Imidazolidinone polymers useful as nonwoven binders
Novel polymerizable imidazolidinone monomers, useful in the preparation of self-crosslinking polymers, have the general structure wherein R1 is H or a C1-C6 linear or branched alkyl or hydroxyalkyl group; X is a divalent radical selected from the group consisting of -(CH2)m-, +TR with R being H or C...
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creator | PALMER JOSEPH G IOVINE CARMINE P WALKER JAMES L |
description | Novel polymerizable imidazolidinone monomers, useful in the preparation of self-crosslinking polymers, have the general structure wherein R1 is H or a C1-C6 linear or branched alkyl or hydroxyalkyl group; X is a divalent radical selected from the group consisting of -(CH2)m-, +TR with R being H or CH3, m being 0-5, and n being 1-5; R2 is H or CH3; R3 is H or with R' as defined above; and R4 and R5 are independently H or linear or branched C1-C4 alkyl groups. In a preferred embodiment, aqueous emulsions of the imidazolidinone-containing polymers (e.g. 45-60% vinyl acetate, 34-52% butyl acrylate, and 3-6% imidazolidinone) and an acid-curing catalyst (e.g. ZnCl2) are used as formaldehyde-free binders for nonwoven textiles. |
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In a preferred embodiment, aqueous emulsions of the imidazolidinone-containing polymers (e.g. 45-60% vinyl acetate, 34-52% butyl acrylate, and 3-6% imidazolidinone) and an acid-curing catalyst (e.g. ZnCl2) are used as formaldehyde-free binders for nonwoven textiles.</description><edition>4</edition><language>eng</language><subject>CHEMISTRY ; COMPOSITIONS BASED THEREON ; HETEROCYCLIC COMPOUNDS ; MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS ; METALLURGY ; ORGANIC CHEMISTRY ; ORGANIC MACROMOLECULAR COMPOUNDS ; THEIR PREPARATION OR CHEMICAL WORKING-UP</subject><creationdate>1986</creationdate><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=19861111&DB=EPODOC&CC=US&NR=4622374A$$EHTML$$P50$$Gepo$$Hfree_for_read</linktohtml><link.rule.ids>230,308,776,881,25542,76289</link.rule.ids><linktorsrc>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=19861111&DB=EPODOC&CC=US&NR=4622374A$$EView_record_in_European_Patent_Office$$FView_record_in_$$GEuropean_Patent_Office$$Hfree_for_read</linktorsrc></links><search><creatorcontrib>PALMER; JOSEPH G</creatorcontrib><creatorcontrib>IOVINE; CARMINE P</creatorcontrib><creatorcontrib>WALKER; JAMES L</creatorcontrib><title>Imidazolidinone polymers useful as nonwoven binders</title><description>Novel polymerizable imidazolidinone monomers, useful in the preparation of self-crosslinking polymers, have the general structure wherein R1 is H or a C1-C6 linear or branched alkyl or hydroxyalkyl group; X is a divalent radical selected from the group consisting of -(CH2)m-, +TR with R being H or CH3, m being 0-5, and n being 1-5; R2 is H or CH3; R3 is H or with R' as defined above; and R4 and R5 are independently H or linear or branched C1-C4 alkyl groups. In a preferred embodiment, aqueous emulsions of the imidazolidinone-containing polymers (e.g. 45-60% vinyl acetate, 34-52% butyl acrylate, and 3-6% imidazolidinone) and an acid-curing catalyst (e.g. ZnCl2) are used as formaldehyde-free binders for nonwoven textiles.</description><subject>CHEMISTRY</subject><subject>COMPOSITIONS BASED THEREON</subject><subject>HETEROCYCLIC COMPOUNDS</subject><subject>MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS</subject><subject>METALLURGY</subject><subject>ORGANIC CHEMISTRY</subject><subject>ORGANIC MACROMOLECULAR COMPOUNDS</subject><subject>THEIR PREPARATION OR CHEMICAL WORKING-UP</subject><fulltext>true</fulltext><rsrctype>patent</rsrctype><creationdate>1986</creationdate><recordtype>patent</recordtype><sourceid>EVB</sourceid><recordid>eNrjZDD2zM1MSazKz8lMyczLz0tVKMjPqcxNLSpWKC1OTSvNUUgsVgCKl-eXpeYpJGXmpQCleBhY0xJzilN5oTQ3g7yba4izh25qQX58anFBYnJqXmpJfGiwiZmRkbG5iaMxYRUAqFUsfw</recordid><startdate>19861111</startdate><enddate>19861111</enddate><creator>PALMER; JOSEPH G</creator><creator>IOVINE; CARMINE P</creator><creator>WALKER; JAMES L</creator><scope>EVB</scope></search><sort><creationdate>19861111</creationdate><title>Imidazolidinone polymers useful as nonwoven binders</title><author>PALMER; JOSEPH G ; IOVINE; CARMINE P ; WALKER; JAMES L</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-epo_espacenet_US4622374A3</frbrgroupid><rsrctype>patents</rsrctype><prefilter>patents</prefilter><language>eng</language><creationdate>1986</creationdate><topic>CHEMISTRY</topic><topic>COMPOSITIONS BASED THEREON</topic><topic>HETEROCYCLIC COMPOUNDS</topic><topic>MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS</topic><topic>METALLURGY</topic><topic>ORGANIC CHEMISTRY</topic><topic>ORGANIC MACROMOLECULAR COMPOUNDS</topic><topic>THEIR PREPARATION OR CHEMICAL WORKING-UP</topic><toplevel>online_resources</toplevel><creatorcontrib>PALMER; JOSEPH G</creatorcontrib><creatorcontrib>IOVINE; CARMINE P</creatorcontrib><creatorcontrib>WALKER; JAMES L</creatorcontrib><collection>esp@cenet</collection></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext_linktorsrc</fulltext></delivery><addata><au>PALMER; JOSEPH G</au><au>IOVINE; CARMINE P</au><au>WALKER; JAMES L</au><format>patent</format><genre>patent</genre><ristype>GEN</ristype><title>Imidazolidinone polymers useful as nonwoven binders</title><date>1986-11-11</date><risdate>1986</risdate><abstract>Novel polymerizable imidazolidinone monomers, useful in the preparation of self-crosslinking polymers, have the general structure wherein R1 is H or a C1-C6 linear or branched alkyl or hydroxyalkyl group; X is a divalent radical selected from the group consisting of -(CH2)m-, +TR with R being H or CH3, m being 0-5, and n being 1-5; R2 is H or CH3; R3 is H or with R' as defined above; and R4 and R5 are independently H or linear or branched C1-C4 alkyl groups. In a preferred embodiment, aqueous emulsions of the imidazolidinone-containing polymers (e.g. 45-60% vinyl acetate, 34-52% butyl acrylate, and 3-6% imidazolidinone) and an acid-curing catalyst (e.g. ZnCl2) are used as formaldehyde-free binders for nonwoven textiles.</abstract><edition>4</edition><oa>free_for_read</oa></addata></record> |
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subjects | CHEMISTRY COMPOSITIONS BASED THEREON HETEROCYCLIC COMPOUNDS MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS METALLURGY ORGANIC CHEMISTRY ORGANIC MACROMOLECULAR COMPOUNDS THEIR PREPARATION OR CHEMICAL WORKING-UP |
title | Imidazolidinone polymers useful as nonwoven binders |
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