CROSS-COUPLING SYNTHESIS OF ALKYL (DIALKYLPHENYL) INDENES

A cross-coupling synthesis of 2-alkyl-4-(2,6­dialkylphenyl)indenes is described. A 2-alkylidene is treated with a dialkylboronic acid in the presence of a catalyst. A feature of the invention is the use of a cross-coupling catalyst comprising palladium dichloride (1,5-cyclooctadiene) as a cross-coup...

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description A cross-coupling synthesis of 2-alkyl-4-(2,6­dialkylphenyl)indenes is described. A 2-alkylidene is treated with a dialkylboronic acid in the presence of a catalyst. A feature of the invention is the use of a cross-coupling catalyst comprising palladium dichloride (1,5-cyclooctadiene) as a cross-coupling catalyst. L'invention concerne une synthèse de couplage croisé d'indènes 2-alkyle-4-(2,6-dialkyle phényle). Un indène 2-alkyle est traité avec un acide boronique dialkyle en présence d'un catalyseur. La présente invention porte également sur l'utilisation d'un catalyseur de couplage croisé contenant du dichlorure de palladium (1,5-cyclooctadiène) comme catalyseur de couplage croisé.
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subjects ACYCLIC OR CARBOCYCLIC COMPOUNDS
CHEMISTRY
METALLURGY
ORGANIC CHEMISTRY
title CROSS-COUPLING SYNTHESIS OF ALKYL (DIALKYLPHENYL) INDENES
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