Corrosion-inhibited metal-glass

A corrosion-resistant composite material comprises a sintered intimate mixture of powdered metal and glass particles. The term 'glass' includes enamel and the term 'metal' includes alloys. The glass has softening point below the m.p. of the metal and within \sB 100 DEG C. of the...

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description A corrosion-resistant composite material comprises a sintered intimate mixture of powdered metal and glass particles. The term 'glass' includes enamel and the term 'metal' includes alloys. The glass has softening point below the m.p. of the metal and within \sB 100 DEG C. of the sintering temperature of the metal, and is waterleachable at a rate of 50-10,000 p.p.m. of corrosion-inhibiting ions when agitated in the ratio 1 part glass to 2 parts distilled water for 4 hours at room temperature. Corrosion-inhibiting ions include chromate, tungstate, molybdate, nitrite, nitrate, phosphate, ferrate, and silicate. The glass may contain a colourant. The glass may also contain corrosion inhibitors which release corrosion-inhibiting ions concurrently with those released by dissolution of the glass. Metals include Al, Mg, Zn, Fe and Cu. Articles may be made by dry-mixing the glass and metal powders, preferably finer than 100-mesh, U.S.S. sieve, e.g. 5-41 volume % being glass, cold-pressing to obtain a green compact of 90% theoretical density, and sintering e.g. in an Ar/H2 atmosphere. The hot sintered composite may be mechanically worked, e.g. by forging, rolling or extrusion. Al-glass articles may be etched in 2% NaOH to provide a matte finish. The bodies may be enamelled, and the material may be used as an undercoat for enamelling. Multilayered structures may be made ranging from metal to pure glass with intervening gradations of metal-glass composites.ALSO:A corrosion-resistant composite material comprises a sintered intimate mixture of powdered metal and glass particles. The term "glass" includes enamel and the term "metal" includes alloys. The glass has softening point below the M.P. of the metal and within \sB100 DEG C. of the sintering temperature of the metal, and is water-leachable at a rate of 50-10,000 p.p.m. of corrosion-inhibiting ions when agitated in the ratio 1 part glass to 2 parts distilled water for 4 hours at room temperature. Corrosion-inhibiting ions include chromate, tungstate, molybdate, nitrite, nitrate, phosphate, ferrate, silicate. The glass may contain a colourant. The glass may also contain corrosion inhibitors which release corrosion-inhibiting ions concurrently with those released by dissolution of the glass. Metals include Al, Mg, Zn, Fe and Cu. Articles may be made by dry-mixing the glass and metal powders, preferably finer than 100-mesh, U.S.S. sieve, e.g. 5-41 volume per cent being glass, cold-pressing to obtain a green compact of 9
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The glass has softening point below the m.p. of the metal and within \sB 100 DEG C. of the sintering temperature of the metal, and is waterleachable at a rate of 50-10,000 p.p.m. of corrosion-inhibiting ions when agitated in the ratio 1 part glass to 2 parts distilled water for 4 hours at room temperature. Corrosion-inhibiting ions include chromate, tungstate, molybdate, nitrite, nitrate, phosphate, ferrate, and silicate. The glass may contain a colourant. The glass may also contain corrosion inhibitors which release corrosion-inhibiting ions concurrently with those released by dissolution of the glass. Metals include Al, Mg, Zn, Fe and Cu. Articles may be made by dry-mixing the glass and metal powders, preferably finer than 100-mesh, U.S.S. sieve, e.g. 5-41 volume % being glass, cold-pressing to obtain a green compact of 90% theoretical density, and sintering e.g. in an Ar/H2 atmosphere. The hot sintered composite may be mechanically worked, e.g. by forging, rolling or extrusion. Al-glass articles may be etched in 2% NaOH to provide a matte finish. The bodies may be enamelled, and the material may be used as an undercoat for enamelling. Multilayered structures may be made ranging from metal to pure glass with intervening gradations of metal-glass composites.ALSO:A corrosion-resistant composite material comprises a sintered intimate mixture of powdered metal and glass particles. The term "glass" includes enamel and the term "metal" includes alloys. The glass has softening point below the M.P. of the metal and within \sB100 DEG C. of the sintering temperature of the metal, and is water-leachable at a rate of 50-10,000 p.p.m. of corrosion-inhibiting ions when agitated in the ratio 1 part glass to 2 parts distilled water for 4 hours at room temperature. Corrosion-inhibiting ions include chromate, tungstate, molybdate, nitrite, nitrate, phosphate, ferrate, silicate. The glass may contain a colourant. The glass may also contain corrosion inhibitors which release corrosion-inhibiting ions concurrently with those released by dissolution of the glass. Metals include Al, Mg, Zn, Fe and Cu. Articles may be made by dry-mixing the glass and metal powders, preferably finer than 100-mesh, U.S.S. sieve, e.g. 5-41 volume per cent being glass, cold-pressing to obtain a green compact of 90% theoretical density, and sintering, e.g. in an Ar/H2 atmosphere. The hot sintered composite may be mechanically worked, e.g. by forging, rolling or extrusion. Al-glass articles may be etched in 2% NaOH to provide a matte finish. The bodies may be enamelled, and the material may be used as an undercoat for enamelling. 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The term 'glass' includes enamel and the term 'metal' includes alloys. The glass has softening point below the m.p. of the metal and within \sB 100 DEG C. of the sintering temperature of the metal, and is waterleachable at a rate of 50-10,000 p.p.m. of corrosion-inhibiting ions when agitated in the ratio 1 part glass to 2 parts distilled water for 4 hours at room temperature. Corrosion-inhibiting ions include chromate, tungstate, molybdate, nitrite, nitrate, phosphate, ferrate, and silicate. The glass may contain a colourant. The glass may also contain corrosion inhibitors which release corrosion-inhibiting ions concurrently with those released by dissolution of the glass. Metals include Al, Mg, Zn, Fe and Cu. Articles may be made by dry-mixing the glass and metal powders, preferably finer than 100-mesh, U.S.S. sieve, e.g. 5-41 volume % being glass, cold-pressing to obtain a green compact of 90% theoretical density, and sintering e.g. in an Ar/H2 atmosphere. The hot sintered composite may be mechanically worked, e.g. by forging, rolling or extrusion. Al-glass articles may be etched in 2% NaOH to provide a matte finish. The bodies may be enamelled, and the material may be used as an undercoat for enamelling. Multilayered structures may be made ranging from metal to pure glass with intervening gradations of metal-glass composites.ALSO:A corrosion-resistant composite material comprises a sintered intimate mixture of powdered metal and glass particles. The term "glass" includes enamel and the term "metal" includes alloys. The glass has softening point below the M.P. of the metal and within \sB100 DEG C. of the sintering temperature of the metal, and is water-leachable at a rate of 50-10,000 p.p.m. of corrosion-inhibiting ions when agitated in the ratio 1 part glass to 2 parts distilled water for 4 hours at room temperature. Corrosion-inhibiting ions include chromate, tungstate, molybdate, nitrite, nitrate, phosphate, ferrate, silicate. The glass may contain a colourant. The glass may also contain corrosion inhibitors which release corrosion-inhibiting ions concurrently with those released by dissolution of the glass. Metals include Al, Mg, Zn, Fe and Cu. Articles may be made by dry-mixing the glass and metal powders, preferably finer than 100-mesh, U.S.S. sieve, e.g. 5-41 volume per cent being glass, cold-pressing to obtain a green compact of 90% theoretical density, and sintering, e.g. in an Ar/H2 atmosphere. The hot sintered composite may be mechanically worked, e.g. by forging, rolling or extrusion. Al-glass articles may be etched in 2% NaOH to provide a matte finish. The bodies may be enamelled, and the material may be used as an undercoat for enamelling. Multi-layered structures may be made ranging from metal to pure glass with intervening gradations of metal-glass composites.</description><subject>ALLOYS</subject><subject>CHEMICAL COMPOSITION OF GLASSES, GLAZES, OR VITREOUSENAMELS</subject><subject>CHEMISTRY</subject><subject>FERROUS OR NON-FERROUS ALLOYS</subject><subject>GLASS</subject><subject>JOINING GLASS TO GLASS OR OTHER MATERIALS</subject><subject>METALLURGY</subject><subject>MINERAL OR SLAG WOOL</subject><subject>SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS,MINERALS OR SLAGS</subject><subject>SURFACE TREATMENT OF GLASS</subject><subject>TREATMENT OF ALLOYS OR NON-FERROUS METALS</subject><fulltext>true</fulltext><rsrctype>patent</rsrctype><creationdate>1965</creationdate><recordtype>patent</recordtype><sourceid>EVB</sourceid><recordid>eNrjZJB3zi8qyi_OzM_TzczLyEzKLElNUchNLUnM0U3PSSwu5mFgTUvMKU7lhdLcDPJuriHOHrqpBfnxqcUFicmpeakl8aHBxkYGpqZmZo7GhFUAALgEJHs</recordid><startdate>19650914</startdate><enddate>19650914</enddate><creator>BRETON ERNEST J</creator><scope>EVB</scope></search><sort><creationdate>19650914</creationdate><title>Corrosion-inhibited metal-glass</title><author>BRETON ERNEST J</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-epo_espacenet_US3205566A3</frbrgroupid><rsrctype>patents</rsrctype><prefilter>patents</prefilter><language>eng</language><creationdate>1965</creationdate><topic>ALLOYS</topic><topic>CHEMICAL COMPOSITION OF GLASSES, GLAZES, OR VITREOUSENAMELS</topic><topic>CHEMISTRY</topic><topic>FERROUS OR NON-FERROUS ALLOYS</topic><topic>GLASS</topic><topic>JOINING GLASS TO GLASS OR OTHER MATERIALS</topic><topic>METALLURGY</topic><topic>MINERAL OR SLAG WOOL</topic><topic>SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS,MINERALS OR SLAGS</topic><topic>SURFACE TREATMENT OF GLASS</topic><topic>TREATMENT OF ALLOYS OR NON-FERROUS METALS</topic><toplevel>online_resources</toplevel><creatorcontrib>BRETON ERNEST J</creatorcontrib><collection>esp@cenet</collection></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext_linktorsrc</fulltext></delivery><addata><au>BRETON ERNEST J</au><format>patent</format><genre>patent</genre><ristype>GEN</ristype><title>Corrosion-inhibited metal-glass</title><date>1965-09-14</date><risdate>1965</risdate><abstract>A corrosion-resistant composite material comprises a sintered intimate mixture of powdered metal and glass particles. The term 'glass' includes enamel and the term 'metal' includes alloys. The glass has softening point below the m.p. of the metal and within \sB 100 DEG C. of the sintering temperature of the metal, and is waterleachable at a rate of 50-10,000 p.p.m. of corrosion-inhibiting ions when agitated in the ratio 1 part glass to 2 parts distilled water for 4 hours at room temperature. Corrosion-inhibiting ions include chromate, tungstate, molybdate, nitrite, nitrate, phosphate, ferrate, and silicate. The glass may contain a colourant. The glass may also contain corrosion inhibitors which release corrosion-inhibiting ions concurrently with those released by dissolution of the glass. Metals include Al, Mg, Zn, Fe and Cu. Articles may be made by dry-mixing the glass and metal powders, preferably finer than 100-mesh, U.S.S. sieve, e.g. 5-41 volume % being glass, cold-pressing to obtain a green compact of 90% theoretical density, and sintering e.g. in an Ar/H2 atmosphere. The hot sintered composite may be mechanically worked, e.g. by forging, rolling or extrusion. Al-glass articles may be etched in 2% NaOH to provide a matte finish. The bodies may be enamelled, and the material may be used as an undercoat for enamelling. Multilayered structures may be made ranging from metal to pure glass with intervening gradations of metal-glass composites.ALSO:A corrosion-resistant composite material comprises a sintered intimate mixture of powdered metal and glass particles. The term "glass" includes enamel and the term "metal" includes alloys. The glass has softening point below the M.P. of the metal and within \sB100 DEG C. of the sintering temperature of the metal, and is water-leachable at a rate of 50-10,000 p.p.m. of corrosion-inhibiting ions when agitated in the ratio 1 part glass to 2 parts distilled water for 4 hours at room temperature. Corrosion-inhibiting ions include chromate, tungstate, molybdate, nitrite, nitrate, phosphate, ferrate, silicate. The glass may contain a colourant. The glass may also contain corrosion inhibitors which release corrosion-inhibiting ions concurrently with those released by dissolution of the glass. Metals include Al, Mg, Zn, Fe and Cu. Articles may be made by dry-mixing the glass and metal powders, preferably finer than 100-mesh, U.S.S. sieve, e.g. 5-41 volume per cent being glass, cold-pressing to obtain a green compact of 90% theoretical density, and sintering, e.g. in an Ar/H2 atmosphere. The hot sintered composite may be mechanically worked, e.g. by forging, rolling or extrusion. Al-glass articles may be etched in 2% NaOH to provide a matte finish. The bodies may be enamelled, and the material may be used as an undercoat for enamelling. Multi-layered structures may be made ranging from metal to pure glass with intervening gradations of metal-glass composites.</abstract><oa>free_for_read</oa></addata></record>
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subjects ALLOYS
CHEMICAL COMPOSITION OF GLASSES, GLAZES, OR VITREOUSENAMELS
CHEMISTRY
FERROUS OR NON-FERROUS ALLOYS
GLASS
JOINING GLASS TO GLASS OR OTHER MATERIALS
METALLURGY
MINERAL OR SLAG WOOL
SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS,MINERALS OR SLAGS
SURFACE TREATMENT OF GLASS
TREATMENT OF ALLOYS OR NON-FERROUS METALS
title Corrosion-inhibited metal-glass
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