DUAL METALLOCENE POLYETHYLENE WITH IMPROVED PROCESSABILITY FOR LIGHTWEIGHT BLOW MOLDED PRODUCTS

DUAL METALLOCENE POLYETHYLENE WITH IMPROVED PROCESSABILITY FOR LIGHTWEIGHT BLOW MOLDED PRODUCTS

Ethylene-based polymers having a density of 0.952 to 0.968 g/cm3, a ratio of HLMI/MI from 185 to 550, an IB parameter from 1.46 to 1.80, a tan δ at 0.1 sec−1 from 1.05 to 1.75 degrees, and a slope of a plot of viscosity versus shear rate at 100 sec−1 from 0.18 to 0.28 are described, with low melt fl...

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Hauptverfasser: Praetorius, Jeremy M, Rutledge-Ryal, Brandy, Cruz, Carlos A, Chaffin, Jay M, Brown, JR., Alfred E, Inn, Yongwoo
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CHEMISTRY
COMPOSITIONS BASED THEREON
MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS
METALLURGY
ORGANIC MACROMOLECULAR COMPOUNDS
THEIR PREPARATION OR CHEMICAL WORKING-UP
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creator Praetorius, Jeremy M
Rutledge-Ryal, Brandy
Cruz, Carlos A
Chaffin, Jay M
Brown, JR., Alfred E
Inn, Yongwoo
description Ethylene-based polymers having a density of 0.952 to 0.968 g/cm3, a ratio of HLMI/MI from 185 to 550, an IB parameter from 1.46 to 1.80, a tan δ at 0.1 sec−1 from 1.05 to 1.75 degrees, and a slope of a plot of viscosity versus shear rate at 100 sec−1 from 0.18 to 0.28 are described, with low melt flow versions having a HLMI from 10 to 30 g/10 min and a Mw from 250,000 to 450,000 g/mol, and high melt flow versions having a HLMI from 30 to 55 g/10 min and a Mw from 200,000 to 300,000 g/mol. These polymers have the processability of chromium-based resins, but with improved stress crack resistance and topload strength for bottles and other blow molded products.
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subjects CHEMISTRY
COMPOSITIONS BASED THEREON
MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS
METALLURGY
ORGANIC MACROMOLECULAR COMPOUNDS
THEIR PREPARATION OR CHEMICAL WORKING-UP
title DUAL METALLOCENE POLYETHYLENE WITH IMPROVED PROCESSABILITY FOR LIGHTWEIGHT BLOW MOLDED PRODUCTS
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