Additives for boron rejection enhancement of a membrane

Provided is an interfacial polymerization process for preparation of a highly permeable thin film composite membrane, which can be used for nanofiltration, forward osmosis, or reverse osmosis, particularly for use with brackish water or seawater. The process includes contacting a porous support memb...

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Hauptverfasser: Anderson Holmberg Brett, Goenaga Alberto, Ford Andrew, Choi Hyungsam, Sankhe Amit, Kurth Christopher, Eom Youngsik, Lee Jin Kuk, Choi Sung Yeol, Koehler Jeff, Burk Robert
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creator Anderson Holmberg Brett
Goenaga Alberto
Ford Andrew
Choi Hyungsam
Sankhe Amit
Kurth Christopher
Eom Youngsik
Lee Jin Kuk
Choi Sung Yeol
Koehler Jeff
Burk Robert
description Provided is an interfacial polymerization process for preparation of a highly permeable thin film composite membrane, which can be used for nanofiltration, forward osmosis, or reverse osmosis, particularly for use with brackish water or seawater. The process includes contacting a porous support membrane with an aqueous phase containing a polyamine to form a coated support membrane, and applying an organic phase containing a polyfunctional acid halide to the coated support membrane to interfacially polymerize the polyamine and the polyfunctional acid halide to form a discrimination layer of a thin film composite membrane, where the aqueous and/or organic phases include a flux-enhancing additive and a boron rejection-enhancing additive that includes a biguanide compound, dicarbonate compound, pentathiodicarbonate compound, or salts thereof. Also provided are the membranes prepared by the methods and reverse osmosis modules containing the membranes.
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PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
SEPARATION
TRANSPORTING
title Additives for boron rejection enhancement of a membrane
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