent_Office$$Hfree_for_read</linktorsrc></links><search><creatorcontrib>AGUNDEZ RODRIGUEZ, JAVIER</creatorcontrib><creatorcontrib>PEREZ PARIENTE, JOAQUIN</creatorcontrib><creatorcontrib>SASTRE DE ANDRES, ENRIQUE</creatorcontrib><creatorcontrib>MARQUEZ ALVAREZ, CARLOS</creatorcontrib><creatorcontrib>DIAZ CARRETERO, ISABEL</creatorcontrib><title>MESOPOROUS AND MICROPOROUS ALUMINOSILICATES WITH HIGH CATALYTIC ACTIVITY IN ACID CATALYTIC REACTION AND METHOD FOR THE PRODUCTION THEREOF</title><description>The invention relates to novel microporous and mesoporous materials having a chemical composition of the following formula (in oxide moles): Al O : m SiO : n M O, wherein the value of m is between 2 and 50, preferably between 4 and 10; M represents cations Na&lt;+&gt; or H&lt;+&gt;, and the value of n is between 0.01 and 2, preferably between 0.1 and 1. Said materials have a regular distribution of the pores, the average diameter of which is between 1.0 nm and 15 nm. Said materials show a high catalytic activity in acid catalytic reactions. The invention also relates to the method for the production of said materials and to their use as catalysts in reactions for the transformation of hydrocarbons such as cracking, isomerization, transalkylation, alkylation, dimerization and polymerization. Esta invención se refiere a nuevos materiales de tipo aluminosilicatos microporosos y mesoporosos con una composición química expresada por la siguiente fórmula (en moles de óxidos): Al O : m SiO : n M O en donde el valor de m está comprendido entre 2 y 50, preferentemente entre 4 y 10; M representa los cationes Na&lt;+&gt;o H&lt;+&gt;, y el valor de n está comprendido entre 0,01 y 2, preferentemente entre 0,1 y 1. Estos materiales poseen una distribución regular de poros cuyo diámetro promedio está comprendido entre 1,0 nm y 15 nm. Presentan asimismo una elevada actividad catalítica en reacciones de catálisis ácida. Se describe su procedimiento de preparación y su uso como catalizadores de reacciones de transformación de hidrocarburos, tales como craqueo, isomerización, transalquilación, alquilación, dimerización y polimerización. L'invention se rapporte à de nouveaux matériaux de type aluminosilicates micropores et mésopores présentant une composition chimique exprimée par la formule suivante (en moles d'oxydes): Al2O3 : m SiO2 : n M2O où la valeur de m est comprise entre 2 et 50, de préférence entre 4 et 10; où M représente les cations Na+ o H+, et où la valeur de n est comprise entre 0,01 et 2, de préférence entre 0,1 et 1. Ces matériaux possèdent une distribution régulière de pores dont le diamètre moyen est compris entre 1,0 nm et 15 nm. Ces matériaux présentent également une activité catalytique élevée dans des réactions de catalyse acide. L'invention concerne le procédé de préparation et d'utilisation en tant que catalyseurs de réactions de transformation d'hydrocarbures, tels que le craquage, l'isomérisation, la transalquilation, l'alquilation, la dimérisation et la polymérisation.</description><subject>CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY</subject><subject>CHEMISTRY</subject><subject>COMPOUNDS THEREOF</subject><subject>CRACKING HYDROCARBON OILS</subject><subject>FUELS</subject><subject>INORGANIC CHEMISTRY</subject><subject>LUBRICANTS</subject><subject>METALLURGY</subject><subject>MINERAL WAXES</subject><subject>NON-METALLIC ELEMENTS</subject><subject>PEAT</subject><subject>PERFORMING OPERATIONS</subject><subject>PETROLEUM, GAS OR COKE INDUSTRIES</subject><subject>PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL</subject><subject>PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVEHYDROGENATION, OLIGOMERISATION, POLYMERISATION</subject><subject>RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, ORGASES</subject><subject>REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS</subject><subject>REFORMING OF NAPHTHA</subject><subject>TECHNICAL GASES CONTAINING CARBON MONOXIDE</subject><subject>THEIR RELEVANT APPARATUS</subject><subject>TRANSPORTING</subject><fulltext>true</fulltext><rsrctype>patent</rsrctype><creationdate>2004</creationdate><recordtype>patent</recordtype><sourceid>EVB</sourceid><recordid>eNqNjMEKwjAQRHvxIOo_LHgWWi2ox5CkZqHNSrK19FSKxJNoof6Ef22lIh49zTzeMNPoWWhPR3JUehBWQYHSfTkvC7TkMUcpWHuokA0YPBgYWOQ1owQhGU_INaAdOqof5fRbkh2PNRtSkJEDNhqOjlQ52gGdpmweTS7ttQ-LT86iZaZZmlXo7k3ou_YcbuHRVLSO4zRO0u1-J5LNf6sX7sU__w</recordid><startdate>20040219</startdate><enddate>20040219</enddate><creator>AGUNDEZ RODRIGUEZ, JAVIER</creator><creator>PEREZ PARIENTE, JOAQUIN</creator><creator>SASTRE DE ANDRES, ENRIQUE</creator><creator>MARQUEZ ALVAREZ, CARLOS</creator><creator>DIAZ CARRETERO, ISABEL</creator><scope>EVB</scope></search><sort><creationdate>20040219</creationdate><title>MESOPOROUS AND MICROPOROUS ALUMINOSILICATES WITH HIGH CATALYTIC ACTIVITY IN ACID CATALYTIC REACTION AND METHOD FOR THE PRODUCTION THEREOF</title><author>AGUNDEZ RODRIGUEZ, JAVIER ; PEREZ PARIENTE, JOAQUIN ; SASTRE DE ANDRES, ENRIQUE ; MARQUEZ ALVAREZ, CARLOS ; DIAZ CARRETERO, ISABEL</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-epo_espacenet_WO2004014798A13</frbrgroupid><rsrctype>patents</rsrctype><prefilter>patents</prefilter><language>eng ; fre ; spa</language><creationdate>2004</creationdate><topic>CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY</topic><topic>CHEMISTRY</topic><topic>COMPOUNDS THEREOF</topic><topic>CRACKING HYDROCARBON OILS</topic><topic>FUELS</topic><topic>INORGANIC CHEMISTRY</topic><topic>LUBRICANTS</topic><topic>METALLURGY</topic><topic>MINERAL WAXES</topic><topic>NON-METALLIC ELEMENTS</topic><topic>PEAT</topic><topic>PERFORMING OPERATIONS</topic><topic>PETROLEUM, GAS OR COKE INDUSTRIES</topic><topic>PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL</topic><topic>PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVEHYDROGENATION, OLIGOMERISATION, POLYMERISATION</topic><topic>RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, ORGASES</topic><topic>REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS</topic><topic>REFORMING OF NAPHTHA</topic><topic>TECHNICAL GASES CONTAINING CARBON MONOXIDE</topic><topic>THEIR RELEVANT APPARATUS</topic><topic>TRANSPORTING</topic><toplevel>online_resources</toplevel><creatorcontrib>AGUNDEZ RODRIGUEZ, JAVIER</creatorcontrib><creatorcontrib>PEREZ PARIENTE, JOAQUIN</creatorcontrib><creatorcontrib>SASTRE DE ANDRES, ENRIQUE</creatorcontrib><creatorcontrib>MARQUEZ ALVAREZ, CARLOS</creatorcontrib><creatorcontrib>DIAZ CARRETERO, ISABEL</creatorcontrib><collection>esp@cenet</collection></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext_linktorsrc</fulltext></delivery><addata><au>AGUNDEZ RODRIGUEZ, JAVIER</au><au>PEREZ PARIENTE, JOAQUIN</au><au>SASTRE DE ANDRES, ENRIQUE</au><au>MARQUEZ ALVAREZ, CARLOS</au><au>DIAZ CARRETERO, ISABEL</au><format>patent</format><genre>patent</genre><ristype>GEN</ristype><title>MESOPOROUS AND MICROPOROUS ALUMINOSILICATES WITH HIGH CATALYTIC ACTIVITY IN ACID CATALYTIC REACTION AND METHOD FOR THE PRODUCTION THEREOF</title><date>2004-02-19</date><risdate>2004</risdate><abstract>The invention relates to novel microporous and mesoporous materials having a chemical composition of the following formula (in oxide moles): Al O : m SiO : n M O, wherein the value of m is between 2 and 50, preferably between 4 and 10; M represents cations Na&lt;+&gt; or H&lt;+&gt;, and the value of n is between 0.01 and 2, preferably between 0.1 and 1. Said materials have a regular distribution of the pores, the average diameter of which is between 1.0 nm and 15 nm. Said materials show a high catalytic activity in acid catalytic reactions. The invention also relates to the method for the production of said materials and to their use as catalysts in reactions for the transformation of hydrocarbons such as cracking, isomerization, transalkylation, alkylation, dimerization and polymerization. Esta invención se refiere a nuevos materiales de tipo aluminosilicatos microporosos y mesoporosos con una composición química expresada por la siguiente fórmula (en moles de óxidos): Al O : m SiO : n M O en donde el valor de m está comprendido entre 2 y 50, preferentemente entre 4 y 10; M representa los cationes Na&lt;+&gt;o H&lt;+&gt;, y el valor de n está comprendido entre 0,01 y 2, preferentemente entre 0,1 y 1. Estos materiales poseen una distribución regular de poros cuyo diámetro promedio está comprendido entre 1,0 nm y 15 nm. Presentan asimismo una elevada actividad catalítica en reacciones de catálisis ácida. Se describe su procedimiento de preparación y su uso como catalizadores de reacciones de transformación de hidrocarburos, tales como craqueo, isomerización, transalquilación, alquilación, dimerización y polimerización. L'invention se rapporte à de nouveaux matériaux de type aluminosilicates micropores et mésopores présentant une composition chimique exprimée par la formule suivante (en moles d'oxydes): Al2O3 : m SiO2 : n M2O où la valeur de m est comprise entre 2 et 50, de préférence entre 4 et 10; où M représente les cations Na+ o H+, et où la valeur de n est comprise entre 0,01 et 2, de préférence entre 0,1 et 1. Ces matériaux possèdent une distribution régulière de pores dont le diamètre moyen est compris entre 1,0 nm et 15 nm. Ces matériaux présentent également une activité catalytique élevée dans des réactions de catalyse acide. L'invention concerne le procédé de préparation et d'utilisation en tant que catalyseurs de réactions de transformation d'hydrocarbures, tels que le craquage, l'isomérisation, la transalquilation, l'alquilation, la dimérisation et la polymérisation.</abstract><edition>7</edition><oa>free_for_read</oa></addata></record>
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subjects CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY
CHEMISTRY
COMPOUNDS THEREOF
CRACKING HYDROCARBON OILS
FUELS
INORGANIC CHEMISTRY
LUBRICANTS
METALLURGY
MINERAL WAXES
NON-METALLIC ELEMENTS
PEAT
PERFORMING OPERATIONS
PETROLEUM, GAS OR COKE INDUSTRIES
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVEHYDROGENATION, OLIGOMERISATION, POLYMERISATION
RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, ORGASES
REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS
REFORMING OF NAPHTHA
TECHNICAL GASES CONTAINING CARBON MONOXIDE
THEIR RELEVANT APPARATUS
TRANSPORTING
title MESOPOROUS AND MICROPOROUS ALUMINOSILICATES WITH HIGH CATALYTIC ACTIVITY IN ACID CATALYTIC REACTION AND METHOD FOR THE PRODUCTION THEREOF
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