Method of processing waste gases containing sulphurous-acid anhydride

A method of processing waste gases containing sulphurous-acid anhydride comprises contacting said waste gases with an aqueous solution of sulphuric acid in the presence of oxygen or air and a catalyst comprising an inorganic manganese salt, such as manganese sulphate, perchlorate, chloride, nitrate...

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Hauptverfasser: BARANOVA, RIMMA BRONISLAVOVNA, PANFEROVA, ALEXANDRA TIMOFEEVNA, PETRYAEV, PETROVICH EVGENY, BUGAENKO, LENAR TIMOFEEVICH, NIKESHICHEV, JURY NIKOLAEVICH, BYAKOV, VSEVOLOD MIKHAILOVICH, LAZAREV, VLADIMIR ILICH, MIRONOV, NIKOLAI PETROVICH, PINAEV, VIKTOR ALEXANDROVICH, KALYAZIN, EVGENY PETROVICH
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creator BARANOVA
RIMMA BRONISLAVOVNA
PANFEROVA
ALEXANDRA TIMOFEEVNA
PETRYAEV
PETROVICH EVGENY
BUGAENKO
LENAR TIMOFEEVICH
NIKESHICHEV
JURY NIKOLAEVICH
BYAKOV
VSEVOLOD MIKHAILOVICH
LAZAREV
VLADIMIR ILICH
MIRONOV
NIKOLAI PETROVICH
PINAEV
VIKTOR ALEXANDROVICH
KALYAZIN
EVGENY PETROVICH
description A method of processing waste gases containing sulphurous-acid anhydride comprises contacting said waste gases with an aqueous solution of sulphuric acid in the presence of oxygen or air and a catalyst comprising an inorganic manganese salt, such as manganese sulphate, perchlorate, chloride, nitrate or phosphate used in an amount of 0.0003-0.03 wt.% based on manganese ion to obtain an aqueous solution of sulphuric acid containing sulphurous-acid anhydride. This solution is subjected to the action of an agent for initiating the oxidation of sulphurous-acid anhydride comprising ionizing radiation to obtain an aqueous solution of sulphuric acid free from sulphurous-acid anhydride. A part of the sulphuric acid is derived from the cycle in the form of the resulting aqueous solution in an amount equivalent to the amount of the oxidized sulphurous-acid anhydride, and the remaining part of the sulphuric acid is fed for contacting with the waste gases.
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subjects CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY
CHEMISTRY
COMPOUNDS THEREOF
INORGANIC CHEMISTRY
METALLURGY
NON-METALLIC ELEMENTS
PERFORMING OPERATIONS
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
SEPARATION
THEIR RELEVANT APPARATUS
TRANSPORTING
title Method of processing waste gases containing sulphurous-acid anhydride
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