Thioheterocyclic near-infrared dyes

Disclosed is a novel near-infrared absorbing dye of formula: wherein X1, X2 independently represents -CR8R9-, -S-, -Se-, -NR10-, -CH=CH- or -O-; n is an integer of 2 or 3; R1 and R2 independently represent alkyl of 1 to 10 carbons or substituted alkyl of 1 to 10 carbons; R3 represents a ring chosen...

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Hauptverfasser: WEED, GREGORY C, FABRICIUS, DIETRICH M
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creator WEED
GREGORY C
FABRICIUS
DIETRICH M
description Disclosed is a novel near-infrared absorbing dye of formula: wherein X1, X2 independently represents -CR8R9-, -S-, -Se-, -NR10-, -CH=CH- or -O-; n is an integer of 2 or 3; R1 and R2 independently represent alkyl of 1 to 10 carbons or substituted alkyl of 1 to 10 carbons; R3 represents a ring chosen from the set consisting of aryl, substituted aryl, and heterocyclic containing 5 or 6 carbons in the ring; R4, R5, R6 and R7 independently represent hydrogen, alkyl of 1-10 carbons, substituted alkyl of 1-10 carbons, R4 and R5 taken together or R6 and R7 taken together may represent the atoms necessary to form a 5 or 6-membered aliphatic ring, an aromatic six-membered ring, an aromatic 10-membered ring, a substituted aromatic six-member ring or a substituted aromatic 10-member ring; R8, R9 independently represent alkyl of 1-10 carbons, substituted alkyl of 1-10 carbons, aryl of 6-10 carbons, substituted aryl of 6-10 carbons; R10 represents an alkyl of 1-10 carbons, substituted alkyl of 1-10 carbons, aryl of 6-10 carbons, substituted aryl of 6-10 carbons; with the proviso that when R3 is phenyl or substituted phenyl and n=3, R1 or R2 is not an unsubstituted alkyl. Disclosed is a novel near-infrared absorbing dye of formula: wherein X1, X2 independently represents -CR8R9-, -S-, -Se-, -NR10-, -CH=CH- or -O-; n is an integer of 2 or 3; R1 and R2 independently represent alkyl of 1 to 10 carbons or substituted alkyl of 1 to 10 carbons; R3 represents a ring chosen from the set consisting of aryl, substituted aryl, and heterocyclic containing 5 or 6 carbons in the ring; R4, R5, R6 and R7 independently represent hydrogen, alkyl of 1-10 carbons, substituted alkyl of 1-10 carbons, R4 and R5 taken together or R6 and R7 taken together may represent the atoms necessary to form a 5 or 6-membered aliphatic ring, an aromatic six-membered ring, an aromatic 10-membered ring, a substituted aromatic six-member ring or a substituted aromatic 10-member ring; R8, R9 independently represent alkyl of 1-10 carbons, substituted alkyl of 1-10 carbons, aryl of 6-10 carbons, substituted aryl of 6-10 carbons; R10 represents an alkyl of 1-10 carbons, substituted alkyl of 1-10 carbons, aryl of 6-10 carbons, substituted aryl of 6-10 carbons; with the proviso that when R3 is phenyl or substituted phenyl and n=3, R1 or R2 is not an unsubstituted alkyl.
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Disclosed is a novel near-infrared absorbing dye of formula: wherein X1, X2 independently represents -CR8R9-, -S-, -Se-, -NR10-, -CH=CH- or -O-; n is an integer of 2 or 3; R1 and R2 independently represent alkyl of 1 to 10 carbons or substituted alkyl of 1 to 10 carbons; R3 represents a ring chosen from the set consisting of aryl, substituted aryl, and heterocyclic containing 5 or 6 carbons in the ring; R4, R5, R6 and R7 independently represent hydrogen, alkyl of 1-10 carbons, substituted alkyl of 1-10 carbons, R4 and R5 taken together or R6 and R7 taken together may represent the atoms necessary to form a 5 or 6-membered aliphatic ring, an aromatic six-membered ring, an aromatic 10-membered ring, a substituted aromatic six-member ring or a substituted aromatic 10-member ring; R8, R9 independently represent alkyl of 1-10 carbons, substituted alkyl of 1-10 carbons, aryl of 6-10 carbons, substituted aryl of 6-10 carbons; R10 represents an alkyl of 1-10 carbons, substituted alkyl of 1-10 carbons, aryl of 6-10 carbons, substituted aryl of 6-10 carbons; with the proviso that when R3 is phenyl or substituted phenyl and n=3, R1 or R2 is not an unsubstituted alkyl.</description><edition>6</edition><language>eng</language><subject>ADHESIVES ; AUXILIARY PROCESSES IN PHOTOGRAPHY ; CHEMISTRY ; CINEMATOGRAPHY ; DYES ; ELECTROGRAPHY ; HETEROCYCLIC COMPOUNDS ; HOLOGRAPHY ; LAKES ; METALLURGY ; MISCELLANEOUS APPLICATIONS OF MATERIALS ; MISCELLANEOUS COMPOSITIONS ; MORDANTS ; NATURAL RESINS ; ORGANIC CHEMISTRY ; ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES ; PAINTS ; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR,STEREO-PHOTOGRAPHIC PROCESSES ; PHOTOGRAPHY ; PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES ; PHYSICS ; POLISHES</subject><creationdate>1995</creationdate><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&amp;date=19950808&amp;DB=EPODOC&amp;CC=US&amp;NR=5440042A$$EHTML$$P50$$Gepo$$Hfree_for_read</linktohtml><link.rule.ids>230,308,780,885,25564,76547</link.rule.ids><linktorsrc>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&amp;date=19950808&amp;DB=EPODOC&amp;CC=US&amp;NR=5440042A$$EView_record_in_European_Patent_Office$$FView_record_in_$$GEuropean_Patent_Office$$Hfree_for_read</linktorsrc></links><search><creatorcontrib>WEED; GREGORY C</creatorcontrib><creatorcontrib>FABRICIUS; DIETRICH M</creatorcontrib><title>Thioheterocyclic near-infrared dyes</title><description>Disclosed is a novel near-infrared absorbing dye of formula: wherein X1, X2 independently represents -CR8R9-, -S-, -Se-, -NR10-, -CH=CH- or -O-; n is an integer of 2 or 3; R1 and R2 independently represent alkyl of 1 to 10 carbons or substituted alkyl of 1 to 10 carbons; R3 represents a ring chosen from the set consisting of aryl, substituted aryl, and heterocyclic containing 5 or 6 carbons in the ring; R4, R5, R6 and R7 independently represent hydrogen, alkyl of 1-10 carbons, substituted alkyl of 1-10 carbons, R4 and R5 taken together or R6 and R7 taken together may represent the atoms necessary to form a 5 or 6-membered aliphatic ring, an aromatic six-membered ring, an aromatic 10-membered ring, a substituted aromatic six-member ring or a substituted aromatic 10-member ring; R8, R9 independently represent alkyl of 1-10 carbons, substituted alkyl of 1-10 carbons, aryl of 6-10 carbons, substituted aryl of 6-10 carbons; R10 represents an alkyl of 1-10 carbons, substituted alkyl of 1-10 carbons, aryl of 6-10 carbons, substituted aryl of 6-10 carbons; with the proviso that when R3 is phenyl or substituted phenyl and n=3, R1 or R2 is not an unsubstituted alkyl. Disclosed is a novel near-infrared absorbing dye of formula: wherein X1, X2 independently represents -CR8R9-, -S-, -Se-, -NR10-, -CH=CH- or -O-; n is an integer of 2 or 3; R1 and R2 independently represent alkyl of 1 to 10 carbons or substituted alkyl of 1 to 10 carbons; R3 represents a ring chosen from the set consisting of aryl, substituted aryl, and heterocyclic containing 5 or 6 carbons in the ring; R4, R5, R6 and R7 independently represent hydrogen, alkyl of 1-10 carbons, substituted alkyl of 1-10 carbons, R4 and R5 taken together or R6 and R7 taken together may represent the atoms necessary to form a 5 or 6-membered aliphatic ring, an aromatic six-membered ring, an aromatic 10-membered ring, a substituted aromatic six-member ring or a substituted aromatic 10-member ring; R8, R9 independently represent alkyl of 1-10 carbons, substituted alkyl of 1-10 carbons, aryl of 6-10 carbons, substituted aryl of 6-10 carbons; R10 represents an alkyl of 1-10 carbons, substituted alkyl of 1-10 carbons, aryl of 6-10 carbons, substituted aryl of 6-10 carbons; 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GREGORY C</creatorcontrib><creatorcontrib>FABRICIUS; DIETRICH M</creatorcontrib><collection>esp@cenet</collection></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext_linktorsrc</fulltext></delivery><addata><au>WEED; GREGORY C</au><au>FABRICIUS; DIETRICH M</au><format>patent</format><genre>patent</genre><ristype>GEN</ristype><title>Thioheterocyclic near-infrared dyes</title><date>1995-08-08</date><risdate>1995</risdate><abstract>Disclosed is a novel near-infrared absorbing dye of formula: wherein X1, X2 independently represents -CR8R9-, -S-, -Se-, -NR10-, -CH=CH- or -O-; n is an integer of 2 or 3; R1 and R2 independently represent alkyl of 1 to 10 carbons or substituted alkyl of 1 to 10 carbons; R3 represents a ring chosen from the set consisting of aryl, substituted aryl, and heterocyclic containing 5 or 6 carbons in the ring; R4, R5, R6 and R7 independently represent hydrogen, alkyl of 1-10 carbons, substituted alkyl of 1-10 carbons, R4 and R5 taken together or R6 and R7 taken together may represent the atoms necessary to form a 5 or 6-membered aliphatic ring, an aromatic six-membered ring, an aromatic 10-membered ring, a substituted aromatic six-member ring or a substituted aromatic 10-member ring; R8, R9 independently represent alkyl of 1-10 carbons, substituted alkyl of 1-10 carbons, aryl of 6-10 carbons, substituted aryl of 6-10 carbons; R10 represents an alkyl of 1-10 carbons, substituted alkyl of 1-10 carbons, aryl of 6-10 carbons, substituted aryl of 6-10 carbons; with the proviso that when R3 is phenyl or substituted phenyl and n=3, R1 or R2 is not an unsubstituted alkyl. Disclosed is a novel near-infrared absorbing dye of formula: wherein X1, X2 independently represents -CR8R9-, -S-, -Se-, -NR10-, -CH=CH- or -O-; n is an integer of 2 or 3; R1 and R2 independently represent alkyl of 1 to 10 carbons or substituted alkyl of 1 to 10 carbons; R3 represents a ring chosen from the set consisting of aryl, substituted aryl, and heterocyclic containing 5 or 6 carbons in the ring; R4, R5, R6 and R7 independently represent hydrogen, alkyl of 1-10 carbons, substituted alkyl of 1-10 carbons, R4 and R5 taken together or R6 and R7 taken together may represent the atoms necessary to form a 5 or 6-membered aliphatic ring, an aromatic six-membered ring, an aromatic 10-membered ring, a substituted aromatic six-member ring or a substituted aromatic 10-member ring; R8, R9 independently represent alkyl of 1-10 carbons, substituted alkyl of 1-10 carbons, aryl of 6-10 carbons, substituted aryl of 6-10 carbons; R10 represents an alkyl of 1-10 carbons, substituted alkyl of 1-10 carbons, aryl of 6-10 carbons, substituted aryl of 6-10 carbons; with the proviso that when R3 is phenyl or substituted phenyl and n=3, R1 or R2 is not an unsubstituted alkyl.</abstract><edition>6</edition><oa>free_for_read</oa></addata></record>
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subjects ADHESIVES
AUXILIARY PROCESSES IN PHOTOGRAPHY
CHEMISTRY
CINEMATOGRAPHY
DYES
ELECTROGRAPHY
HETEROCYCLIC COMPOUNDS
HOLOGRAPHY
LAKES
METALLURGY
MISCELLANEOUS APPLICATIONS OF MATERIALS
MISCELLANEOUS COMPOSITIONS
MORDANTS
NATURAL RESINS
ORGANIC CHEMISTRY
ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES
PAINTS
PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR,STEREO-PHOTOGRAPHIC PROCESSES
PHOTOGRAPHY
PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES
PHYSICS
POLISHES
title Thioheterocyclic near-infrared dyes
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