SILICA-BASED SOLS

A process for the production of an aqueous sol containing silica-based particles which comprises (a) acidifying an aqueous silicate solution to a pH of from 1 to 4 to form an acid sol; (b) alkalising the acid sol at an SiO2 content within the range of from 4.5 to 8% by weight; (c) allowing particle...

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Hauptverfasser: TOKARZ MAREK, JOHANSSON-VESTIN HANS, DAHLGREN MAJ-LIS, PERSSON MICHAEL
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creator TOKARZ MAREK
JOHANSSON-VESTIN HANS
DAHLGREN MAJ-LIS
PERSSON MICHAEL
description A process for the production of an aqueous sol containing silica-based particles which comprises (a) acidifying an aqueous silicate solution to a pH of from 1 to 4 to form an acid sol; (b) alkalising the acid sol at an SiO2 content within the range of from 4.5 to 8% by weight; (c) allowing particle growth of the alkalised sol for at least 10 minutes; or heat-treating the alkalised sol at a temperature of a least 30° C.; (d) alkalising the obtained sol to a pH of at least 10.0; and (e) optionally concentrating the sol obtained according to (b), (c) or (d) to provide an aqueous sol containing silica-based particles and having a specific surface area of at least 90 m2/g aqueous sol; as well as an aqueous sol containing silica-based particles obtainable by the process. The invention also relates to an aqueous sol containing silica-based particles which sol has a specific surface area of at least 115 m2/g aqueous sol and an S-value within the range of from 10 to 45% or contains silica-based particles having a specific surface area of at least 550 and less than 1000 m2/g SiO2. The invention further relates to the use of the aqueous sol containing silica-based particles as a drainage and retention aid in the production of paper as well as a process for the production of paper from an aqueous suspension containing cellulosic fibres, and optional filler, in which silica-based particles and at least one charged organic polymer are added to the cellulosic suspension.
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The invention also relates to an aqueous sol containing silica-based particles which sol has a specific surface area of at least 115 m2/g aqueous sol and an S-value within the range of from 10 to 45% or contains silica-based particles having a specific surface area of at least 550 and less than 1000 m2/g SiO2. 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recordid cdi_epo_espacenet_US2011196047A1
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subjects CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY
CHEMISTRY
COMPOUNDS THEREOF
IMPREGNATING OR COATING OF PAPER
INORGANIC CHEMISTRY
METALLURGY
MIXING, e.g. DISSOLVING, EMULSIFYING, DISPERSING
NON-METALLIC ELEMENTS
PAPER NOT OTHERWISE PROVIDED FOR
PAPER-MAKING
PERFORMING OPERATIONS
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D
PRODUCTION OF CELLULOSE
PULP COMPOSITIONS
TEXTILES
THEIR RELEVANT APPARATUS
TRANSPORTING
TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G
title SILICA-BASED SOLS
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