TRANSPARENT BRANCHED POLYCARBONATE
A method for preparing a modified polycarbonate comprising i) providing a polycarbonate prepared by the melt transesterification of a bisphenol and a diaryl carbonate preferably having a Fries branching level of from 750 to 2000 ppm, ii) combining said polycarbonate and from 0.10-0.75 wt. %, based o...
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| creator | Thelakkadan, Abdul Salam Ponniah, Thavamani Singh, Rajendra Li, Sijun Jha, Roshan Kumar |
| description | A method for preparing a modified polycarbonate comprising i) providing a polycarbonate prepared by the melt transesterification of a bisphenol and a diaryl carbonate preferably having a Fries branching level of from 750 to 2000 ppm, ii) combining said polycarbonate and from 0.10-0.75 wt. %, based on the amount of polycarbonate, of a modifier, iii) reacting said modifier and said polycarbonate in molten state at a temperature of from 250-300° C. and a reaction time of at least 30 seconds so as to form the modified polycarbonate, wherein said modifier is a styrene-(meth)acrylate copolymer containing glycidyl groups and having i) from 250 to 500 gram epoxy groups per mol and ii) a weight average molecular weight of from 3000 to 8500 g/mol, and wherein said modified polycarbonate has a transmittance of at least 85% and a haze of at most 5% as determined in accordance with ASTM D1003-13 on an injection moulded sheet having a thickness of 3 mm. |
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| subjects | CHEMISTRY COMPOSITIONS BASED THEREON COMPOSITIONS OF MACROMOLECULAR COMPOUNDS MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONSONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS METALLURGY ORGANIC MACROMOLECULAR COMPOUNDS THEIR PREPARATION OR CHEMICAL WORKING-UP |
| title | TRANSPARENT BRANCHED POLYCARBONATE |
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