Electrodeionization Configuration for Enhanced Boron Removal

Electrochemical water treatment devices are disclosed. The device includes an electrochemical separation module fluidly connectable to the source of water to be treated. The electrochemical separation module includes a first electrode, a second electrode, and a plurality of dilution compartments. Each of the dilution compartments includes a first region of ion exchange media having a first average particle size, a second region of ion exchange media having a second average particle size, and a third region of ion exchange media having a third average particle size. A volume of the second region of ion exchange media being greater than or equal to a total volume of the first and third regions of ion exchange media. Methods of facilitating treatment of water containing weakly ionized species, e.g., dissolved boron containing species and dissolved silica containing species, are disclosed. Electrochemical separation modules are also disclosed.