Phenolytic Kinetic Resolution of Azido and Alkoxy Epoxides

Phenolytic Kinetic Resolution of Azido and Alkoxy Epoxides

Disclosed herein is a single step catalytic process for the production of enantiomerically pure α-Aryloxy-α′-Azido/Alkoxy alcohols of formula (A). The invention, in particular discloses phenolytic kinetic resolution of racemic anti and syn azido/alkoxy epoxides to generate two stereocentres of high...

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Hauptverfasser: KAMBLE DAYANAND AMBADAS, SUDALAI ARUMUGAM, KARABAL PRATIBHA UTTAM
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ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM
CHEMISTRY
METALLURGY
ORGANIC CHEMISTRY
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creator KAMBLE DAYANAND AMBADAS
SUDALAI ARUMUGAM
KARABAL PRATIBHA UTTAM
description Disclosed herein is a single step catalytic process for the production of enantiomerically pure α-Aryloxy-α′-Azido/Alkoxy alcohols of formula (A). The invention, in particular discloses phenolytic kinetic resolution of racemic anti and syn azido/alkoxy epoxides to generate two stereocentres of high optical purities of formula (A).
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subjects ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM
CHEMISTRY
METALLURGY
ORGANIC CHEMISTRY
title Phenolytic Kinetic Resolution of Azido and Alkoxy Epoxides
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