Process for preparing methylenedianiline and methylenebis (phenylisocyanate)

A process for preparing methylenedianiline by reacting aniline with formaldehyde in the presence of acid catalysts comprising, in a semicontinuous process, introducing aniline with or without acid catalyst, feeding formaldehyde with or without acid catalyst through a mixing element into a circuit in...

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Hauptverfasser: SEYFERT WILFRIED, JACOBS JAN, SCHWEERS OLAF, STROFER ECKHARD, PENZEL ULRICH, SCHWARZ HANS VOLKMAR, SCHARR VOLKER
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creator SEYFERT WILFRIED
JACOBS JAN
SCHWEERS OLAF
STROFER ECKHARD
PENZEL ULRICH
SCHWARZ HANS VOLKMAR
SCHARR VOLKER
description A process for preparing methylenedianiline by reacting aniline with formaldehyde in the presence of acid catalysts comprising, in a semicontinuous process, introducing aniline with or without acid catalyst, feeding formaldehyde with or without acid catalyst through a mixing element into a circuit in which aniline with or without acid catalyst and with or without previously added formaldehyde is circulated and, after feeding in at least 50% of the total amount of formaldehyde to be fed in, heating the reaction mixture to a temperature above 75° C. In addition, the invention relates to a process for preparing polyisocyanates by phosgenation of amines obtainable in this manner and to the polyisocyanates obtainable by this process.
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subjects ACYCLIC OR CARBOCYCLIC COMPOUNDS
APPARATUS THEREFOR
CHEMISTRY
GENERAL METHODS OF ORGANIC CHEMISTRY
METALLURGY
ORGANIC CHEMISTRY
title Process for preparing methylenedianiline and methylenebis (phenylisocyanate)
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