Production of low sulfur syngas from natural gas with C4+/C5+ hydrocarbon recovery
Sour natural gas is processed to remove the sulfur compounds and recover C4+/C5+ hydrocarbons by scrubbing the gas with an amine solution to remove most of the sulfur, followed cooling the gas to remove C4+/C5+ hydrocarbons and more sulfur compounds as liquid condensate to produce a gas having less...
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creator | FEDICH ROBERT B O'CONNOR RICHARD P ALEXION DENNIS G GLASS, JR. JAMES P TAYLOR, JR. JAMES H SAY GEOFFREY R WILBUR JOHN C |
description | Sour natural gas is processed to remove the sulfur compounds and recover C4+/C5+ hydrocarbons by scrubbing the gas with an amine solution to remove most of the sulfur, followed cooling the gas to remove C4+/C5+ hydrocarbons and more sulfur compounds as liquid condensate to produce a gas having less than 20 vppm of total sulfur. The condensate is sent to a fractionator to recover the C4+/C5+ hydrocarbons. The sulfur and hydrocarbon reduced gas is contacted first with zinc oxide and then nickel, to produce a gas having less than 10 vppb of total sulfur which is passed into a synthesis gas generating unit to form a very low sulfur synthesis gas comprising a mixture of H2 and CO. This synthesis gas is useful for hydrocarbon synthesis with increased life of the hydrocarbon synthesis catalyst and greater hydrocarbon production from the hydrocarbon synthesis reactor. Contacting the synthesis gas with zinc oxide further reduces the sulfur content to below 3 vppb. |
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JAMES P ; TAYLOR, JR. JAMES H ; SAY GEOFFREY R ; WILBUR JOHN C</creatorcontrib><description>Sour natural gas is processed to remove the sulfur compounds and recover C4+/C5+ hydrocarbons by scrubbing the gas with an amine solution to remove most of the sulfur, followed cooling the gas to remove C4+/C5+ hydrocarbons and more sulfur compounds as liquid condensate to produce a gas having less than 20 vppm of total sulfur. The condensate is sent to a fractionator to recover the C4+/C5+ hydrocarbons. The sulfur and hydrocarbon reduced gas is contacted first with zinc oxide and then nickel, to produce a gas having less than 10 vppb of total sulfur which is passed into a synthesis gas generating unit to form a very low sulfur synthesis gas comprising a mixture of H2 and CO. This synthesis gas is useful for hydrocarbon synthesis with increased life of the hydrocarbon synthesis catalyst and greater hydrocarbon production from the hydrocarbon synthesis reactor. Contacting the synthesis gas with zinc oxide further reduces the sulfur content to below 3 vppb.</description><edition>7</edition><language>eng</language><subject>ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE ORUNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL ; CHEMISTRY ; FIRELIGHTERS ; FUELS ; FUELS NOT OTHERWISE PROVIDED FOR ; LIQUEFIED PETROLEUM GAS ; LUBRICANTS ; METALLURGY ; NATURAL GAS ; PEAT ; PERFORMING OPERATIONS ; PETROLEUM, GAS OR COKE INDUSTRIES ; PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL ; SEPARATION ; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BYSUBCLASSES C10G, C10K ; TECHNICAL GASES CONTAINING CARBON MONOXIDE ; TRANSPORTING</subject><creationdate>2004</creationdate><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=20040217&DB=EPODOC&CC=US&NR=6692711B1$$EHTML$$P50$$Gepo$$Hfree_for_read</linktohtml><link.rule.ids>230,308,780,885,25564,76547</link.rule.ids><linktorsrc>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=20040217&DB=EPODOC&CC=US&NR=6692711B1$$EView_record_in_European_Patent_Office$$FView_record_in_$$GEuropean_Patent_Office$$Hfree_for_read</linktorsrc></links><search><creatorcontrib>FEDICH ROBERT B</creatorcontrib><creatorcontrib>O'CONNOR RICHARD P</creatorcontrib><creatorcontrib>ALEXION DENNIS G</creatorcontrib><creatorcontrib>GLASS, JR. 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JAMES H</au><au>SAY GEOFFREY R</au><au>WILBUR JOHN C</au><format>patent</format><genre>patent</genre><ristype>GEN</ristype><title>Production of low sulfur syngas from natural gas with C4+/C5+ hydrocarbon recovery</title><date>2004-02-17</date><risdate>2004</risdate><abstract>Sour natural gas is processed to remove the sulfur compounds and recover C4+/C5+ hydrocarbons by scrubbing the gas with an amine solution to remove most of the sulfur, followed cooling the gas to remove C4+/C5+ hydrocarbons and more sulfur compounds as liquid condensate to produce a gas having less than 20 vppm of total sulfur. The condensate is sent to a fractionator to recover the C4+/C5+ hydrocarbons. The sulfur and hydrocarbon reduced gas is contacted first with zinc oxide and then nickel, to produce a gas having less than 10 vppb of total sulfur which is passed into a synthesis gas generating unit to form a very low sulfur synthesis gas comprising a mixture of H2 and CO. This synthesis gas is useful for hydrocarbon synthesis with increased life of the hydrocarbon synthesis catalyst and greater hydrocarbon production from the hydrocarbon synthesis reactor. Contacting the synthesis gas with zinc oxide further reduces the sulfur content to below 3 vppb.</abstract><edition>7</edition><oa>free_for_read</oa></addata></record> |
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subjects | ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE ORUNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL CHEMISTRY FIRELIGHTERS FUELS FUELS NOT OTHERWISE PROVIDED FOR LIQUEFIED PETROLEUM GAS LUBRICANTS METALLURGY NATURAL GAS PEAT PERFORMING OPERATIONS PETROLEUM, GAS OR COKE INDUSTRIES PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL SEPARATION SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BYSUBCLASSES C10G, C10K TECHNICAL GASES CONTAINING CARBON MONOXIDE TRANSPORTING |
title | Production of low sulfur syngas from natural gas with C4+/C5+ hydrocarbon recovery |
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