ASYMMETRIC DIVINYLSTILBENE-SULPHONIC ACIDS

The present invention relates to novel asymmetric divinylstilbene-sulphonic acids represented by the formula (I) in which X and Y are different and each represents COOR1, -CONR2R3 wherein R1, R2 and R3 each, independently, represent hydrogen, a C1-C18alkyl or a C2-C18alkenyl residue, which is unsubs...

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Hauptverfasser: ROHRINGER, PETER, HAUSER, JULIA, ELIU, VICTOR, PAUL
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creator ROHRINGER, PETER
HAUSER, JULIA
ELIU, VICTOR, PAUL
description The present invention relates to novel asymmetric divinylstilbene-sulphonic acids represented by the formula (I) in which X and Y are different and each represents COOR1, -CONR2R3 wherein R1, R2 and R3 each, independently, represent hydrogen, a C1-C18alkyl or a C2-C18alkenyl residue, which is unsubstituted or substituted by one or more hydroxy, thiol, amino, cyano, C1-C4alkoxy, -COOC1-C4alkyl or sulphone groups;-CNm, phenyl, which is unsubstituted or substituted by one or more C1-C4alkyl or C1-C4alkoxy groups, halogen, SO3M or CN; SO3M or PO3M2 and M represents H, Na, Li, K, Ca, Mg, ammonium, or ammonium that is mono-, di, tri, or tetrasubstituted by C1-C4alkyl, C2-C4hydroxyalkyl or a mixture thereof, a process for their preparation and their use as fluorescent whitening agents (FWA's) for synthetic or natural organic materials. L'invention concerne des acides divinylstilbène-sulphoniques asymétriques représentés par la formule (I), dans laquelle X et Y sont différents et représentent chacun COOR1, -CONR2R3, sachant que R1, R2 et R3 sont chacun indépendamment hydrogène, un alkyle C1-C18 ou un résidu alcényle C2-C18, non substitué ou substitué par un ou plusieurs groupes hydroxy, thiol, amino, cyano, alcoxy C1-C4, alkyle -COOC1-C4 ou sulphone; -CN, phényle, non substitué ou substitué par un ou plusieurs groupes alkyle C1-C4 ou alcoxy C1-C4, halogène, SO3M ou CN; SO3M ou PO3M2, et M représente H, Na, Li, K, Ca, Mg, ammonium, ou ammonium mono-, di, tri, ou tétra-substitué par alkyle C1-C4, hydroxyalkyle C2-C4, ou un mélange correspondant. L'invention concerne également un procédé relatif à l'élaboration de ces acides et à leur utilisation comme agents blanchissants fluorescents pour matériaux organiques de synthèse ou naturels.
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L'invention concerne des acides divinylstilbène-sulphoniques asymétriques représentés par la formule (I), dans laquelle X et Y sont différents et représentent chacun COOR1, -CONR2R3, sachant que R1, R2 et R3 sont chacun indépendamment hydrogène, un alkyle C1-C18 ou un résidu alcényle C2-C18, non substitué ou substitué par un ou plusieurs groupes hydroxy, thiol, amino, cyano, alcoxy C1-C4, alkyle -COOC1-C4 ou sulphone; -CN, phényle, non substitué ou substitué par un ou plusieurs groupes alkyle C1-C4 ou alcoxy C1-C4, halogène, SO3M ou CN; SO3M ou PO3M2, et M représente H, Na, Li, K, Ca, Mg, ammonium, ou ammonium mono-, di, tri, ou tétra-substitué par alkyle C1-C4, hydroxyalkyle C2-C4, ou un mélange correspondant. 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HAUSER, JULIA ; ELIU, VICTOR, PAUL</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-epo_espacenet_WO02055488A13</frbrgroupid><rsrctype>patents</rsrctype><prefilter>patents</prefilter><language>eng ; fre</language><creationdate>2002</creationdate><topic>ACYCLIC OR CARBOCYCLIC COMPOUNDS</topic><topic>ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM</topic><topic>ANIMAL AND VEGETABLE OILS, FATS, FATTY SUBSTANCES AND WAXES</topic><topic>BLEACHING LEATHER OR FURS</topic><topic>CANDLES</topic><topic>CHEMISTRY</topic><topic>DETERGENT COMPOSITIONS</topic><topic>DETERGENTS</topic><topic>DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS,YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS</topic><topic>FATTY ACIDS THEREFROM</topic><topic>FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR</topic><topic>IMPREGNATING OR COATING OF PAPER</topic><topic>LAUNDERING</topic><topic>METALLURGY</topic><topic>ORGANIC CHEMISTRY</topic><topic>PAPER NOT OTHERWISE PROVIDED FOR</topic><topic>PAPER-MAKING</topic><topic>PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D</topic><topic>PRODUCTION OF CELLULOSE</topic><topic>PULP COMPOSITIONS</topic><topic>RECOVERY OF GLYCEROL</topic><topic>RESIN SOAPS</topic><topic>SOAP OR SOAP-MAKING</topic><topic>TEXTILES</topic><topic>TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G</topic><topic>TREATMENT OF TEXTILES OR THE LIKE</topic><topic>USE OF SINGLE SUBSTANCES AS DETERGENTS</topic><toplevel>online_resources</toplevel><creatorcontrib>ROHRINGER, PETER</creatorcontrib><creatorcontrib>HAUSER, JULIA</creatorcontrib><creatorcontrib>ELIU, VICTOR, PAUL</creatorcontrib><collection>esp@cenet</collection></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext_linktorsrc</fulltext></delivery><addata><au>ROHRINGER, PETER</au><au>HAUSER, JULIA</au><au>ELIU, VICTOR, PAUL</au><format>patent</format><genre>patent</genre><ristype>GEN</ristype><title>ASYMMETRIC DIVINYLSTILBENE-SULPHONIC ACIDS</title><date>2002-07-18</date><risdate>2002</risdate><abstract>The present invention relates to novel asymmetric divinylstilbene-sulphonic acids represented by the formula (I) in which X and Y are different and each represents COOR1, -CONR2R3 wherein R1, R2 and R3 each, independently, represent hydrogen, a C1-C18alkyl or a C2-C18alkenyl residue, which is unsubstituted or substituted by one or more hydroxy, thiol, amino, cyano, C1-C4alkoxy, -COOC1-C4alkyl or sulphone groups;-CNm, phenyl, which is unsubstituted or substituted by one or more C1-C4alkyl or C1-C4alkoxy groups, halogen, SO3M or CN; SO3M or PO3M2 and M represents H, Na, Li, K, Ca, Mg, ammonium, or ammonium that is mono-, di, tri, or tetrasubstituted by C1-C4alkyl, C2-C4hydroxyalkyl or a mixture thereof, a process for their preparation and their use as fluorescent whitening agents (FWA's) for synthetic or natural organic materials. L'invention concerne des acides divinylstilbène-sulphoniques asymétriques représentés par la formule (I), dans laquelle X et Y sont différents et représentent chacun COOR1, -CONR2R3, sachant que R1, R2 et R3 sont chacun indépendamment hydrogène, un alkyle C1-C18 ou un résidu alcényle C2-C18, non substitué ou substitué par un ou plusieurs groupes hydroxy, thiol, amino, cyano, alcoxy C1-C4, alkyle -COOC1-C4 ou sulphone; -CN, phényle, non substitué ou substitué par un ou plusieurs groupes alkyle C1-C4 ou alcoxy C1-C4, halogène, SO3M ou CN; SO3M ou PO3M2, et M représente H, Na, Li, K, Ca, Mg, ammonium, ou ammonium mono-, di, tri, ou tétra-substitué par alkyle C1-C4, hydroxyalkyle C2-C4, ou un mélange correspondant. L'invention concerne également un procédé relatif à l'élaboration de ces acides et à leur utilisation comme agents blanchissants fluorescents pour matériaux organiques de synthèse ou naturels.</abstract><edition>7</edition><oa>free_for_read</oa></addata></record>
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subjects ACYCLIC OR CARBOCYCLIC COMPOUNDS
ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM
ANIMAL AND VEGETABLE OILS, FATS, FATTY SUBSTANCES AND WAXES
BLEACHING LEATHER OR FURS
CANDLES
CHEMISTRY
DETERGENT COMPOSITIONS
DETERGENTS
DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS,YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS
FATTY ACIDS THEREFROM
FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
IMPREGNATING OR COATING OF PAPER
LAUNDERING
METALLURGY
ORGANIC CHEMISTRY
PAPER NOT OTHERWISE PROVIDED FOR
PAPER-MAKING
PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D
PRODUCTION OF CELLULOSE
PULP COMPOSITIONS
RECOVERY OF GLYCEROL
RESIN SOAPS
SOAP OR SOAP-MAKING
TEXTILES
TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G
TREATMENT OF TEXTILES OR THE LIKE
USE OF SINGLE SUBSTANCES AS DETERGENTS
title ASYMMETRIC DIVINYLSTILBENE-SULPHONIC ACIDS
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