Double loop technology

A method for the copolymerization of ethylene and a C3+ olefin copolymer in a loop reactor system and polymers formed therefrom are described herein. The method generally includes introducing an ethylene monomer, a C3+ alpha olefin comonomer and a diluent carrier liquid into a reactor system compris...

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Hauptverfasser: SIRAUX DANIEL, VAN CAMP CARL, SILLIS MARJAN, VAN DER AUWERA MARC, VANDAELE HUGO, VERLEYSEN MARK, FOUARGE LOUIS, FOLIE PASCAL, BODART PHILIPPE, MARECHAL PHILIPPE, OREINS RENAUD, D'HOOGHE LEOPOLD, LEWALLE ANDRE, DAMME ERIC, CONTI GIACOMO, LAURENT ETIENNE, MISERQUE OLIVIER, HORTMAN KAI, MOERS MARC, VAN DEN BRANDE FRANS
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creator SIRAUX DANIEL
VAN CAMP CARL
SILLIS MARJAN
VAN DER AUWERA MARC
VANDAELE HUGO
VERLEYSEN MARK
FOUARGE LOUIS
FOLIE PASCAL
BODART PHILIPPE
MARECHAL PHILIPPE
OREINS RENAUD
D'HOOGHE LEOPOLD
LEWALLE ANDRE
DAMME ERIC
CONTI GIACOMO
LAURENT ETIENNE
MISERQUE OLIVIER
HORTMAN KAI
MOERS MARC
VAN DEN BRANDE FRANS
description A method for the copolymerization of ethylene and a C3+ olefin copolymer in a loop reactor system and polymers formed therefrom are described herein. The method generally includes introducing an ethylene monomer, a C3+ alpha olefin comonomer and a diluent carrier liquid into a reactor system comprising at least one loop reactor; supplying at least one polymerization catalyst system to said reactor system; circulating said diluent liquid, ethylene monomer, and alpha olefin copolymer through said loop reactor while copolymerizing said ethylene and said alpha olefin monomer in the presence of said catalyst system to produce a slurry of polymer fluff particles in said diluent carrier liquid; diverting the flow of said slurry through said loop reactor into at least one settling leg connected to the loop reactor and sequentially discharging the settled polymer slurry from said at least one settling leg to withdraw said polymer slurry from said reactor system; and introducing an ethylene monomer co-feed into said loop reactor at least two spaced locations downstream of the point of introduction of ethylene comonomer and diluent in subparagraph a), said ethylene co-feed being introduced in an amount effective to reduce the variation in the ratio of ethylene monomer and comonomer within said loop reactor.
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The method generally includes introducing an ethylene monomer, a C3+ alpha olefin comonomer and a diluent carrier liquid into a reactor system comprising at least one loop reactor; supplying at least one polymerization catalyst system to said reactor system; circulating said diluent liquid, ethylene monomer, and alpha olefin copolymer through said loop reactor while copolymerizing said ethylene and said alpha olefin monomer in the presence of said catalyst system to produce a slurry of polymer fluff particles in said diluent carrier liquid; diverting the flow of said slurry through said loop reactor into at least one settling leg connected to the loop reactor and sequentially discharging the settled polymer slurry from said at least one settling leg to withdraw said polymer slurry from said reactor system; and introducing an ethylene monomer co-feed into said loop reactor at least two spaced locations downstream of the point of introduction of ethylene comonomer and diluent in subparagraph a), said ethylene co-feed being introduced in an amount effective to reduce the variation in the ratio of ethylene monomer and comonomer within said loop reactor.</abstract><oa>free_for_read</oa></addata></record>
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subjects CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY
CHEMISTRY
COMPOSITIONS BASED THEREON
MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS
METALLURGY
ORGANIC MACROMOLECULAR COMPOUNDS
PERFORMING OPERATIONS
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
THEIR PREPARATION OR CHEMICAL WORKING-UP
THEIR RELEVANT APPARATUS
TRANSPORTING
title Double loop technology
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