Epoxy functional acrylic coating powders and powder coatings therefrom having improved filiform corrosion resistance
The present invention provides coating powders that enable improved filiform corrosion resistance in clear or tinted clear coating comprising an epoxy functional acrylic copolymer component having a Tg of from 40° C. to 90° C. and chosen from a copolymer or copolymer mixture that comprises, based on...
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creator | MOLITOR-LIMBERG SABINE DALY ANDREW T |
description | The present invention provides coating powders that enable improved filiform corrosion resistance in clear or tinted clear coating comprising an epoxy functional acrylic copolymer component having a Tg of from 40° C. to 90° C. and chosen from a copolymer or copolymer mixture that comprises, based on the total weight of copolymerized monomers in the epoxy functional acrylic copolymer component, i) from 10 to 40 wt. % of one or more epoxy functional unsaturated monomer, e.g. glycidyl (meth)acrylate; ii) from 2.0 wt. % to 13 wt. %, preferably 12 wt. % or less, or, more preferably, 6 wt. % or less, of one or more hydrophobic acrylic monomer that has a mass solubility in water of 3.5 g/L or less and which would itself form a homopolymer having a glass transition temperature (Tg) of 50° C. to 175° C., e.g. a bicycloalkyl(meth)acrylate, and iii) the remainder of one or more nonionic comonomer that is not a hydrophobic acrylic monomer ii), e.g. methyl methacrylate; one or more crosslinker for the thermosetting acrylic copolymer; and, optionally, one or more adhesion promoter, e.g. epoxy resin, a light stabilizer, an ultraviolet (UV) absorber, and/or a hydrophobic submicron particle. |
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ii) from 2.0 wt. % to 13 wt. %, preferably 12 wt. % or less, or, more preferably, 6 wt. % or less, of one or more hydrophobic acrylic monomer that has a mass solubility in water of 3.5 g/L or less and which would itself form a homopolymer having a glass transition temperature (Tg) of 50° C. to 175° C., e.g. a bicycloalkyl(meth)acrylate, and iii) the remainder of one or more nonionic comonomer that is not a hydrophobic acrylic monomer ii), e.g. methyl methacrylate; one or more crosslinker for the thermosetting acrylic copolymer; and, optionally, one or more adhesion promoter, e.g. epoxy resin, a light stabilizer, an ultraviolet (UV) absorber, and/or a hydrophobic submicron particle.</description><language>eng</language><subject>ADHESIVES ; CHEMICAL PAINT OR INK REMOVERS ; CHEMISTRY ; COATING COMPOSITIONS, e.g. PAINTS, VARNISHES ORLACQUERS ; CORRECTING FLUIDS ; DYES ; FILLING PASTES ; INKS ; METALLURGY ; MISCELLANEOUS APPLICATIONS OF MATERIALS ; MISCELLANEOUS COMPOSITIONS ; NATURAL RESINS ; 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ii) from 2.0 wt. % to 13 wt. %, preferably 12 wt. % or less, or, more preferably, 6 wt. % or less, of one or more hydrophobic acrylic monomer that has a mass solubility in water of 3.5 g/L or less and which would itself form a homopolymer having a glass transition temperature (Tg) of 50° C. to 175° C., e.g. a bicycloalkyl(meth)acrylate, and iii) the remainder of one or more nonionic comonomer that is not a hydrophobic acrylic monomer ii), e.g. methyl methacrylate; one or more crosslinker for the thermosetting acrylic copolymer; and, optionally, one or more adhesion promoter, e.g. epoxy resin, a light stabilizer, an ultraviolet (UV) absorber, and/or a hydrophobic submicron particle.</description><subject>ADHESIVES</subject><subject>CHEMICAL PAINT OR INK REMOVERS</subject><subject>CHEMISTRY</subject><subject>COATING COMPOSITIONS, e.g. PAINTS, VARNISHES ORLACQUERS</subject><subject>CORRECTING FLUIDS</subject><subject>DYES</subject><subject>FILLING PASTES</subject><subject>INKS</subject><subject>METALLURGY</subject><subject>MISCELLANEOUS APPLICATIONS OF MATERIALS</subject><subject>MISCELLANEOUS COMPOSITIONS</subject><subject>NATURAL RESINS</subject><subject>PAINTS</subject><subject>PASTES OR SOLIDS FOR COLOURING OR PRINTING</subject><subject>POLISHES</subject><subject>USE OF MATERIALS THEREFOR</subject><subject>WOODSTAINS</subject><fulltext>true</fulltext><rsrctype>patent</rsrctype><creationdate>2009</creationdate><recordtype>patent</recordtype><sourceid>EVB</sourceid><recordid>eNqNzLEKwkAQBNA0FqL-w4K1EGMRLUUi9modlsueObjcHrtnNH9vhNhbzcA8Zp6lKvJ7APsMJjkO6AGNDN4ZMIzJhQdEfjUkChiaqf8mhdSSkBXuoMX-i10XhXtqwDrvLEs3WhHW8RqE1GnCYGiZzSx6pdWUi2x9rm6ny4Yi16QRDQVK9f1a5PmhKMoy3x-3u__UB2YYR0M</recordid><startdate>20090910</startdate><enddate>20090910</enddate><creator>MOLITOR-LIMBERG SABINE</creator><creator>DALY ANDREW T</creator><scope>EVB</scope></search><sort><creationdate>20090910</creationdate><title>Epoxy functional acrylic coating powders and powder coatings therefrom having improved filiform corrosion resistance</title><author>MOLITOR-LIMBERG SABINE ; DALY ANDREW T</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-epo_espacenet_US2009227708A13</frbrgroupid><rsrctype>patents</rsrctype><prefilter>patents</prefilter><language>eng</language><creationdate>2009</creationdate><topic>ADHESIVES</topic><topic>CHEMICAL PAINT OR INK REMOVERS</topic><topic>CHEMISTRY</topic><topic>COATING COMPOSITIONS, e.g. PAINTS, VARNISHES ORLACQUERS</topic><topic>CORRECTING FLUIDS</topic><topic>DYES</topic><topic>FILLING PASTES</topic><topic>INKS</topic><topic>METALLURGY</topic><topic>MISCELLANEOUS APPLICATIONS OF MATERIALS</topic><topic>MISCELLANEOUS COMPOSITIONS</topic><topic>NATURAL RESINS</topic><topic>PAINTS</topic><topic>PASTES OR SOLIDS FOR COLOURING OR PRINTING</topic><topic>POLISHES</topic><topic>USE OF MATERIALS THEREFOR</topic><topic>WOODSTAINS</topic><toplevel>online_resources</toplevel><creatorcontrib>MOLITOR-LIMBERG SABINE</creatorcontrib><creatorcontrib>DALY ANDREW T</creatorcontrib><collection>esp@cenet</collection></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext_linktorsrc</fulltext></delivery><addata><au>MOLITOR-LIMBERG SABINE</au><au>DALY ANDREW T</au><format>patent</format><genre>patent</genre><ristype>GEN</ristype><title>Epoxy functional acrylic coating powders and powder coatings therefrom having improved filiform corrosion resistance</title><date>2009-09-10</date><risdate>2009</risdate><abstract>The present invention provides coating powders that enable improved filiform corrosion resistance in clear or tinted clear coating comprising an epoxy functional acrylic copolymer component having a Tg of from 40° C. to 90° C. and chosen from a copolymer or copolymer mixture that comprises, based on the total weight of copolymerized monomers in the epoxy functional acrylic copolymer component, i) from 10 to 40 wt. % of one or more epoxy functional unsaturated monomer, e.g. glycidyl (meth)acrylate; 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subjects | ADHESIVES CHEMICAL PAINT OR INK REMOVERS CHEMISTRY COATING COMPOSITIONS, e.g. PAINTS, VARNISHES ORLACQUERS CORRECTING FLUIDS DYES FILLING PASTES INKS METALLURGY MISCELLANEOUS APPLICATIONS OF MATERIALS MISCELLANEOUS COMPOSITIONS NATURAL RESINS PAINTS PASTES OR SOLIDS FOR COLOURING OR PRINTING POLISHES USE OF MATERIALS THEREFOR WOODSTAINS |
title | Epoxy functional acrylic coating powders and powder coatings therefrom having improved filiform corrosion resistance |
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