Stable, catalytically active and coke selective zeolite

A stable rare earth exchanged zeolite having high catalytic activity and improved coke selectivity is prepared by a series of exchange steps whereby the rare earth is introduced into the zeolite in a multi-step e.g., two step manner. The method comprises exchanging a sodium zeolite to less than 4.0...

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Hauptverfasser: MCDANIEL, CARL VANCE, MAGEE, JR., JOHN STOREY
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creator MCDANIEL
CARL VANCE
MAGEE, JR.
JOHN STOREY
description A stable rare earth exchanged zeolite having high catalytic activity and improved coke selectivity is prepared by a series of exchange steps whereby the rare earth is introduced into the zeolite in a multi-step e.g., two step manner. The method comprises exchanging a sodium zeolite to less than 4.0 weight percent Na2O, exchanging with rare earth to give an initial rare earth oxide content of 0.3 to 5 weight percent, calcining, and further rare earth exchanging the zeolite to give a final rare earth content of 1.0 to 10 weight percent.
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subjects CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY
CHEMISTRY
CRACKING HYDROCARBON OILS
FUELS
LUBRICANTS
METALLURGY
MINERAL WAXES
PEAT
PERFORMING OPERATIONS
PETROLEUM, GAS OR COKE INDUSTRIES
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVEHYDROGENATION, OLIGOMERISATION, POLYMERISATION
RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, ORGASES
REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS
REFORMING OF NAPHTHA
TECHNICAL GASES CONTAINING CARBON MONOXIDE
THEIR RELEVANT APPARATUS
TRANSPORTING
title Stable, catalytically active and coke selective zeolite
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