METHODS FOR CELLULOSE HYDROLYSIS USING SULFONATED POLYAROMATIC CATALYSTS
The disclosure relates to a method for hydrolyzing cellulosic material using a sulfonated polyaromatic catalyst. A cellulosic material is combined with the sulfonated polyaromatic catalyst in water to at least partially hydrolyze the cellulosic material and to form a monosaccharide hydrolysis produc...
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creator | Jackson, James E Redko, Mikhail Saffron, Christopher M Kilponen, Kyle Mtthew |
description | The disclosure relates to a method for hydrolyzing cellulosic material using a sulfonated polyaromatic catalyst. A cellulosic material is combined with the sulfonated polyaromatic catalyst in water to at least partially hydrolyze the cellulosic material and to form a monosaccharide hydrolysis product, thereby forming a reaction mixture including (i) an aqueous phase with the monosaccharide hydrolysis product in solution therein, and (ii) a dispersed phase including the sulfonated polyaromatic catalyst as well as any non-hydrolyzed cellulosic material. The sulfonated polyaromatic catalyst includes a mixture of partially sulfonated polycyclic aromatic hydrocarbons that is substantially insoluble in the aqueous phase, thus providing it with an affinity for the water-insoluble cellulosic substrate where it preferentially exhibits its catalytic hydrolytic activity. The monosaccharide hydrolysis product can be recovered from the aqueous phase of the reaction mixture. |
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subjects | CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY CHEMISTRY COMPOSITIONS BASED THEREON DERIVATIVES THEREOF METALLURGY ORGANIC MACROMOLECULAR COMPOUNDS PERFORMING OPERATIONS PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL POLYSACCHARIDES THEIR PREPARATION OR CHEMICAL WORKING-UP THEIR RELEVANT APPARATUS TRANSPORTING |
title | METHODS FOR CELLULOSE HYDROLYSIS USING SULFONATED POLYAROMATIC CATALYSTS |
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