Electrochemical organic reactions via catalytic halide substitution
An improved process for the electrochemical reaction of a lower organic halide, e.g., benzyl chloride, wherein the improvement comprises the catalytic in situ conversion of the lower organic halide to a higher organic halide, e.g., benzyl iodide, which reacts under milder conditions than does the lo...
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| creator | STUTTS KENNETH J |
| description | An improved process for the electrochemical reaction of a lower organic halide, e.g., benzyl chloride, wherein the improvement comprises the catalytic in situ conversion of the lower organic halide to a higher organic halide, e.g., benzyl iodide, which reacts under milder conditions than does the lower organic halide. An example of such an improved process is the dimerization of a benzyl chloride to form a diphenylethane wherein a catalytic amount of sodium iodide is added to the electrochemical cell under conditions such that the conversion of the benzyl chloride to benzyl iodide is effectively driven to completion. |
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An example of such an improved process is the dimerization of a benzyl chloride to form a diphenylethane wherein a catalytic amount of sodium iodide is added to the electrochemical cell under conditions such that the conversion of the benzyl chloride to benzyl iodide is effectively driven to completion.</description><language>eng</language><subject>APPARATUS THEREFOR ; CHEMISTRY ; ELECTROLYTIC OR ELECTROPHORETIC PROCESSES ; ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTIONOF COMPOUNDS OR NON-METALS ; METALLURGY</subject><creationdate>1990</creationdate><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=19900227&DB=EPODOC&CC=US&NR=4904370A$$EHTML$$P50$$Gepo$$Hfree_for_read</linktohtml><link.rule.ids>230,308,780,885,25564,76547</link.rule.ids><linktorsrc>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=19900227&DB=EPODOC&CC=US&NR=4904370A$$EView_record_in_European_Patent_Office$$FView_record_in_$$GEuropean_Patent_Office$$Hfree_for_read</linktorsrc></links><search><creatorcontrib>STUTTS; KENNETH J</creatorcontrib><title>Electrochemical organic reactions via catalytic halide substitution</title><description>An improved process for the electrochemical reaction of a lower organic halide, e.g., benzyl chloride, wherein the improvement comprises the catalytic in situ conversion of the lower organic halide to a higher organic halide, e.g., benzyl iodide, which reacts under milder conditions than does the lower organic halide. An example of such an improved process is the dimerization of a benzyl chloride to form a diphenylethane wherein a catalytic amount of sodium iodide is added to the electrochemical cell under conditions such that the conversion of the benzyl chloride to benzyl iodide is effectively driven to completion.</description><subject>APPARATUS THEREFOR</subject><subject>CHEMISTRY</subject><subject>ELECTROLYTIC OR ELECTROPHORETIC PROCESSES</subject><subject>ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTIONOF COMPOUNDS OR NON-METALS</subject><subject>METALLURGY</subject><fulltext>true</fulltext><rsrctype>patent</rsrctype><creationdate>1990</creationdate><recordtype>patent</recordtype><sourceid>EVB</sourceid><recordid>eNrjZHB2zUlNLinKT85Izc1MTsxRyC9KT8zLTFYoSk1MLsnMzytWKMtMVEhOLEnMqSwBimck5mSmpCoUlyYVl2SWlIKU8DCwpiXmFKfyQmluBnk31xBnD93Ugvz41OKCxOTUvNSS-NBgE0sDE2NzA0djwioAFa8ymw</recordid><startdate>19900227</startdate><enddate>19900227</enddate><creator>STUTTS; KENNETH J</creator><scope>EVB</scope></search><sort><creationdate>19900227</creationdate><title>Electrochemical organic reactions via catalytic halide substitution</title><author>STUTTS; KENNETH J</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-epo_espacenet_US4904370A3</frbrgroupid><rsrctype>patents</rsrctype><prefilter>patents</prefilter><language>eng</language><creationdate>1990</creationdate><topic>APPARATUS THEREFOR</topic><topic>CHEMISTRY</topic><topic>ELECTROLYTIC OR ELECTROPHORETIC PROCESSES</topic><topic>ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTIONOF COMPOUNDS OR NON-METALS</topic><topic>METALLURGY</topic><toplevel>online_resources</toplevel><creatorcontrib>STUTTS; KENNETH J</creatorcontrib><collection>esp@cenet</collection></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext_linktorsrc</fulltext></delivery><addata><au>STUTTS; KENNETH J</au><format>patent</format><genre>patent</genre><ristype>GEN</ristype><title>Electrochemical organic reactions via catalytic halide substitution</title><date>1990-02-27</date><risdate>1990</risdate><abstract>An improved process for the electrochemical reaction of a lower organic halide, e.g., benzyl chloride, wherein the improvement comprises the catalytic in situ conversion of the lower organic halide to a higher organic halide, e.g., benzyl iodide, which reacts under milder conditions than does the lower organic halide. An example of such an improved process is the dimerization of a benzyl chloride to form a diphenylethane wherein a catalytic amount of sodium iodide is added to the electrochemical cell under conditions such that the conversion of the benzyl chloride to benzyl iodide is effectively driven to completion.</abstract><oa>free_for_read</oa></addata></record> |
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| subjects | APPARATUS THEREFOR CHEMISTRY ELECTROLYTIC OR ELECTROPHORETIC PROCESSES ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTIONOF COMPOUNDS OR NON-METALS METALLURGY |
| title | Electrochemical organic reactions via catalytic halide substitution |
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