Catalyst systems for ethylene oligomerisation to linear alpha olefins

A catalyst system comprising: (a) one or more bisarylimino pyridine iron or cobalt catalysts; (b) a first co-catalyst compound which is selected from aluminium alkyls, aluminoxanes, and mixtures thereof; and (c) a second co-catalyst compound which comprises one or more compounds of the formula ZnR&#...

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Hauptverfasser: DE BOER ERIC JOHANNES MARIA, DE BOER-WILDSCHUT MARIJKE, ZON ARIE VAH, HEIJDEN HARRY VAN DER
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creator DE BOER ERIC JOHANNES MARIA
DE BOER-WILDSCHUT MARIJKE
ZON ARIE VAH
HEIJDEN HARRY VAN DER
description A catalyst system comprising: (a) one or more bisarylimino pyridine iron or cobalt catalysts; (b) a first co-catalyst compound which is selected from aluminium alkyls, aluminoxanes, and mixtures thereof; and (c) a second co-catalyst compound which comprises one or more compounds of the formula ZnR'2 wherein each R', which may be the same or different, is selected from hydrogen, optionally substituted C1-C20 hydrocarbyl, phenyl, Cl, Br, I, SR'', NR''2, OH, OR'', CN, NC wherein R'', which within the same molecule may the same or different, is C1-C20 hydrocarbyl.
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subjects ACYCLIC OR CARBOCYCLIC COMPOUNDS
ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY
CHEMISTRY
HETEROCYCLIC COMPOUNDS
METALLURGY
ORGANIC CHEMISTRY
PERFORMING OPERATIONS
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
THEIR RELEVANT APPARATUS
TRANSPORTING
title Catalyst systems for ethylene oligomerisation to linear alpha olefins
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