Catalyst complex and process for producing multimodal molecular weight polyolefins

Multinuclear catalyst complex comprising two or more active metal centers and at least one phenoxyimine derivative and at least one substituted cyclopentadienyl, indenyl or fluorenyl derivative, each phenoxyimine derivative being bonded to a cyclopentadienyl, indenyl or fluorenyl derivative forming...

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Hauptverfasser: ALT HELMUT G, PALACKAL SYRIAC, GOERL CHRISTIAN, ABURAQABAH ATIEH
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creator ALT HELMUT G
PALACKAL SYRIAC
GOERL CHRISTIAN
ABURAQABAH ATIEH
description Multinuclear catalyst complex comprising two or more active metal centers and at least one phenoxyimine derivative and at least one substituted cyclopentadienyl, indenyl or fluorenyl derivative, each phenoxyimine derivative being bonded to a cyclopentadienyl, indenyl or fluorenyl derivative forming a ligand framework, the cyclopentadienyl, indenyl or fluorenyl derivative being coordinated with one of the metal centers and the phenoxyimine derivative being coordinated with an active metal center other than the metal center the cyclopentadienyl, indenyl or fluorenyl derivative is coordinated with, and wherein the phenoxyimine derivative is derived from a phenoxyimine compound of the formula wherein R1 is hydrogen, alkyl, cycloalkyl, aryl or aralkyl; R2 is hydrogen, halogen, alkyl, cycloalkyl, aryl, O-alkyl or aralkyl; and R3 is alkyl, cycloalkyl, aryl or aralkyl, process for preparing a multinuclear catalyst composition comprising the steps of bonding the substituted phenoxyimine compound to a substituted cyclopentadienyl, indenyl or fluorenyl derivative to obtain a ligand framework and reacting at least one ligand framework with an active metal component and process for the polymerization of olefins, in particular of ethylene and optionally one or more other a-olefins, wherein said multinuclear catalyst is applied.
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R2 is hydrogen, halogen, alkyl, cycloalkyl, aryl, O-alkyl or aralkyl; and R3 is alkyl, cycloalkyl, aryl or aralkyl, process for preparing a multinuclear catalyst composition comprising the steps of bonding the substituted phenoxyimine compound to a substituted cyclopentadienyl, indenyl or fluorenyl derivative to obtain a ligand framework and reacting at least one ligand framework with an active metal component and process for the polymerization of olefins, in particular of ethylene and optionally one or more other a-olefins, wherein said multinuclear catalyst is applied.</abstract><oa>free_for_read</oa></addata></record>
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subjects ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY
CHEMISTRY
COMPOSITIONS BASED THEREON
MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS
METALLURGY
ORGANIC CHEMISTRY
ORGANIC MACROMOLECULAR COMPOUNDS
PERFORMING OPERATIONS
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
THEIR PREPARATION OR CHEMICAL WORKING-UP
THEIR RELEVANT APPARATUS
TRANSPORTING
title Catalyst complex and process for producing multimodal molecular weight polyolefins
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