Battery separator

A method for producing a battery separator is disclosed. The method comprises applying a coating of an ethylenically unsaturated monomer to the fibers of a non-woven sheet and polymerizing the monomer in situ on the fiber surfaces. The non-woven sheet is from 50 to 3000 microns thick, and is compose...

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description A method for producing a battery separator is disclosed. The method comprises applying a coating of an ethylenically unsaturated monomer to the fibers of a non-woven sheet and polymerizing the monomer in situ on the fiber surfaces. The non-woven sheet is from 50 to 3000 microns thick, and is composed of polyolefin fibers having an average fiber diameter from 0.5 to 5 microns and a surface area from 0.2 to 30 square meters per gram. The ethylenically unsaturated monomer is polymerizable to a thermoplastic polymer which is hydrophilic as a consequence of containing COOH, OH, sulfonyl, sulfonic acid or carbonyl groups, or a monomer which has one of the following formulas:In the foregoing formulas, R is an aliphatic or aromatic hydrocarbon group having from 2 to 8 carbon atoms, R4 is hydrogen or methyl, n is an integer from 2 to 15, and Xis a cation selected from the group consisting of hydrogen, alkali metal cations, alkaline earth cations, cations of the transition metals Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu and Zn, and ammonium cations of the following formula:each of R5R6, R7 and R8 is hydrogen, alkyl, alkenyl, cycloalkyl or cycloaklkenylene, and not more than one is a bivalent group bonded to Nand by removing two hydrogens from an alkane, an alkene, a cycloalkane or a cycloalkene; the total number of carbons in R5 R6, R7 and R8 does not exceed 21.
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The non-woven sheet is from 50 to 3000 microns thick, and is composed of polyolefin fibers having an average fiber diameter from 0.5 to 5 microns and a surface area from 0.2 to 30 square meters per gram. 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The method comprises applying a coating of an ethylenically unsaturated monomer to the fibers of a non-woven sheet and polymerizing the monomer in situ on the fiber surfaces. The non-woven sheet is from 50 to 3000 microns thick, and is composed of polyolefin fibers having an average fiber diameter from 0.5 to 5 microns and a surface area from 0.2 to 30 square meters per gram. The ethylenically unsaturated monomer is polymerizable to a thermoplastic polymer which is hydrophilic as a consequence of containing COOH, OH, sulfonyl, sulfonic acid or carbonyl groups, or a monomer which has one of the following formulas:In the foregoing formulas, R is an aliphatic or aromatic hydrocarbon group having from 2 to 8 carbon atoms, R4 is hydrogen or methyl, n is an integer from 2 to 15, and X&lt;+ &gt;is a cation selected from the group consisting of hydrogen, alkali metal cations, alkaline earth cations, cations of the transition metals Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu and Zn, and ammonium cations of the following formula:each of R5R6, R7 and R8 is hydrogen, alkyl, alkenyl, cycloalkyl or cycloaklkenylene, and not more than one is a bivalent group bonded to N&lt;+ &gt;and by removing two hydrogens from an alkane, an alkene, a cycloalkane or a cycloalkene; the total number of carbons in R5 R6, R7 and R8 does not exceed 21.</description><subject>AFTER-TREATMENT NOT 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M</creatorcontrib><collection>esp@cenet</collection></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext_linktorsrc</fulltext></delivery><addata><au>CHOI WAI M</au><format>patent</format><genre>patent</genre><ristype>GEN</ristype><title>Battery separator</title><date>2004-01-20</date><risdate>2004</risdate><abstract>A method for producing a battery separator is disclosed. The method comprises applying a coating of an ethylenically unsaturated monomer to the fibers of a non-woven sheet and polymerizing the monomer in situ on the fiber surfaces. The non-woven sheet is from 50 to 3000 microns thick, and is composed of polyolefin fibers having an average fiber diameter from 0.5 to 5 microns and a surface area from 0.2 to 30 square meters per gram. The ethylenically unsaturated monomer is polymerizable to a thermoplastic polymer which is hydrophilic as a consequence of containing COOH, OH, sulfonyl, sulfonic acid or carbonyl groups, or a monomer which has one of the following formulas:In the foregoing formulas, R is an aliphatic or aromatic hydrocarbon group having from 2 to 8 carbon atoms, R4 is hydrogen or methyl, n is an integer from 2 to 15, and X&lt;+ &gt;is a cation selected from the group consisting of hydrogen, alkali metal cations, alkaline earth cations, cations of the transition metals Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu and Zn, and ammonium cations of the following formula:each of R5R6, R7 and R8 is hydrogen, alkyl, alkenyl, cycloalkyl or cycloaklkenylene, and not more than one is a bivalent group bonded to N&lt;+ &gt;and by removing two hydrogens from an alkane, an alkene, a cycloalkane or a cycloalkene; the total number of carbons in R5 R6, R7 and R8 does not exceed 21.</abstract><edition>7</edition><oa>free_for_read</oa></addata></record>
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subjects AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F,C08G
BASIC ELECTRIC ELEMENTS
BRAIDING
CHEMISTRY
COMPOSITIONS BASED THEREON
COTTON-WOOL
ELECTRICITY
FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS,NON-WOVEN FABRICS
FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
GENERAL PROCESSES OF COMPOUNDING
KNITTING
LACE-MAKING
LAUNDERING
LAYERED PRODUCTS
LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT ORNON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS
MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARYMATERIAL
METALLURGY
NON-WOVEN FABRICS
ORGANIC MACROMOLECULAR COMPOUNDS
PERFORMING OPERATIONS
PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSIONOF CHEMICAL INTO ELECTRICAL ENERGY
TEXTILES
THEIR PREPARATION OR CHEMICAL WORKING-UP
TRANSPORTING
TREATMENT OF TEXTILES OR THE LIKE
TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS,FABRICS, FEATHERS, OR FIBROUS GOODS MADE FROM SUCH MATERIALS
TRIMMINGS
WADDING
WORKING-UP
title Battery separator
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