Olefin polymerization process

An olefin polymerization process for the preparation of polyolefins having relatively low molecular weights and high melt indexes without loss of catalyst activity, utilizing a catalyst comprising a silica xerogel support having a pore volume greater than about 2.0 cc/g, the major portion of which v...

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Hauptverfasser: ABOUTBOUL, HENRI A, KREKELER, JEROME H, KIRCH, WILLIAM
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creator ABOUTBOUL
HENRI A
KREKELER
JEROME H
KIRCH
WILLIAM
description An olefin polymerization process for the preparation of polyolefins having relatively low molecular weights and high melt indexes without loss of catalyst activity, utilizing a catalyst comprising a silica xerogel support having a pore volume greater than about 2.0 cc/g, the major portion of which volume is provided by pores having pore diameters ranging from 300 to 600 A and a surface area ranging from 200 to 500 m2/g, and having deposited thereon a metal-containing catalytic material, such as chromium oxide, or other metal oxide. The process is designed for the preparation of polymers and copolymers of 1-olefins having a maximum of 8 carbon atoms in the chain and having no branching nearer the double bond than the 4-position, e.g., ethylene polymers.
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subjects CHEMISTRY
COMPOSITIONS BASED THEREON
COMPOUNDS THEREOF
INORGANIC CHEMISTRY
MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS
METALLURGY
NON-METALLIC ELEMENTS
ORGANIC MACROMOLECULAR COMPOUNDS
THEIR PREPARATION OR CHEMICAL WORKING-UP
title Olefin polymerization process
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