Ethylene- alpha -olefin-nonconjugated polyene random copolymer
Disclosed is a process for preparing an ethylene- alpha -olefin-nonconjugated polyene random copolymer comprising random copolymerizing (a) ethylene, (b) an alpha -olefin of 3 or more carbon atoms and (c) a nonconjugated polyene in the presence of a metallocene catalyst containing a specific metallo...
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creator | SAGANE TOSHIHIRO TSUTSUI TOSHIYUKI |
description | Disclosed is a process for preparing an ethylene- alpha -olefin-nonconjugated polyene random copolymer comprising random copolymerizing (a) ethylene, (b) an alpha -olefin of 3 or more carbon atoms and (c) a nonconjugated polyene in the presence of a metallocene catalyst containing a specific metallocene compound. The ethylene- alpha -olefin-nonconjugated polyene random copolymer prepared by the process has such properties that (i) the copolymer contains units derived from ethylene (a) and units derived from the alpha -olefin of 3 or more carbon atoms (b) in a molar ratio of 40/60 to 95/5 [(a)/(b)], (ii) the iodine value is 1 to 50, (iii) the intrinsic viscosity ( eta ) is more than 0.1 dl/g and less than 8.0 10 dl/g, (iv) the intensity ratio D of T alpha beta to T alpha alpha in the 13C-NMR spectrum, T alpha beta /T alpha alpha , is not more than 0.5, (v) the B value is 1.00 to 1.50, (vi) the glass transition temperature Tg is not higher than -50 DEG C., and (vii) the ratio g eta * of the intrinsic viscosity ( eta ) of this copolymer defined above to the intrinsic viscosity ( eta )blank of a straight-chain ethylene-propylene copolymer having the same weight-average molecular weight as this random copolymer and having an ethylene content of 70% by mol, ( eta )/( eta )blank, is more than 0.9. Also disclosed is a vulcanizable rubber composition containing the random copolymer. The ethylene- alpha -olefin-nonconjugated polyene random copolymer and the rubber composition are excellent in mechanical strength, weathering resistance, ozone resistance, processability, low-temperature flexibility and heat resistance. |
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fullrecord | <record><control><sourceid>epo_EVB</sourceid><recordid>TN_cdi_epo_espacenet_US5922823A</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>US5922823A</sourcerecordid><originalsourceid>FETCH-epo_espacenet_US5922823A3</originalsourceid><addsrcrecordid>eNrjZLBzLcmozEnNS9VVSMwpyEhU0M3PSU3LzNPNy89Lzs_LKk1PLElNUSjIz6kEKlIoSsxLyc9VSM4HCeSmFvEwsKYl5hSn8kJpbgZ5N9cQZw_d1IL8-NTigsRkoK6S-NBgU0sjIwsjY0djwioAtZQwOw</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>patent</recordtype></control><display><type>patent</type><title>Ethylene- alpha -olefin-nonconjugated polyene random copolymer</title><source>esp@cenet</source><creator>SAGANE; TOSHIHIRO ; TSUTSUI; TOSHIYUKI</creator><creatorcontrib>SAGANE; TOSHIHIRO ; TSUTSUI; TOSHIYUKI</creatorcontrib><description>Disclosed is a process for preparing an ethylene- alpha -olefin-nonconjugated polyene random copolymer comprising random copolymerizing (a) ethylene, (b) an alpha -olefin of 3 or more carbon atoms and (c) a nonconjugated polyene in the presence of a metallocene catalyst containing a specific metallocene compound. The ethylene- alpha -olefin-nonconjugated polyene random copolymer prepared by the process has such properties that (i) the copolymer contains units derived from ethylene (a) and units derived from the alpha -olefin of 3 or more carbon atoms (b) in a molar ratio of 40/60 to 95/5 [(a)/(b)], (ii) the iodine value is 1 to 50, (iii) the intrinsic viscosity ( eta ) is more than 0.1 dl/g and less than 8.0 10 dl/g, (iv) the intensity ratio D of T alpha beta to T alpha alpha in the 13C-NMR spectrum, T alpha beta /T alpha alpha , is not more than 0.5, (v) the B value is 1.00 to 1.50, (vi) the glass transition temperature Tg is not higher than -50 DEG C., and (vii) the ratio g eta * of the intrinsic viscosity ( eta ) of this copolymer defined above to the intrinsic viscosity ( eta )blank of a straight-chain ethylene-propylene copolymer having the same weight-average molecular weight as this random copolymer and having an ethylene content of 70% by mol, ( eta )/( eta )blank, is more than 0.9. Also disclosed is a vulcanizable rubber composition containing the random copolymer. The ethylene- alpha -olefin-nonconjugated polyene random copolymer and the rubber composition are excellent in mechanical strength, weathering resistance, ozone resistance, processability, low-temperature flexibility and heat resistance.</description><edition>6</edition><language>eng</language><subject>CHEMISTRY ; COMPOSITIONS BASED THEREON ; COMPOSITIONS OF MACROMOLECULAR COMPOUNDS ; MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS ; METALLURGY ; ORGANIC MACROMOLECULAR COMPOUNDS ; THEIR PREPARATION OR CHEMICAL WORKING-UP</subject><creationdate>1999</creationdate><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=19990713&DB=EPODOC&CC=US&NR=5922823A$$EHTML$$P50$$Gepo$$Hfree_for_read</linktohtml><link.rule.ids>230,308,780,885,25563,76318</link.rule.ids><linktorsrc>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=19990713&DB=EPODOC&CC=US&NR=5922823A$$EView_record_in_European_Patent_Office$$FView_record_in_$$GEuropean_Patent_Office$$Hfree_for_read</linktorsrc></links><search><creatorcontrib>SAGANE; TOSHIHIRO</creatorcontrib><creatorcontrib>TSUTSUI; TOSHIYUKI</creatorcontrib><title>Ethylene- alpha -olefin-nonconjugated polyene random copolymer</title><description>Disclosed is a process for preparing an ethylene- alpha -olefin-nonconjugated polyene random copolymer comprising random copolymerizing (a) ethylene, (b) an alpha -olefin of 3 or more carbon atoms and (c) a nonconjugated polyene in the presence of a metallocene catalyst containing a specific metallocene compound. The ethylene- alpha -olefin-nonconjugated polyene random copolymer prepared by the process has such properties that (i) the copolymer contains units derived from ethylene (a) and units derived from the alpha -olefin of 3 or more carbon atoms (b) in a molar ratio of 40/60 to 95/5 [(a)/(b)], (ii) the iodine value is 1 to 50, (iii) the intrinsic viscosity ( eta ) is more than 0.1 dl/g and less than 8.0 10 dl/g, (iv) the intensity ratio D of T alpha beta to T alpha alpha in the 13C-NMR spectrum, T alpha beta /T alpha alpha , is not more than 0.5, (v) the B value is 1.00 to 1.50, (vi) the glass transition temperature Tg is not higher than -50 DEG C., and (vii) the ratio g eta * of the intrinsic viscosity ( eta ) of this copolymer defined above to the intrinsic viscosity ( eta )blank of a straight-chain ethylene-propylene copolymer having the same weight-average molecular weight as this random copolymer and having an ethylene content of 70% by mol, ( eta )/( eta )blank, is more than 0.9. Also disclosed is a vulcanizable rubber composition containing the random copolymer. The ethylene- alpha -olefin-nonconjugated polyene random copolymer and the rubber composition are excellent in mechanical strength, weathering resistance, ozone resistance, processability, low-temperature flexibility and heat resistance.</description><subject>CHEMISTRY</subject><subject>COMPOSITIONS BASED THEREON</subject><subject>COMPOSITIONS OF MACROMOLECULAR COMPOUNDS</subject><subject>MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS</subject><subject>METALLURGY</subject><subject>ORGANIC MACROMOLECULAR COMPOUNDS</subject><subject>THEIR PREPARATION OR CHEMICAL WORKING-UP</subject><fulltext>true</fulltext><rsrctype>patent</rsrctype><creationdate>1999</creationdate><recordtype>patent</recordtype><sourceid>EVB</sourceid><recordid>eNrjZLBzLcmozEnNS9VVSMwpyEhU0M3PSU3LzNPNy89Lzs_LKk1PLElNUSjIz6kEKlIoSsxLyc9VSM4HCeSmFvEwsKYl5hSn8kJpbgZ5N9cQZw_d1IL8-NTigsRkoK6S-NBgU0sjIwsjY0djwioAtZQwOw</recordid><startdate>19990713</startdate><enddate>19990713</enddate><creator>SAGANE; TOSHIHIRO</creator><creator>TSUTSUI; TOSHIYUKI</creator><scope>EVB</scope></search><sort><creationdate>19990713</creationdate><title>Ethylene- alpha -olefin-nonconjugated polyene random copolymer</title><author>SAGANE; TOSHIHIRO ; TSUTSUI; TOSHIYUKI</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-epo_espacenet_US5922823A3</frbrgroupid><rsrctype>patents</rsrctype><prefilter>patents</prefilter><language>eng</language><creationdate>1999</creationdate><topic>CHEMISTRY</topic><topic>COMPOSITIONS BASED THEREON</topic><topic>COMPOSITIONS OF MACROMOLECULAR COMPOUNDS</topic><topic>MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS</topic><topic>METALLURGY</topic><topic>ORGANIC MACROMOLECULAR COMPOUNDS</topic><topic>THEIR PREPARATION OR CHEMICAL WORKING-UP</topic><toplevel>online_resources</toplevel><creatorcontrib>SAGANE; TOSHIHIRO</creatorcontrib><creatorcontrib>TSUTSUI; TOSHIYUKI</creatorcontrib><collection>esp@cenet</collection></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext_linktorsrc</fulltext></delivery><addata><au>SAGANE; TOSHIHIRO</au><au>TSUTSUI; TOSHIYUKI</au><format>patent</format><genre>patent</genre><ristype>GEN</ristype><title>Ethylene- alpha -olefin-nonconjugated polyene random copolymer</title><date>1999-07-13</date><risdate>1999</risdate><abstract>Disclosed is a process for preparing an ethylene- alpha -olefin-nonconjugated polyene random copolymer comprising random copolymerizing (a) ethylene, (b) an alpha -olefin of 3 or more carbon atoms and (c) a nonconjugated polyene in the presence of a metallocene catalyst containing a specific metallocene compound. The ethylene- alpha -olefin-nonconjugated polyene random copolymer prepared by the process has such properties that (i) the copolymer contains units derived from ethylene (a) and units derived from the alpha -olefin of 3 or more carbon atoms (b) in a molar ratio of 40/60 to 95/5 [(a)/(b)], (ii) the iodine value is 1 to 50, (iii) the intrinsic viscosity ( eta ) is more than 0.1 dl/g and less than 8.0 10 dl/g, (iv) the intensity ratio D of T alpha beta to T alpha alpha in the 13C-NMR spectrum, T alpha beta /T alpha alpha , is not more than 0.5, (v) the B value is 1.00 to 1.50, (vi) the glass transition temperature Tg is not higher than -50 DEG C., and (vii) the ratio g eta * of the intrinsic viscosity ( eta ) of this copolymer defined above to the intrinsic viscosity ( eta )blank of a straight-chain ethylene-propylene copolymer having the same weight-average molecular weight as this random copolymer and having an ethylene content of 70% by mol, ( eta )/( eta )blank, is more than 0.9. Also disclosed is a vulcanizable rubber composition containing the random copolymer. The ethylene- alpha -olefin-nonconjugated polyene random copolymer and the rubber composition are excellent in mechanical strength, weathering resistance, ozone resistance, processability, low-temperature flexibility and heat resistance.</abstract><edition>6</edition><oa>free_for_read</oa></addata></record> |
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subjects | CHEMISTRY COMPOSITIONS BASED THEREON COMPOSITIONS OF MACROMOLECULAR COMPOUNDS MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS METALLURGY ORGANIC MACROMOLECULAR COMPOUNDS THEIR PREPARATION OR CHEMICAL WORKING-UP |
title | Ethylene- alpha -olefin-nonconjugated polyene random copolymer |
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