Method for shortstopping polymerization processes in the manufacture of synthetic rubbers

This invention is related to a new shortstopping combination for use in stopping free radical and redox intiated polymerization is the combination of hydroxylamine (free base) (HA) and i-propylhydroxylamine (IPAH). It is more effective as related N-alcylated-hydroxylamines with regard to mooney stab...

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Hauptverfasser: KREBES WOLFGANG, GUTH ILONA, HOEHNE KLAUS, EDEL HANS A. R, MATHIES FRIEDHELM, MARX DORIS R, STILLER HARTMUT K, BOGEN HEINZ-JUERGEN
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creator KREBES WOLFGANG
GUTH ILONA
HOEHNE KLAUS
EDEL HANS A. R
MATHIES FRIEDHELM
MARX DORIS R
STILLER HARTMUT K
BOGEN HEINZ-JUERGEN
description This invention is related to a new shortstopping combination for use in stopping free radical and redox intiated polymerization is the combination of hydroxylamine (free base) (HA) and i-propylhydroxylamine (IPAH). It is more effective as related N-alcylated-hydroxylamines with regard to mooney stability. The combination is not corrosive to metals used in commercial equipment fr emulsion polymerization and prevents the rust formation and the formation of nitrosamins, coagulate and precipitate.
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subjects CHEMISTRY
COMPOSITIONS BASED THEREON
MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS
METALLURGY
ORGANIC MACROMOLECULAR COMPOUNDS
THEIR PREPARATION OR CHEMICAL WORKING-UP
title Method for shortstopping polymerization processes in the manufacture of synthetic rubbers
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