Conversion of alcohols to distillate fuels

A process for the production of jet and other heavy fuels from alcohols and mixture of alcohols is disclosed. The process may include contacting in a reaction zone at least one C2 to C11 alcohol with a solid catalyst having activity for the simultaneous dehydration of the alcohols to form olefins, i...

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Hauptverfasser: Greene Marvin I, Judzis, Jr. Arvids, Song Ruozhi
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creator Greene Marvin I
Judzis, Jr. Arvids
Song Ruozhi
description A process for the production of jet and other heavy fuels from alcohols and mixture of alcohols is disclosed. The process may include contacting in a reaction zone at least one C2 to C11 alcohol with a solid catalyst having activity for the simultaneous dehydration of the alcohols to form olefins, isomerization of the olefins to form internal olefins, and oligomerization of the olefins produced in situ via the dehydration reaction to form an effluent comprising mono-olefinic hydrocarbons. Preferably, the alcohol feed is a mixture of alcohols, such as C2 to C7 alcohols or C4 and C6 alcohols, enabling the production of a mixture of branched hydrocarbons that may be used directly as a jet fuel without blending.
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The process may include contacting in a reaction zone at least one C2 to C11 alcohol with a solid catalyst having activity for the simultaneous dehydration of the alcohols to form olefins, isomerization of the olefins to form internal olefins, and oligomerization of the olefins produced in situ via the dehydration reaction to form an effluent comprising mono-olefinic hydrocarbons. 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subjects ACYCLIC OR CARBOCYCLIC COMPOUNDS
ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE ORUNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL
CHEMISTRY
CRACKING HYDROCARBON OILS
FIRELIGHTERS
FUELS
FUELS NOT OTHERWISE PROVIDED FOR
LIQUEFIED PETROLEUM GAS
LUBRICANTS
METALLURGY
MINERAL WAXES
NATURAL GAS
ORGANIC CHEMISTRY
PEAT
PETROLEUM, GAS OR COKE INDUSTRIES
PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVEHYDROGENATION, OLIGOMERISATION, POLYMERISATION
RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, ORGASES
REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS
REFORMING OF NAPHTHA
SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BYSUBCLASSES C10G, C10K
TECHNICAL GASES CONTAINING CARBON MONOXIDE
title Conversion of alcohols to distillate fuels
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