Curable crosslinking system with monobenzaldimine as crosslinker

This invention relates to improved crosslinking systems for polymeric dispersions and solutions having suitability for coatings, adhesives and use in many other applications. These systems are based upon crosslinkable polymers having a plurality of activated keto methylene groups, e.g., a beta diket...

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Hauptverfasser: CHEN, NING, SANTOSUSSO, THOMAS M, WASOWSKI, LARRY A, PINSCHMIDT, JR., ROBERT K, TIEN, CHAO-FONG
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creator CHEN
NING
SANTOSUSSO
THOMAS M
WASOWSKI
LARRY A
PINSCHMIDT, JR.
ROBERT K
TIEN
CHAO-FONG
description This invention relates to improved crosslinking systems for polymeric dispersions and solutions having suitability for coatings, adhesives and use in many other applications. These systems are based upon crosslinkable polymers having a plurality of activated keto methylene groups, e.g., a beta diketone such as an acetoacetate or a keto cyano methylene functional groups and a crosslinkable component comprising an aldimine. A sufficient amount of the aldimine curing agent is used to effect reaction with the polymer containing the activated keto methylene groups and cure thereof. The improvement in the crosslinking system resides in the utilization of a monoaldimine having only one aldimine group and no other methylene reactive group as a crosslinking agent. Another improvement variation to that previously suggested comprises a redispersible polymer(s) containing activated methylene functionality and combined with the monoaldimine and the use of heterocyclic aldimine.
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subjects CHEMISTRY
COMPOSITIONS BASED THEREON
MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS
MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONSONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
METALLURGY
ORGANIC MACROMOLECULAR COMPOUNDS
THEIR PREPARATION OR CHEMICAL WORKING-UP
title Curable crosslinking system with monobenzaldimine as crosslinker
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