METHODS FOR CELLULOSE HYDROLYSIS USING SULFONATED POLYAROMATIC CATALYSTS

The disclosure relates to a method for hydrolyzing cellulosic material using a sulfonated polyaromatic catalyst. A cellulosic material is combined with the sulfonated polyaromatic catalyst in water to at least partially hydrolyze the cellulosic material and to form a monosaccharide hydrolysis produc...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Hauptverfasser: Jackson, James E, Redko, Mikhail, Saffron, Christopher M, Kilponen, Kyle Mtthew
Format: Patent
Sprache:eng
Schlagworte:
Online-Zugang:Volltext bestellen
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page
container_issue
container_start_page
container_title
container_volume
creator Jackson, James E
Redko, Mikhail
Saffron, Christopher M
Kilponen, Kyle Mtthew
description The disclosure relates to a method for hydrolyzing cellulosic material using a sulfonated polyaromatic catalyst. A cellulosic material is combined with the sulfonated polyaromatic catalyst in water to at least partially hydrolyze the cellulosic material and to form a monosaccharide hydrolysis product, thereby forming a reaction mixture including (i) an aqueous phase with the monosaccharide hydrolysis product in solution therein, and (ii) a dispersed phase including the sulfonated polyaromatic catalyst as well as any non-hydrolyzed cellulosic material. The sulfonated polyaromatic catalyst includes a mixture of partially sulfonated polycyclic aromatic hydrocarbons that is substantially insoluble in the aqueous phase, thus providing it with an affinity for the water-insoluble cellulosic substrate where it preferentially exhibits its catalytic hydrolytic activity. The monosaccharide hydrolysis product can be recovered from the aqueous phase of the reaction mixture.
format Patent
fullrecord <record><control><sourceid>epo_EVB</sourceid><recordid>TN_cdi_epo_espacenet_US2022001367A1</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>US2022001367A1</sourcerecordid><originalsourceid>FETCH-epo_espacenet_US2022001367A13</originalsourceid><addsrcrecordid>eNrjZPDwdQ3x8HcJVnDzD1JwdvXxCfXxD3ZV8Ih0CfL3iQz2DFYIDfb0c1cIDvVx8_dzDHF1UQgASjgG-fs6hng6Kzg7hjgC1YUE8zCwpiXmFKfyQmluBmU31xBnD93Ugvz41OKCxOTUvNSS-NBgIwMjIwMDQ2Mzc0dDY-JUAQASRi51</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>patent</recordtype></control><display><type>patent</type><title>METHODS FOR CELLULOSE HYDROLYSIS USING SULFONATED POLYAROMATIC CATALYSTS</title><source>esp@cenet</source><creator>Jackson, James E ; Redko, Mikhail ; Saffron, Christopher M ; Kilponen, Kyle Mtthew</creator><creatorcontrib>Jackson, James E ; Redko, Mikhail ; Saffron, Christopher M ; Kilponen, Kyle Mtthew</creatorcontrib><description>The disclosure relates to a method for hydrolyzing cellulosic material using a sulfonated polyaromatic catalyst. A cellulosic material is combined with the sulfonated polyaromatic catalyst in water to at least partially hydrolyze the cellulosic material and to form a monosaccharide hydrolysis product, thereby forming a reaction mixture including (i) an aqueous phase with the monosaccharide hydrolysis product in solution therein, and (ii) a dispersed phase including the sulfonated polyaromatic catalyst as well as any non-hydrolyzed cellulosic material. The sulfonated polyaromatic catalyst includes a mixture of partially sulfonated polycyclic aromatic hydrocarbons that is substantially insoluble in the aqueous phase, thus providing it with an affinity for the water-insoluble cellulosic substrate where it preferentially exhibits its catalytic hydrolytic activity. The monosaccharide hydrolysis product can be recovered from the aqueous phase of the reaction mixture.</description><language>eng</language><subject>CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY ; CHEMISTRY ; COMPOSITIONS BASED THEREON ; DERIVATIVES THEREOF ; METALLURGY ; ORGANIC MACROMOLECULAR COMPOUNDS ; PERFORMING OPERATIONS ; PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL ; POLYSACCHARIDES ; THEIR PREPARATION OR CHEMICAL WORKING-UP ; THEIR RELEVANT APPARATUS ; TRANSPORTING</subject><creationdate>2022</creationdate><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&amp;date=20220106&amp;DB=EPODOC&amp;CC=US&amp;NR=2022001367A1$$EHTML$$P50$$Gepo$$Hfree_for_read</linktohtml><link.rule.ids>230,308,780,885,25564,76547</link.rule.ids><linktorsrc>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&amp;date=20220106&amp;DB=EPODOC&amp;CC=US&amp;NR=2022001367A1$$EView_record_in_European_Patent_Office$$FView_record_in_$$GEuropean_Patent_Office$$Hfree_for_read</linktorsrc></links><search><creatorcontrib>Jackson, James E</creatorcontrib><creatorcontrib>Redko, Mikhail</creatorcontrib><creatorcontrib>Saffron, Christopher M</creatorcontrib><creatorcontrib>Kilponen, Kyle Mtthew</creatorcontrib><title>METHODS FOR CELLULOSE HYDROLYSIS USING SULFONATED POLYAROMATIC CATALYSTS</title><description>The disclosure relates to a method for hydrolyzing cellulosic material using a sulfonated polyaromatic catalyst. A cellulosic material is combined with the sulfonated polyaromatic catalyst in water to at least partially hydrolyze the cellulosic material and to form a monosaccharide hydrolysis product, thereby forming a reaction mixture including (i) an aqueous phase with the monosaccharide hydrolysis product in solution therein, and (ii) a dispersed phase including the sulfonated polyaromatic catalyst as well as any non-hydrolyzed cellulosic material. The sulfonated polyaromatic catalyst includes a mixture of partially sulfonated polycyclic aromatic hydrocarbons that is substantially insoluble in the aqueous phase, thus providing it with an affinity for the water-insoluble cellulosic substrate where it preferentially exhibits its catalytic hydrolytic activity. The monosaccharide hydrolysis product can be recovered from the aqueous phase of the reaction mixture.</description><subject>CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY</subject><subject>CHEMISTRY</subject><subject>COMPOSITIONS BASED THEREON</subject><subject>DERIVATIVES THEREOF</subject><subject>METALLURGY</subject><subject>ORGANIC MACROMOLECULAR COMPOUNDS</subject><subject>PERFORMING OPERATIONS</subject><subject>PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL</subject><subject>POLYSACCHARIDES</subject><subject>THEIR PREPARATION OR CHEMICAL WORKING-UP</subject><subject>THEIR RELEVANT APPARATUS</subject><subject>TRANSPORTING</subject><fulltext>true</fulltext><rsrctype>patent</rsrctype><creationdate>2022</creationdate><recordtype>patent</recordtype><sourceid>EVB</sourceid><recordid>eNrjZPDwdQ3x8HcJVnDzD1JwdvXxCfXxD3ZV8Ih0CfL3iQz2DFYIDfb0c1cIDvVx8_dzDHF1UQgASjgG-fs6hng6Kzg7hjgC1YUE8zCwpiXmFKfyQmluBmU31xBnD93Ugvz41OKCxOTUvNSS-NBgIwMjIwMDQ2Mzc0dDY-JUAQASRi51</recordid><startdate>20220106</startdate><enddate>20220106</enddate><creator>Jackson, James E</creator><creator>Redko, Mikhail</creator><creator>Saffron, Christopher M</creator><creator>Kilponen, Kyle Mtthew</creator><scope>EVB</scope></search><sort><creationdate>20220106</creationdate><title>METHODS FOR CELLULOSE HYDROLYSIS USING SULFONATED POLYAROMATIC CATALYSTS</title><author>Jackson, James E ; Redko, Mikhail ; Saffron, Christopher M ; Kilponen, Kyle Mtthew</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-epo_espacenet_US2022001367A13</frbrgroupid><rsrctype>patents</rsrctype><prefilter>patents</prefilter><language>eng</language><creationdate>2022</creationdate><topic>CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY</topic><topic>CHEMISTRY</topic><topic>COMPOSITIONS BASED THEREON</topic><topic>DERIVATIVES THEREOF</topic><topic>METALLURGY</topic><topic>ORGANIC MACROMOLECULAR COMPOUNDS</topic><topic>PERFORMING OPERATIONS</topic><topic>PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL</topic><topic>POLYSACCHARIDES</topic><topic>THEIR PREPARATION OR CHEMICAL WORKING-UP</topic><topic>THEIR RELEVANT APPARATUS</topic><topic>TRANSPORTING</topic><toplevel>online_resources</toplevel><creatorcontrib>Jackson, James E</creatorcontrib><creatorcontrib>Redko, Mikhail</creatorcontrib><creatorcontrib>Saffron, Christopher M</creatorcontrib><creatorcontrib>Kilponen, Kyle Mtthew</creatorcontrib><collection>esp@cenet</collection></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext_linktorsrc</fulltext></delivery><addata><au>Jackson, James E</au><au>Redko, Mikhail</au><au>Saffron, Christopher M</au><au>Kilponen, Kyle Mtthew</au><format>patent</format><genre>patent</genre><ristype>GEN</ristype><title>METHODS FOR CELLULOSE HYDROLYSIS USING SULFONATED POLYAROMATIC CATALYSTS</title><date>2022-01-06</date><risdate>2022</risdate><abstract>The disclosure relates to a method for hydrolyzing cellulosic material using a sulfonated polyaromatic catalyst. A cellulosic material is combined with the sulfonated polyaromatic catalyst in water to at least partially hydrolyze the cellulosic material and to form a monosaccharide hydrolysis product, thereby forming a reaction mixture including (i) an aqueous phase with the monosaccharide hydrolysis product in solution therein, and (ii) a dispersed phase including the sulfonated polyaromatic catalyst as well as any non-hydrolyzed cellulosic material. The sulfonated polyaromatic catalyst includes a mixture of partially sulfonated polycyclic aromatic hydrocarbons that is substantially insoluble in the aqueous phase, thus providing it with an affinity for the water-insoluble cellulosic substrate where it preferentially exhibits its catalytic hydrolytic activity. The monosaccharide hydrolysis product can be recovered from the aqueous phase of the reaction mixture.</abstract><oa>free_for_read</oa></addata></record>
fulltext fulltext_linktorsrc
identifier
ispartof
issn
language eng
recordid cdi_epo_espacenet_US2022001367A1
source esp@cenet
subjects CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY
CHEMISTRY
COMPOSITIONS BASED THEREON
DERIVATIVES THEREOF
METALLURGY
ORGANIC MACROMOLECULAR COMPOUNDS
PERFORMING OPERATIONS
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
POLYSACCHARIDES
THEIR PREPARATION OR CHEMICAL WORKING-UP
THEIR RELEVANT APPARATUS
TRANSPORTING
title METHODS FOR CELLULOSE HYDROLYSIS USING SULFONATED POLYAROMATIC CATALYSTS
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-25T19%3A05%3A05IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-epo_EVB&rft_val_fmt=info:ofi/fmt:kev:mtx:patent&rft.genre=patent&rft.au=Jackson,%20James%20E&rft.date=2022-01-06&rft_id=info:doi/&rft_dat=%3Cepo_EVB%3EUS2022001367A1%3C/epo_EVB%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true