Electrochemically active material for the positive electrode of an electrochemically rechargeable lithium cell

An electrochemically active material resulting from substituting a portion of the nickel in a single-phase composite oxide of nickel and lithium of the LiNiO2 type, characterized in that the active material satisfies the formula: Li(M1(1-a-b-c)LiaM2bM3c)O2 in which: 0.02

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Hauptverfasser: BOEUVE JEAN-PIERRE, AUDRY CLAUDETTE, BIENSAN PHILIPPE, JORDY CHRISTIAN, LECERF ANDRE
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creator BOEUVE JEAN-PIERRE
AUDRY CLAUDETTE
BIENSAN PHILIPPE
JORDY CHRISTIAN
LECERF ANDRE
description An electrochemically active material resulting from substituting a portion of the nickel in a single-phase composite oxide of nickel and lithium of the LiNiO2 type, characterized in that the active material satisfies the formula: Li(M1(1-a-b-c)LiaM2bM3c)O2 in which: 0.02
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0<=b<0.30; 0<=c<0.30; (a+b+c)<0.50; M3 is at least one element selected from Al, B, and Ga; M2 is at least one element selected from Mg and Zn; and M1=Ni(1-x-y-z)CoxMnyM4z in which M4 is at least one element selected from Fe, Cu, Ti, Zr, V, Ga, and Si; and 0<=x<0.70; 0.10<=y<0.55; 0<=z<0.30; and 0.20<(1-x-y-z); b+c+z>0; and in that said active material, regardless of its state of charge, satisfies the relationship: 0.40<R<0.90, where: R=(1-a-b-c)*[3-[(nU/nMA+dox)/(4-2b-3c)]*(2-b-2c)] in which: nU is the lithium content expressed in moles; nMA is the sum of the contents of Ni, Mn, Co, and M4 expressed in moles; and dox is the overall degree of oxidation of M1.]]></description><language>eng</language><subject>BASIC ELECTRIC ELEMENTS ; CHEMISTRY ; COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSESC01D OR C01F ; ELECTRICITY ; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC ; GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS ; INORGANIC CHEMISTRY ; 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AUDRY CLAUDETTE ; BIENSAN PHILIPPE ; JORDY CHRISTIAN ; LECERF ANDRE</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-epo_espacenet_US7285357B23</frbrgroupid><rsrctype>patents</rsrctype><prefilter>patents</prefilter><language>eng</language><creationdate>2007</creationdate><topic>BASIC ELECTRIC ELEMENTS</topic><topic>CHEMISTRY</topic><topic>COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSESC01D OR C01F</topic><topic>ELECTRICITY</topic><topic>GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC</topic><topic>GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS</topic><topic>INORGANIC CHEMISTRY</topic><topic>METALLURGY</topic><topic>PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSIONOF CHEMICAL INTO ELECTRICAL ENERGY</topic><topic>REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGYGENERATION, TRANSMISSION OR DISTRIBUTION</topic><topic>TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS</topic><topic>TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINSTCLIMATE CHANGE</topic><toplevel>online_resources</toplevel><creatorcontrib>BOEUVE JEAN-PIERRE</creatorcontrib><creatorcontrib>AUDRY CLAUDETTE</creatorcontrib><creatorcontrib>BIENSAN PHILIPPE</creatorcontrib><creatorcontrib>JORDY CHRISTIAN</creatorcontrib><creatorcontrib>LECERF ANDRE</creatorcontrib><collection>esp@cenet</collection></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext_linktorsrc</fulltext></delivery><addata><au>BOEUVE JEAN-PIERRE</au><au>AUDRY CLAUDETTE</au><au>BIENSAN PHILIPPE</au><au>JORDY CHRISTIAN</au><au>LECERF ANDRE</au><format>patent</format><genre>patent</genre><ristype>GEN</ristype><title>Electrochemically active material for the positive electrode of an electrochemically rechargeable lithium cell</title><date>2007-10-23</date><risdate>2007</risdate><abstract><![CDATA[An electrochemically active material resulting from substituting a portion of the nickel in a single-phase composite oxide of nickel and lithium of the LiNiO2 type, characterized in that the active material satisfies the formula: Li(M1(1-a-b-c)LiaM2bM3c)O2 in which: 0.02<a<=0.25; 0<=b<0.30; 0<=c<0.30; (a+b+c)<0.50; M3 is at least one element selected from Al, B, and Ga; M2 is at least one element selected from Mg and Zn; and M1=Ni(1-x-y-z)CoxMnyM4z in which M4 is at least one element selected from Fe, Cu, Ti, Zr, V, Ga, and Si; and 0<=x<0.70; 0.10<=y<0.55; 0<=z<0.30; and 0.20<(1-x-y-z); b+c+z>0; and in that said active material, regardless of its state of charge, satisfies the relationship: 0.40<R<0.90, where: R=(1-a-b-c)*[3-[(nU/nMA+dox)/(4-2b-3c)]*(2-b-2c)] in which: nU is the lithium content expressed in moles; nMA is the sum of the contents of Ni, Mn, Co, and M4 expressed in moles; and dox is the overall degree of oxidation of M1.]]></abstract><oa>free_for_read</oa></addata></record>
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subjects BASIC ELECTRIC ELEMENTS
CHEMISTRY
COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSESC01D OR C01F
ELECTRICITY
GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS
INORGANIC CHEMISTRY
METALLURGY
PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSIONOF CHEMICAL INTO ELECTRICAL ENERGY
REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGYGENERATION, TRANSMISSION OR DISTRIBUTION
TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINSTCLIMATE CHANGE
title Electrochemically active material for the positive electrode of an electrochemically rechargeable lithium cell
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