PD-CATALYZED AMINATION OF FLUORINATED ARYL CHLORIDES

The presently claimed invention relates to a process for the preparation of di-, tri-, or tetra fluoroarylamine by reacting polyfluorinated aryl chlorides with ammonia in the presence of a base, a metal catalyst and a ligand. Di-, tri-, tetrafluoroarylamines are valuable intermediates and find appli...

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Hauptverfasser: Kaduskar, Rahul, Borate, Kailaskumar, Shinde, Harish, Goetz, Roland, Thirunavukkarasu, Saravanan
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creator Kaduskar, Rahul
Borate, Kailaskumar
Shinde, Harish
Goetz, Roland
Thirunavukkarasu, Saravanan
description The presently claimed invention relates to a process for the preparation of di-, tri-, or tetra fluoroarylamine by reacting polyfluorinated aryl chlorides with ammonia in the presence of a base, a metal catalyst and a ligand. Di-, tri-, tetrafluoroarylamines are valuable intermediates and find application in several areas, mainly in epoxy polymers, colorants, dyes, polyurethanes, agrochemicals and pharmaceutical active agents.
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subjects ACYCLIC OR CARBOCYCLIC COMPOUNDS
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY
CHEMISTRY
METALLURGY
ORGANIC CHEMISTRY
PERFORMING OPERATIONS
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
THEIR RELEVANT APPARATUS
TRANSPORTING
title PD-CATALYZED AMINATION OF FLUORINATED ARYL CHLORIDES
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