Reverse ALD

A semiconductor process and apparatus includes forming first and second gate electrodes (151, 161) by forming the first gate electrode (151) over a first high-k gate dielectric (121) and forming the second gate electrode (161) over at least a second high-k gate dielectric (122) different from the fi...

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Hauptverfasser: ADETUTU OLUBUNMI O, TRIYOSO DINA H
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creator ADETUTU OLUBUNMI O
TRIYOSO DINA H
description A semiconductor process and apparatus includes forming first and second gate electrodes (151, 161) by forming the first gate electrode (151) over a first high-k gate dielectric (121) and forming the second gate electrode (161) over at least a second high-k gate dielectric (122) different from the first gate dielectric (121). Either or both of the high-k gate dielectric layers (121, 122) may be formed by depositing and selectively etching an initial layer of high-k dielectric material (e.g., 14). As deposited, the initial layer (14) has an exposed surface (18) and an initial predetermined crystalline structure. An exposed thin surface layer (20) of the initial layer (14) is prepared for etching by modifying the initial crystalline structure in the exposed thin surface layer. The modified crystalline structure in the exposed thin surface layer may be removed by applying a selective etch, such as HF or HCl.
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Either or both of the high-k gate dielectric layers (121, 122) may be formed by depositing and selectively etching an initial layer of high-k dielectric material (e.g., 14). As deposited, the initial layer (14) has an exposed surface (18) and an initial predetermined crystalline structure. An exposed thin surface layer (20) of the initial layer (14) is prepared for etching by modifying the initial crystalline structure in the exposed thin surface layer. 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Either or both of the high-k gate dielectric layers (121, 122) may be formed by depositing and selectively etching an initial layer of high-k dielectric material (e.g., 14). As deposited, the initial layer (14) has an exposed surface (18) and an initial predetermined crystalline structure. An exposed thin surface layer (20) of the initial layer (14) is prepared for etching by modifying the initial crystalline structure in the exposed thin surface layer. 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Either or both of the high-k gate dielectric layers (121, 122) may be formed by depositing and selectively etching an initial layer of high-k dielectric material (e.g., 14). As deposited, the initial layer (14) has an exposed surface (18) and an initial predetermined crystalline structure. An exposed thin surface layer (20) of the initial layer (14) is prepared for etching by modifying the initial crystalline structure in the exposed thin surface layer. The modified crystalline structure in the exposed thin surface layer may be removed by applying a selective etch, such as HF or HCl.</abstract><oa>free_for_read</oa></addata></record>
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subjects BASIC ELECTRIC ELEMENTS
CHEMICAL SURFACE TREATMENT
CHEMISTRY
COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATIONOR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
COATING MATERIAL WITH METALLIC MATERIAL
COATING METALLIC MATERIAL
DECORATIVE ARTS
DIFFUSION TREATMENT OF METALLIC MATERIAL
ELECTRIC SOLID STATE DEVICES NOT OTHERWISE PROVIDED FOR
ELECTRICITY
INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION INGENERAL
METALLURGY
MOSAICS
MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLICMATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASSC23 AND AT LEAST ONEPROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE
PAPERHANGING
PERFORMING OPERATIONS
PRODUCING DECORATIVE EFFECTS
SEMICONDUCTOR DEVICES
TARSIA WORK
TRANSPORTING
title Reverse ALD
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