Method and Membrane for Nanoporous, Bicontinuous Cubic Lyotropic Liquid Crystal Polymer Membranes that Enable Facile Film Processing and Pore Size Control

A method of forming a nanoporous membrane includes preparing a solution of a gemini Imidazolium Lyotropic Liquid Crystal (LLC) monomer, a polar low-volatility organic solvent, and a radical photo-initiator in a volatile organic solvent; solvent-casting the solution onto a porous material, evaporatin...

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Hauptverfasser: HATAKEYAMA EVAN S, NOBLE RICHARD D, WIESENAUER BRIAN R, BARTON JOHN L, GIN DOUGLAS L, CARTER BLAINE M
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creator HATAKEYAMA EVAN S
NOBLE RICHARD D
WIESENAUER BRIAN R
BARTON JOHN L
GIN DOUGLAS L
CARTER BLAINE M
description A method of forming a nanoporous membrane includes preparing a solution of a gemini Imidazolium Lyotropic Liquid Crystal (LLC) monomer, a polar low-volatility organic solvent, and a radical photo-initiator in a volatile organic solvent; solvent-casting the solution onto a porous material, evaporating the volatile organic solvent; heating such that the gemini imidazolium monomer forms a Q-phase material and photopolymerizing the imidazolium monomer by exposing the radical photo-initiator to UV light; and exchanging the polar low-volatility organic solvent. Also disclosed is a membrane composed of polymerized gemini imidazolium LLC monomers, and a thin-film composite membrane having the Q-phase material supported on a porous supporting membrane.
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subjects AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F,C08G
CHEMISTRY
COMPOSITIONS BASED THEREON
GENERAL PROCESSES OF COMPOUNDING
MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS
METALLURGY
ORGANIC MACROMOLECULAR COMPOUNDS
THEIR PREPARATION OR CHEMICAL WORKING-UP
WORKING-UP
title Method and Membrane for Nanoporous, Bicontinuous Cubic Lyotropic Liquid Crystal Polymer Membranes that Enable Facile Film Processing and Pore Size Control
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