Oxidation treatment of a recycle stream in production of acetic acid by methanol carbonylation

A method and system is provided for producing acetic acid by the catalytic carbonylation of methanol with carbon monoxide to obtain a reaction product stream comprising acetic acid and a minor amount of acetaldehyde. The acetaldehyde content in the reaction product stream is reduced by oxidation to...

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Hauptverfasser: CHEUNG HUNGUN, TORRENCE G.PAULL, KARNILAW MICHAEL L, BROUSSARD JERRY A, HUCKMAN MICHAEL E, MCKARNS MACATANGAY PEGGY, HOULISTON STEPHEN ANDREW, SINGH MADAN
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creator CHEUNG HUNGUN
TORRENCE G.PAULL
KARNILAW MICHAEL L
BROUSSARD JERRY A
HUCKMAN MICHAEL E
MCKARNS MACATANGAY PEGGY
HOULISTON STEPHEN ANDREW
SINGH MADAN
description A method and system is provided for producing acetic acid by the catalytic carbonylation of methanol with carbon monoxide to obtain a reaction product stream comprising acetic acid and a minor amount of acetaldehyde. The acetaldehyde content in the reaction product stream is reduced by oxidation to convert at least a portion of the acetaldehyde in the stream to acetic acid or further to CO2 and H2O. The oxidized stream may then be directed to the purification section, the reaction section, or both whereby the deleterious effects of acetaldehyde are reduced. Advantage of the present invention over conventional processes is the reduced need to dispose of acetaldehyde as waste and improved overall system efficiency in the production of acetic acid.
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subjects ACYCLIC OR CARBOCYCLIC COMPOUNDS
APPARATUS THEREFOR
CHEMISTRY
COMPOSITIONS BASED THEREON
GENERAL METHODS OF ORGANIC CHEMISTRY
MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS
METALLURGY
ORGANIC CHEMISTRY
ORGANIC MACROMOLECULAR COMPOUNDS
THEIR PREPARATION OR CHEMICAL WORKING-UP
title Oxidation treatment of a recycle stream in production of acetic acid by methanol carbonylation
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