Bridged polysesquioxane host matrices containing lanthanides chelated by organic guest ligands, and methods of making such matrices

Bridged polysesquioxane compositions comprising: a bridged polysesquioxane host matrix comprising sesquioxane moieties and organic moieties, the sesquioxane moieties comprising a metallic element, the organic moieties interposed between sesquioxane moieties; and a guest molecule comprising a lanthan...

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description Bridged polysesquioxane compositions comprising: a bridged polysesquioxane host matrix comprising sesquioxane moieties and organic moieties, the sesquioxane moieties comprising a metallic element, the organic moieties interposed between sesquioxane moieties; and a guest molecule comprising a lanthanide atom; at least some of the organic moieties comprising a substituent selected from the group consisting of electron withdrawing functional groups and electron donating functional groups. Processes for making such bridged polysesquioxane compositions. Gain media and active materials for upconversion lasers comprising such bridged polysesquioxane compositions. Light can be amplified by fluorescence emissions from the bridged polysesquioxane compositions.
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subjects ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM
BASIC ELECTRIC ELEMENTS
CHEMISTRY
COMPOSITIONS BASED THEREON
COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
DEVICES USING STIMULATED EMISSION
ELECTRICITY
MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONSONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
METALLURGY
ORGANIC CHEMISTRY
ORGANIC MACROMOLECULAR COMPOUNDS
THEIR PREPARATION OR CHEMICAL WORKING-UP
USE OF INORGANIC OR NON-MACROMOLECULAR ORGANIC SUBSTANCES ASCOMPOUNDING INGREDIENTS
title Bridged polysesquioxane host matrices containing lanthanides chelated by organic guest ligands, and methods of making such matrices
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