HIGH CAPACITY CALCIUM LITHIUM BASED HYDROGEN STORAGE MATERIAL AND METHOD OF MAKING THE SAME
A nonreversible metal hydride for use as a hydrogen fuel. The nonreversible metal hydride is formed from an intermetallic compound having the formulaa Ca1+aLi2+b. The Ca1+aLi2+b is formed by melting amounts of elemental lithium and calcium together by induction heating in an argon atmosphere. The Ca...
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| description | A nonreversible metal hydride for use as a hydrogen fuel. The nonreversible metal hydride is formed from an intermetallic compound having the formulaa Ca1+aLi2+b. The Ca1+aLi2+b is formed by melting amounts of elemental lithium and calcium together by induction heating in an argon atmosphere. The Ca1+aLi2+b is cooled and crushed into a powder. The alloy powder is subsequently hadrogenated at ambient temperatures or lower. Resulting is a metal hydride having exceptional reactivity to water during the hydrolysis due to its nanocrystalline structure. Dehydrogenation of the metal hydride does not regularly occur due to the absorbed hydrogen being chemically bonded to the lithium and calcium. The ca1+a Li2+b hydride may be used in a variety of applications as a hydrogen fuel and the Ca1+a Li2+b alloy may be used as a desiccant for removing moisture from hydrogen or hydrogen containing streams.
L'invention concerne un hydrure métallique non réversible en tant que carburant à hydrogène. Cet hydrure est formé à partir d'un composé intermétallique de formule Ca1+aLi2+b. Le Ca1+aLi2+b est formé par fusion de quantités de lithium et calcium élémentaires ensemble sous atmosphère d'argon. Le Ca1+aLi2+b est ensuite refroidi et broyé sous forme de poudre. La poudre d'alliage est ensuite hydrogénée à température ambiante ou à une température inférieure. Il en résulte un hydrure métallique d'exceptionnelle réactivité à l'eau lors de l'hydrolyse en raison de sa structure nanocristalline. La perte en hydrogène de l'hydrure métallique ne se produit pas régulièrement car l'hydrogène absorbé est lié chimiquement au lithium et au calcium. L'hydrure Ca1+aLi2+b peut être utilisé dans différentes applications en tant que carburant à hydrogène et l'alliage Ca1+aLi2+b peut être utilisé en tant que dessicant afin d'éliminer l'humidité de l'hydrogène ou de flux contenant de l'hydrogène. |
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L'invention concerne un hydrure métallique non réversible en tant que carburant à hydrogène. Cet hydrure est formé à partir d'un composé intermétallique de formule Ca1+aLi2+b. Le Ca1+aLi2+b est formé par fusion de quantités de lithium et calcium élémentaires ensemble sous atmosphère d'argon. Le Ca1+aLi2+b est ensuite refroidi et broyé sous forme de poudre. La poudre d'alliage est ensuite hydrogénée à température ambiante ou à une température inférieure. Il en résulte un hydrure métallique d'exceptionnelle réactivité à l'eau lors de l'hydrolyse en raison de sa structure nanocristalline. La perte en hydrogène de l'hydrure métallique ne se produit pas régulièrement car l'hydrogène absorbé est lié chimiquement au lithium et au calcium. L'hydrure Ca1+aLi2+b peut être utilisé dans différentes applications en tant que carburant à hydrogène et l'alliage Ca1+aLi2+b peut être utilisé en tant que dessicant afin d'éliminer l'humidité de l'hydrogène ou de flux contenant de l'hydrogène.</description><edition>7</edition><language>eng ; fre</language><subject>ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE ORUNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL ; BASIC ELECTRIC ELEMENTS ; BLASTING ; CHEMISTRY ; CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION ORPROCESSING OF GOODS ; COMPOUNDS THEREOF ; ELECTRICITY ; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED,LIQUEFIED, OR SOLIDIFIED GASES ; FIRELIGHTERS ; FIXED-CAPACITY GAS-HOLDERS ; FUELS ; FUELS NOT OTHERWISE PROVIDED FOR ; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC ; GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS ; HEATING ; INORGANIC CHEMISTRY ; LIGHTING ; LIQUEFIED PETROLEUM GAS ; LUBRICANTS ; MECHANICAL ENGINEERING ; METALLURGY ; NATURAL GAS ; NON-METALLIC ELEMENTS ; PEAT ; PETROLEUM, GAS OR COKE INDUSTRIES ; PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSIONOF CHEMICAL INTO ELECTRICAL ENERGY ; REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGYGENERATION, TRANSMISSION OR DISTRIBUTION ; STORING OF DISTRIBUTING GASES OR LIQUIDS ; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BYSUBCLASSES C10G, C10K ; TECHNICAL GASES CONTAINING CARBON MONOXIDE ; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS ; TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINSTCLIMATE CHANGE ; VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED ORSOLIDIFIED GASES ; WEAPONS</subject><creationdate>2003</creationdate><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=20030807&DB=EPODOC&CC=WO&NR=03064320A1$$EHTML$$P50$$Gepo$$Hfree_for_read</linktohtml><link.rule.ids>230,308,776,881,25544,76293</link.rule.ids><linktorsrc>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=20030807&DB=EPODOC&CC=WO&NR=03064320A1$$EView_record_in_European_Patent_Office$$FView_record_in_$$GEuropean_Patent_Office$$Hfree_for_read</linktorsrc></links><search><creatorcontrib>SAPRU, KRISHNA</creatorcontrib><creatorcontrib>TAN, ZHAOSHENG</creatorcontrib><title>HIGH CAPACITY CALCIUM LITHIUM BASED HYDROGEN STORAGE MATERIAL AND METHOD OF MAKING THE SAME</title><description>A nonreversible metal hydride for use as a hydrogen fuel. The nonreversible metal hydride is formed from an intermetallic compound having the formulaa Ca1+aLi2+b. The Ca1+aLi2+b is formed by melting amounts of elemental lithium and calcium together by induction heating in an argon atmosphere. The Ca1+aLi2+b is cooled and crushed into a powder. The alloy powder is subsequently hadrogenated at ambient temperatures or lower. Resulting is a metal hydride having exceptional reactivity to water during the hydrolysis due to its nanocrystalline structure. Dehydrogenation of the metal hydride does not regularly occur due to the absorbed hydrogen being chemically bonded to the lithium and calcium. The ca1+a Li2+b hydride may be used in a variety of applications as a hydrogen fuel and the Ca1+a Li2+b alloy may be used as a desiccant for removing moisture from hydrogen or hydrogen containing streams.
L'invention concerne un hydrure métallique non réversible en tant que carburant à hydrogène. Cet hydrure est formé à partir d'un composé intermétallique de formule Ca1+aLi2+b. Le Ca1+aLi2+b est formé par fusion de quantités de lithium et calcium élémentaires ensemble sous atmosphère d'argon. Le Ca1+aLi2+b est ensuite refroidi et broyé sous forme de poudre. La poudre d'alliage est ensuite hydrogénée à température ambiante ou à une température inférieure. Il en résulte un hydrure métallique d'exceptionnelle réactivité à l'eau lors de l'hydrolyse en raison de sa structure nanocristalline. La perte en hydrogène de l'hydrure métallique ne se produit pas régulièrement car l'hydrogène absorbé est lié chimiquement au lithium et au calcium. L'hydrure Ca1+aLi2+b peut être utilisé dans différentes applications en tant que carburant à hydrogène et l'alliage Ca1+aLi2+b peut être utilisé en tant que dessicant afin d'éliminer l'humidité de l'hydrogène ou de flux contenant de l'hydrogène.</description><subject>ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE ORUNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL</subject><subject>BASIC ELECTRIC ELEMENTS</subject><subject>BLASTING</subject><subject>CHEMISTRY</subject><subject>CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION ORPROCESSING OF GOODS</subject><subject>COMPOUNDS THEREOF</subject><subject>ELECTRICITY</subject><subject>FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED,LIQUEFIED, OR SOLIDIFIED GASES</subject><subject>FIRELIGHTERS</subject><subject>FIXED-CAPACITY GAS-HOLDERS</subject><subject>FUELS</subject><subject>FUELS NOT OTHERWISE PROVIDED FOR</subject><subject>GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC</subject><subject>GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS</subject><subject>HEATING</subject><subject>INORGANIC CHEMISTRY</subject><subject>LIGHTING</subject><subject>LIQUEFIED PETROLEUM GAS</subject><subject>LUBRICANTS</subject><subject>MECHANICAL ENGINEERING</subject><subject>METALLURGY</subject><subject>NATURAL GAS</subject><subject>NON-METALLIC ELEMENTS</subject><subject>PEAT</subject><subject>PETROLEUM, GAS OR COKE INDUSTRIES</subject><subject>PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSIONOF CHEMICAL INTO ELECTRICAL ENERGY</subject><subject>REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGYGENERATION, TRANSMISSION OR DISTRIBUTION</subject><subject>STORING OF DISTRIBUTING GASES OR LIQUIDS</subject><subject>SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BYSUBCLASSES C10G, C10K</subject><subject>TECHNICAL GASES CONTAINING CARBON MONOXIDE</subject><subject>TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS</subject><subject>TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINSTCLIMATE CHANGE</subject><subject>VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED ORSOLIDIFIED GASES</subject><subject>WEAPONS</subject><fulltext>true</fulltext><rsrctype>patent</rsrctype><creationdate>2003</creationdate><recordtype>patent</recordtype><sourceid>EVB</sourceid><recordid>eNqNikEKwjAQAHvxIOof1gcI1Yj3Ndlmg00i7RYpHkqReBIt1P9jBR_gaYZh5tmVnWXQeEbtpJ2k1K7xUDrhL49YkwFuTRUtBaglVmgJPApVDkvAYMCTcDQQiymfXLAgTFCjp2U2u_ePMa1-XGTrgkTzJg2vLo1Df0vP9O4uMVf5Ya92OW7VP88HP80xhA</recordid><startdate>20030807</startdate><enddate>20030807</enddate><creator>SAPRU, KRISHNA</creator><creator>TAN, ZHAOSHENG</creator><scope>EVB</scope></search><sort><creationdate>20030807</creationdate><title>HIGH CAPACITY CALCIUM LITHIUM BASED HYDROGEN STORAGE MATERIAL AND METHOD OF MAKING THE SAME</title><author>SAPRU, KRISHNA ; TAN, ZHAOSHENG</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-epo_espacenet_WO03064320A13</frbrgroupid><rsrctype>patents</rsrctype><prefilter>patents</prefilter><language>eng ; fre</language><creationdate>2003</creationdate><topic>ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE ORUNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL</topic><topic>BASIC ELECTRIC ELEMENTS</topic><topic>BLASTING</topic><topic>CHEMISTRY</topic><topic>CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION ORPROCESSING OF GOODS</topic><topic>COMPOUNDS THEREOF</topic><topic>ELECTRICITY</topic><topic>FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED,LIQUEFIED, OR SOLIDIFIED GASES</topic><topic>FIRELIGHTERS</topic><topic>FIXED-CAPACITY GAS-HOLDERS</topic><topic>FUELS</topic><topic>FUELS NOT OTHERWISE PROVIDED FOR</topic><topic>GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC</topic><topic>GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS</topic><topic>HEATING</topic><topic>INORGANIC CHEMISTRY</topic><topic>LIGHTING</topic><topic>LIQUEFIED PETROLEUM GAS</topic><topic>LUBRICANTS</topic><topic>MECHANICAL ENGINEERING</topic><topic>METALLURGY</topic><topic>NATURAL GAS</topic><topic>NON-METALLIC ELEMENTS</topic><topic>PEAT</topic><topic>PETROLEUM, GAS OR COKE INDUSTRIES</topic><topic>PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSIONOF CHEMICAL INTO ELECTRICAL ENERGY</topic><topic>REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGYGENERATION, TRANSMISSION OR DISTRIBUTION</topic><topic>STORING OF DISTRIBUTING GASES OR LIQUIDS</topic><topic>SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BYSUBCLASSES C10G, C10K</topic><topic>TECHNICAL GASES CONTAINING CARBON MONOXIDE</topic><topic>TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS</topic><topic>TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINSTCLIMATE CHANGE</topic><topic>VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED ORSOLIDIFIED GASES</topic><topic>WEAPONS</topic><toplevel>online_resources</toplevel><creatorcontrib>SAPRU, KRISHNA</creatorcontrib><creatorcontrib>TAN, ZHAOSHENG</creatorcontrib><collection>esp@cenet</collection></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext_linktorsrc</fulltext></delivery><addata><au>SAPRU, KRISHNA</au><au>TAN, ZHAOSHENG</au><format>patent</format><genre>patent</genre><ristype>GEN</ristype><title>HIGH CAPACITY CALCIUM LITHIUM BASED HYDROGEN STORAGE MATERIAL AND METHOD OF MAKING THE SAME</title><date>2003-08-07</date><risdate>2003</risdate><abstract>A nonreversible metal hydride for use as a hydrogen fuel. The nonreversible metal hydride is formed from an intermetallic compound having the formulaa Ca1+aLi2+b. The Ca1+aLi2+b is formed by melting amounts of elemental lithium and calcium together by induction heating in an argon atmosphere. The Ca1+aLi2+b is cooled and crushed into a powder. The alloy powder is subsequently hadrogenated at ambient temperatures or lower. Resulting is a metal hydride having exceptional reactivity to water during the hydrolysis due to its nanocrystalline structure. Dehydrogenation of the metal hydride does not regularly occur due to the absorbed hydrogen being chemically bonded to the lithium and calcium. The ca1+a Li2+b hydride may be used in a variety of applications as a hydrogen fuel and the Ca1+a Li2+b alloy may be used as a desiccant for removing moisture from hydrogen or hydrogen containing streams.
L'invention concerne un hydrure métallique non réversible en tant que carburant à hydrogène. Cet hydrure est formé à partir d'un composé intermétallique de formule Ca1+aLi2+b. Le Ca1+aLi2+b est formé par fusion de quantités de lithium et calcium élémentaires ensemble sous atmosphère d'argon. Le Ca1+aLi2+b est ensuite refroidi et broyé sous forme de poudre. La poudre d'alliage est ensuite hydrogénée à température ambiante ou à une température inférieure. Il en résulte un hydrure métallique d'exceptionnelle réactivité à l'eau lors de l'hydrolyse en raison de sa structure nanocristalline. La perte en hydrogène de l'hydrure métallique ne se produit pas régulièrement car l'hydrogène absorbé est lié chimiquement au lithium et au calcium. L'hydrure Ca1+aLi2+b peut être utilisé dans différentes applications en tant que carburant à hydrogène et l'alliage Ca1+aLi2+b peut être utilisé en tant que dessicant afin d'éliminer l'humidité de l'hydrogène ou de flux contenant de l'hydrogène.</abstract><edition>7</edition><oa>free_for_read</oa></addata></record> |
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| subjects | ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE ORUNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL BASIC ELECTRIC ELEMENTS BLASTING CHEMISTRY CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION ORPROCESSING OF GOODS COMPOUNDS THEREOF ELECTRICITY FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED,LIQUEFIED, OR SOLIDIFIED GASES FIRELIGHTERS FIXED-CAPACITY GAS-HOLDERS FUELS FUELS NOT OTHERWISE PROVIDED FOR GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS HEATING INORGANIC CHEMISTRY LIGHTING LIQUEFIED PETROLEUM GAS LUBRICANTS MECHANICAL ENGINEERING METALLURGY NATURAL GAS NON-METALLIC ELEMENTS PEAT PETROLEUM, GAS OR COKE INDUSTRIES PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSIONOF CHEMICAL INTO ELECTRICAL ENERGY REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGYGENERATION, TRANSMISSION OR DISTRIBUTION STORING OF DISTRIBUTING GASES OR LIQUIDS SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BYSUBCLASSES C10G, C10K TECHNICAL GASES CONTAINING CARBON MONOXIDE TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINSTCLIMATE CHANGE VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED ORSOLIDIFIED GASES WEAPONS |
| title | HIGH CAPACITY CALCIUM LITHIUM BASED HYDROGEN STORAGE MATERIAL AND METHOD OF MAKING THE SAME |
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