Process for producing overbased alkaline earth hydrocarbyl sulfonates

Overbased alkaline earth metal hydrocarbyl sulfonates are made by injecting carbon dioxide into a mixture of hydrocarbon sulfonic acid, alkaline earth metal base and lower alkanol. Solids are removed using a centrifuge or filter forming a cake of such solids and hydrocarbyl sulfonic acid values. The...

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Hauptverfasser: SETH, KISHANKUMAR K
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Sprache:eng
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Zusammenfassung:Overbased alkaline earth metal hydrocarbyl sulfonates are made by injecting carbon dioxide into a mixture of hydrocarbon sulfonic acid, alkaline earth metal base and lower alkanol. Solids are removed using a centrifuge or filter forming a cake of such solids and hydrocarbyl sulfonic acid values. The cake is mixed with an aqueous acid which forms a water-soluble alkaline earth metal salt. The resulting organic phase is separated and hydrocarbyl sulfonic acid is recovered from it.