Process for the preparation of polycarbonates

An improvement to the phase interface process of preparing aromatic polycarbonate is disclosed. The process is characterized in that the phosgenation is carried out at 0 to 40° C., and in that the temperature of the reaction mixture at the time of addition of the catalyst at 10 to 40° C., and in tha...

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Hauptverfasser: EINBERGER HELMUT, HAESE WILFRIED, EH CHRISTIAN, RUYTINX BERT, MEYER ALEXANDER, FRANKENAU ANDREAS, DE VOS STEFAAN, FRANZ ULI, KAUTH HERMANN, EBERT WOLFGANG
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creator EINBERGER HELMUT
HAESE WILFRIED
EH CHRISTIAN
RUYTINX BERT
MEYER ALEXANDER
FRANKENAU ANDREAS
DE VOS STEFAAN
FRANZ ULI
KAUTH HERMANN
EBERT WOLFGANG
description An improvement to the phase interface process of preparing aromatic polycarbonate is disclosed. The process is characterized in that the phosgenation is carried out at 0 to 40° C., and in that the temperature of the reaction mixture at the time of addition of the catalyst at 10 to 40° C., and in that the molar ratio of aromatic dihydroxy compounds to phosgene at 1:1.05 to 1:1.20. The polycarbonate thus produced is characterized in its low content of carbamates, making it particularly suitable for the preparation of optical storage media.
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subjects CHEMISTRY
COMPOSITIONS BASED THEREON
MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONSONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
METALLURGY
ORGANIC MACROMOLECULAR COMPOUNDS
THEIR PREPARATION OR CHEMICAL WORKING-UP
title Process for the preparation of polycarbonates
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