Crystal of enantiomer pair of phenylacetic acid ester derivative and process for obtaining a mixture of stereoisomers of the derivative

A crystal of an enantiomer pair of stereoisomers of alpha -cyano-3-phenoxybenzyl 2-(4-chlorophenyl)isovalerate (general name: fenvalerate) comprising (S)- alpha -cyano-3-phenoxybenzyl (S)-2-(4-chlorophenyl)isovalerate and an enantiomer thereof, which has the crystal characteristics as specified in t...

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Hauptverfasser: HAYASHI, MASAHIRO, TAKUMA, KENZI, SUZUKI, YUKIO
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creator HAYASHI
MASAHIRO
TAKUMA
KENZI
SUZUKI
YUKIO
description A crystal of an enantiomer pair of stereoisomers of alpha -cyano-3-phenoxybenzyl 2-(4-chlorophenyl)isovalerate (general name: fenvalerate) comprising (S)- alpha -cyano-3-phenoxybenzyl (S)-2-(4-chlorophenyl)isovalerate and an enantiomer thereof, which has the crystal characteristics as specified in the specification, is disclosed. A process for preparing the enantiomer pair or the fenvalerate rich in the enantiomer pair by depositing the above-described crystal from a solution of a racemate of fenvalerate is also disclosed. A process for preparing the enantiomer pair by depositing the crystal from a solution of the fenvalerate rich in the enantiomer pair is further disclosed.
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A process for preparing the enantiomer pair or the fenvalerate rich in the enantiomer pair by depositing the above-described crystal from a solution of a racemate of fenvalerate is also disclosed. A process for preparing the enantiomer pair by depositing the crystal from a solution of the fenvalerate rich in the enantiomer pair is further disclosed.</description><language>eng</language><subject>ACYCLIC OR CARBOCYCLIC COMPOUNDS ; AGRICULTURE ; ANIMAL HUSBANDRY ; APPARATUS THEREFOR ; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES, AS HERBICIDES ; CHEMISTRY ; CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION ORPROCESSING OF GOODS ; FISHING ; FORESTRY ; GENERAL METHODS OF ORGANIC CHEMISTRY ; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC ; GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS ; HUMAN NECESSITIES ; HUNTING ; METALLURGY ; ORGANIC CHEMISTRY ; PEST REPELLANTS OR ATTRACTANTS ; PLANT GROWTH REGULATORS ; PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTSTHEREOF ; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS ; TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINSTCLIMATE CHANGE ; TRAPPING</subject><creationdate>1984</creationdate><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&amp;date=19840221&amp;DB=EPODOC&amp;CC=US&amp;NR=4432908A$$EHTML$$P50$$Gepo$$Hfree_for_read</linktohtml><link.rule.ids>230,308,780,885,25564,76547</link.rule.ids><linktorsrc>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&amp;date=19840221&amp;DB=EPODOC&amp;CC=US&amp;NR=4432908A$$EView_record_in_European_Patent_Office$$FView_record_in_$$GEuropean_Patent_Office$$Hfree_for_read</linktorsrc></links><search><creatorcontrib>HAYASHI; MASAHIRO</creatorcontrib><creatorcontrib>TAKUMA; KENZI</creatorcontrib><creatorcontrib>SUZUKI; YUKIO</creatorcontrib><title>Crystal of enantiomer pair of phenylacetic acid ester derivative and process for obtaining a mixture of stereoisomers of the derivative</title><description>A crystal of an enantiomer pair of stereoisomers of alpha -cyano-3-phenoxybenzyl 2-(4-chlorophenyl)isovalerate (general name: fenvalerate) comprising (S)- alpha -cyano-3-phenoxybenzyl (S)-2-(4-chlorophenyl)isovalerate and an enantiomer thereof, which has the crystal characteristics as specified in the specification, is disclosed. A process for preparing the enantiomer pair or the fenvalerate rich in the enantiomer pair by depositing the above-described crystal from a solution of a racemate of fenvalerate is also disclosed. 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A process for preparing the enantiomer pair or the fenvalerate rich in the enantiomer pair by depositing the above-described crystal from a solution of a racemate of fenvalerate is also disclosed. A process for preparing the enantiomer pair by depositing the crystal from a solution of the fenvalerate rich in the enantiomer pair is further disclosed.</abstract><oa>free_for_read</oa></addata></record>
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subjects ACYCLIC OR CARBOCYCLIC COMPOUNDS
AGRICULTURE
ANIMAL HUSBANDRY
APPARATUS THEREFOR
BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES, AS HERBICIDES
CHEMISTRY
CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION ORPROCESSING OF GOODS
FISHING
FORESTRY
GENERAL METHODS OF ORGANIC CHEMISTRY
GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS
HUMAN NECESSITIES
HUNTING
METALLURGY
ORGANIC CHEMISTRY
PEST REPELLANTS OR ATTRACTANTS
PLANT GROWTH REGULATORS
PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTSTHEREOF
TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINSTCLIMATE CHANGE
TRAPPING
title Crystal of enantiomer pair of phenylacetic acid ester derivative and process for obtaining a mixture of stereoisomers of the derivative
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