CATALYST FOR VAPOUR CONVERSION OF CARBON MONOXIDE METHODS FOR THE PRODUCTION AND FOR THE USE THEREOF

The invention relates to producing hydrogen by means of the vapour conversion of carbon monoxide and a catalyst for said process and can be used in different industries. The invention discloses an iron-chromium catalyst containing an iron-chromium hydroxyl compound phase having a goethite and/or hyd...

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Hauptverfasser: POSOKHOVA OLGA MIKHAILOVNA, BOCHAROV ALEXANDR PETROVICH, LEBEDEVA MARINA VALERIEVNA, BARONSKAYA NATALYA ALEKSEEVNA, ANDREEVA TATYANA IVANOVNA, JURIEVA TAMARA MIKHAILOVNA, TSELJUTINA MARINA IVANOVNA, PLYASOVA LJUDMILA MIKHAILOVNA, REZNICHENKO IRINA DMITRIEVNA, VOLCHATOV LEONID GENNADIEVICH, DEMESHKINA MARGARITA PETROVNA, KHASIN ALEXANDR ALEXANDROVICH, MINJUKOVA TATYANA PETROVNA
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creator POSOKHOVA OLGA MIKHAILOVNA
BOCHAROV ALEXANDR PETROVICH
LEBEDEVA MARINA VALERIEVNA
BARONSKAYA NATALYA ALEKSEEVNA
ANDREEVA TATYANA IVANOVNA
JURIEVA TAMARA MIKHAILOVNA
TSELJUTINA MARINA IVANOVNA
PLYASOVA LJUDMILA MIKHAILOVNA
REZNICHENKO IRINA DMITRIEVNA
VOLCHATOV LEONID GENNADIEVICH
DEMESHKINA MARGARITA PETROVNA
KHASIN ALEXANDR ALEXANDROVICH
MINJUKOVA TATYANA PETROVNA
description The invention relates to producing hydrogen by means of the vapour conversion of carbon monoxide and a catalyst for said process and can be used in different industries. The invention discloses an iron-chromium catalyst containing an iron-chromium hydroxyl compound phase having a goethite and/or hydrohematite structure, a method for the preparation thereof and a method for the use thereof in a process for the vapour conversion of carbon monoxide. The catalyst can also contain copper. The catalyst is obtainable by precipitating sodium and potassium, by means on solutions of carbonates or ammonia hydroxides, from solutions of mixture of iron 2+ and 3+ and chromium 3+ nitrates which are obtained by the oxidation-reduction interaction of metal iron, chromium 6+ compounds and nitric acid. A process for the vapour conversion of carbon monoxide using said catalyst according to the inventive method is carried out at a temperature greater than 250° C. Said invention makes it possible to produce a catalyst having low sulphur (equal to or less than 0.03 mass %) and chromium 6+ (equal to or less than 0.05 mass %) contents and exhibiting a high activity at temperatures of 350° C. and less.
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The invention discloses an iron-chromium catalyst containing an iron-chromium hydroxyl compound phase having a goethite and/or hydrohematite structure, a method for the preparation thereof and a method for the use thereof in a process for the vapour conversion of carbon monoxide. The catalyst can also contain copper. The catalyst is obtainable by precipitating sodium and potassium, by means on solutions of carbonates or ammonia hydroxides, from solutions of mixture of iron 2+ and 3+ and chromium 3+ nitrates which are obtained by the oxidation-reduction interaction of metal iron, chromium 6+ compounds and nitric acid. A process for the vapour conversion of carbon monoxide using said catalyst according to the inventive method is carried out at a temperature greater than 250° C. Said invention makes it possible to produce a catalyst having low sulphur (equal to or less than 0.03 mass %) and chromium 6+ (equal to or less than 0.05 mass %) contents and exhibiting a high activity at temperatures of 350° C. and less.</abstract><oa>free_for_read</oa></addata></record>
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subjects CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY
CHEMISTRY
COMPOUNDS THEREOF
INORGANIC CHEMISTRY
METALLURGY
NON-METALLIC ELEMENTS
PERFORMING OPERATIONS
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
THEIR RELEVANT APPARATUS
TRANSPORTING
title CATALYST FOR VAPOUR CONVERSION OF CARBON MONOXIDE METHODS FOR THE PRODUCTION AND FOR THE USE THEREOF
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