Process for making polyol neoalkylester plasticizers from neo acids

Provided are compositions, processes for making, and processes for using neoalkyl polyol esters and triglycerides as plasticizers. In one form, a neoalkylester triglyceride plasticizers can be produced by (i) drying a polyol feedstream; (ii) contacting in a reactor the dried polyol feedstream with a...

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Hauptverfasser: JAMES PETER STOKES, COLLE KARLA SCHALL, BECK CARL ROBERT, STANAT JON EDMOND RANDOLPH, GODWIN ALLEN DAVID, BENITEZ FRANCISCO MANUEL, MOZELESKI EDMUND JOHN, DAKKA JIHAD MOHAMMED, BAUGH LISA SAUNDERS
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creator JAMES PETER STOKES
COLLE KARLA SCHALL
BECK CARL ROBERT
STANAT JON EDMOND RANDOLPH
GODWIN ALLEN DAVID
BENITEZ FRANCISCO MANUEL
MOZELESKI EDMUND JOHN
DAKKA JIHAD MOHAMMED
BAUGH LISA SAUNDERS
description Provided are compositions, processes for making, and processes for using neoalkyl polyol esters and triglycerides as plasticizers. In one form, a neoalkylester triglyceride plasticizers can be produced by (i) drying a polyol feedstream; (ii) contacting in a reactor the dried polyol feedstream with a neoacid feedstream under effective temperature, pressure and time to form a neoalkylester plasticizer effluent stream, and (iii) purifying the neoalkylester plasticizer effluent stream to remove unreacted polyol and unreacted neoacid to form a neoalkylester plasticizer. Such plasticizers can be phthalate-free and provide outstanding properties including a suitable melting or pour point, glass transition temperature, low volatility, increased compatibility, increased hydrolytic stability, and excellent low temperature properties in a range of polymeric resins.
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subjects CHEMISTRY
COMPOSITIONS BASED THEREON
LAYERED PRODUCTS
LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT ORNON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
METALLURGY
ORGANIC MACROMOLECULAR COMPOUNDS
PERFORMING OPERATIONS
THEIR PREPARATION OR CHEMICAL WORKING-UP
TRANSPORTING
USE OF INORGANIC OR NON-MACROMOLECULAR ORGANIC SUBSTANCES ASCOMPOUNDING INGREDIENTS
title Process for making polyol neoalkylester plasticizers from neo acids
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