EXPANDABLE MICROSPHERES AND METHODS OF MAKING AND USING THE SAME
Expandable microspheres formed by suspension polymerization using a shot growth method are provided. The microspheres are formed of a continuous, gas impermeable shell surrounding a blowing agent. The shell includes a first polymer layer formed from primary monomers and a second layer that includes...
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| creator | SUDOL EDWARD DAVID HONG YAOLIANG FAGAN MARK FROASS PETER M BOYARS BRIAN KLEIN ANDREW MOHAN KOSARAJU KRISHNA DANIELS ERIC SCOTT ANDERSON CHRISTOPHER D DIMONIE VICTORIA LAURENTIA |
| description | Expandable microspheres formed by suspension polymerization using a shot growth method are provided. The microspheres are formed of a continuous, gas impermeable shell surrounding a blowing agent. The shell includes a first polymer layer formed from primary monomers and a second layer that includes a chemically reactive monomer or a high Tg monomer. To form the microspheres, the primary monomers are polymerized in a reaction vessel to an approximate 90% polymerization, at which time a secondary monomer that is either a monomer having a Tg of at least 85° C. or a chemically reactive monomer, is added to the reaction vessel to drive the polymerization reaction to completion. The outer layer thus contains either a larger amount of the high Tg monomer or a chemically reactive monomer that possesses the ability to covalently bond a cationic species. The microspheres may be used in papermaking processes to increase the paper bulk. |
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| subjects | AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F,C08G CHEMISTRY COMPOSITIONS BASED THEREON GENERAL PROCESSES OF COMPOUNDING IMPREGNATING OR COATING OF PAPER METALLURGY ORGANIC MACROMOLECULAR COMPOUNDS PAPER NOT OTHERWISE PROVIDED FOR PAPER-MAKING PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D PRODUCTION OF CELLULOSE PULP COMPOSITIONS TEXTILES THEIR PREPARATION OR CHEMICAL WORKING-UP TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G WORKING-UP |
| title | EXPANDABLE MICROSPHERES AND METHODS OF MAKING AND USING THE SAME |
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