METHOD FOR POLYOL SYNTHESIS FROM TRIACYLGLYCERIDE OILS

A method for preparation of polyols from an unsaturated TAG oil that involves first epoxidizing the unsaturated TAG oil; then subjecting the epoxidized TAG oil to transesterification using a diol and/or triol in the presence of a catalyst to produce hydroxyalkyl esters of fatty acid epoxides; and fi...

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Hauptverfasser: CURTIS, Jonathan M, KONG, Xiaohua, TAVASSOLI-KAFRANI, Hossein M, KHARRAZ, Ereddad, OMONOV, Tolibjon S
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creator CURTIS, Jonathan M
KONG, Xiaohua
TAVASSOLI-KAFRANI, Hossein M
KHARRAZ, Ereddad
OMONOV, Tolibjon S
description A method for preparation of polyols from an unsaturated TAG oil that involves first epoxidizing the unsaturated TAG oil; then subjecting the epoxidized TAG oil to transesterification using a diol and/or triol in the presence of a catalyst to produce hydroxyalkyl esters of fatty acid epoxides; and finally hydroxylating the transesterification product using a diol and/or triol and a solid acid catalyst to obtain a polyol with relatively high hydroxyl value and low viscosity.
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subjects ACYCLIC OR CARBOCYCLIC COMPOUNDS
ANIMAL AND VEGETABLE OILS, FATS, FATTY SUBSTANCES AND WAXES
CANDLES
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY
CHEMISTRY
DETERGENTS
FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS,OILS, OR FATTY ACIDS OBTAINED THEREFROM
FATTY ACIDS FROM FATS, OILS OR WAXES
FATTY ACIDS THEREFROM
METALLURGY
ORGANIC CHEMISTRY
PERFORMING OPERATIONS
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
THEIR RELEVANT APPARATUS
TRANSPORTING
title METHOD FOR POLYOL SYNTHESIS FROM TRIACYLGLYCERIDE OILS
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