CATALYST FOR POLYESTER PRODUCTION, PROCESS FOR PRODUCING POLYESTER USING THE CATALYST, POLYESTER OBTAINED BY THE PROCESS, AND USES OF THE POLYESTER

The present invention provides a catalyst or polyester production capable of producing a polyester with high catalytic activity and a process For producing a polyester using the catalyst. The catalyst for polyester production comprises a solid titanium compound which is obtained by dehydro-drying a...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Hauptverfasser: IMUTA JUNICHI, NAKAMACHI KOJI, SAKAI SAYUKI, TOYOTA KAZUO, TSUGAWA MICHIO, FUKUTANI KENZABUROU, NODA SEIJI, ONOGI TAKAYUKI, SHIMIZU AKIVOSHI, OHMATSUZAWA TAKESHI, HIRAOKA SHOJI, MIYAZOE SATORU, HORI HIDESHI, EHARA FUJITO
Format: Patent
Sprache:eng
Schlagworte:
Online-Zugang:Volltext bestellen
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page
container_issue
container_start_page
container_title
container_volume
creator IMUTA JUNICHI
NAKAMACHI KOJI
SAKAI SAYUKI
TOYOTA KAZUO
TSUGAWA MICHIO
FUKUTANI KENZABUROU
NODA SEIJI
ONOGI TAKAYUKI
SHIMIZU AKIVOSHI
OHMATSUZAWA TAKESHI
HIRAOKA SHOJI
MIYAZOE SATORU
HORI HIDESHI
EHARA FUJITO
description The present invention provides a catalyst or polyester production capable of producing a polyester with high catalytic activity and a process For producing a polyester using the catalyst. The catalyst for polyester production comprises a solid titanium compound which is obtained by dehydro-drying a hydrolyzate obtained by hydrolysis of a titanium halide and which has a molar ratio (OH/Ti) of a hydroxyl group (OH) to titanium (Ti) exceeding 0.09 and less than 4. The present invention also provides a method to obtain a polyester having a small increase of the acetaldehyde content during the molding. This method comprises bringing a polyester, which is obtained by the use of a titanium compound catalyst and in which the reaction has been completed, into contact with a phosphoric ester aqueous solution or the like having a concentration of not less than 10 ppm in terms of phosphorus atom. The present invention further provides a polyester having excellent transparency and tint and molded products of the polyester such as a blow molded article, arm, a sheet and a fiber. The polyester is obtained by polycondensing an aromatic dicarboxylic acid or an ester-forming derivative thereof and an aliphatic diol or an ester-forming derivative thereof in the presence of a catalyst for polyester production which comprises a polycondensation catalyst component comprising a solid titanium compound and a co-catalyst component comprising a magnesium compound. This polyester has a titanium content of 1 to 100 ppm, a magnesium content of 1 to 200 ppm and a weight ratio (Mg/Ti) of magnesium to titanium of not less than 0.01.
format Patent
fullrecord <record><control><sourceid>epo_EVB</sourceid><recordid>TN_cdi_epo_espacenet_US2002137879A1</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>US2002137879A1</sourcerecordid><originalsourceid>FETCH-epo_espacenet_US2002137879A13</originalsourceid><addsrcrecordid>eNrjZJjs7Bji6BMZHKLg5h-kEODvE-kaHOIKZAX5u4Q6h3j6--mA2M6uwcEQFWBxTz93JLWhwSB-iIerAswwHSRZf6cQR08_VxcFp0iwGqhpOgqOfi5Ara7BCv5uEAmYFh4G1rTEnOJUXijNzaDs5hri7KGbWpAfn1pckJicmpdaEh8abGRgYGRobG5hbuloaEycKgCHNELW</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>patent</recordtype></control><display><type>patent</type><title>CATALYST FOR POLYESTER PRODUCTION, PROCESS FOR PRODUCING POLYESTER USING THE CATALYST, POLYESTER OBTAINED BY THE PROCESS, AND USES OF THE POLYESTER</title><source>esp@cenet</source><creator>IMUTA JUNICHI ; NAKAMACHI KOJI ; SAKAI SAYUKI ; TOYOTA KAZUO ; TSUGAWA MICHIO ; FUKUTANI KENZABUROU ; NODA SEIJI ; ONOGI TAKAYUKI ; SHIMIZU AKIVOSHI ; OHMATSUZAWA TAKESHI ; HIRAOKA SHOJI ; MIYAZOE SATORU ; HORI HIDESHI ; EHARA FUJITO</creator><creatorcontrib>IMUTA JUNICHI ; NAKAMACHI KOJI ; SAKAI SAYUKI ; TOYOTA KAZUO ; TSUGAWA MICHIO ; FUKUTANI KENZABUROU ; NODA SEIJI ; ONOGI TAKAYUKI ; SHIMIZU AKIVOSHI ; OHMATSUZAWA TAKESHI ; HIRAOKA SHOJI ; MIYAZOE SATORU ; HORI HIDESHI ; EHARA FUJITO</creatorcontrib><description>The present invention provides a catalyst or polyester production capable of producing a polyester with high catalytic activity and a process For producing a polyester using the catalyst. The catalyst for polyester production comprises a solid titanium compound which is obtained by dehydro-drying a hydrolyzate obtained by hydrolysis of a titanium halide and which has a molar ratio (OH/Ti) of a hydroxyl group (OH) to titanium (Ti) exceeding 0.09 and less than 4. The present invention also provides a method to obtain a polyester having a small increase of the acetaldehyde content during the molding. This method comprises bringing a polyester, which is obtained by the use of a titanium compound catalyst and in which the reaction has been completed, into contact with a phosphoric ester aqueous solution or the like having a concentration of not less than 10 ppm in terms of phosphorus atom. The present invention further provides a polyester having excellent transparency and tint and molded products of the polyester such as a blow molded article, arm, a sheet and a fiber. The polyester is obtained by polycondensing an aromatic dicarboxylic acid or an ester-forming derivative thereof and an aliphatic diol or an ester-forming derivative thereof in the presence of a catalyst for polyester production which comprises a polycondensation catalyst component comprising a solid titanium compound and a co-catalyst component comprising a magnesium compound. This polyester has a titanium content of 1 to 100 ppm, a magnesium content of 1 to 200 ppm and a weight ratio (Mg/Ti) of magnesium to titanium of not less than 0.01.</description><edition>7</edition><language>eng</language><subject>CHEMISTRY ; COMPOSITIONS BASED THEREON ; MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONSONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS ; METALLURGY ; ORGANIC MACROMOLECULAR COMPOUNDS ; THEIR PREPARATION OR CHEMICAL WORKING-UP</subject><creationdate>2002</creationdate><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&amp;date=20020926&amp;DB=EPODOC&amp;CC=US&amp;NR=2002137879A1$$EHTML$$P50$$Gepo$$Hfree_for_read</linktohtml><link.rule.ids>230,308,777,882,25545,76296</link.rule.ids><linktorsrc>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&amp;date=20020926&amp;DB=EPODOC&amp;CC=US&amp;NR=2002137879A1$$EView_record_in_European_Patent_Office$$FView_record_in_$$GEuropean_Patent_Office$$Hfree_for_read</linktorsrc></links><search><creatorcontrib>IMUTA JUNICHI</creatorcontrib><creatorcontrib>NAKAMACHI KOJI</creatorcontrib><creatorcontrib>SAKAI SAYUKI</creatorcontrib><creatorcontrib>TOYOTA KAZUO</creatorcontrib><creatorcontrib>TSUGAWA MICHIO</creatorcontrib><creatorcontrib>FUKUTANI KENZABUROU</creatorcontrib><creatorcontrib>NODA SEIJI</creatorcontrib><creatorcontrib>ONOGI TAKAYUKI</creatorcontrib><creatorcontrib>SHIMIZU AKIVOSHI</creatorcontrib><creatorcontrib>OHMATSUZAWA TAKESHI</creatorcontrib><creatorcontrib>HIRAOKA SHOJI</creatorcontrib><creatorcontrib>MIYAZOE SATORU</creatorcontrib><creatorcontrib>HORI HIDESHI</creatorcontrib><creatorcontrib>EHARA FUJITO</creatorcontrib><title>CATALYST FOR POLYESTER PRODUCTION, PROCESS FOR PRODUCING POLYESTER USING THE CATALYST, POLYESTER OBTAINED BY THE PROCESS, AND USES OF THE POLYESTER</title><description>The present invention provides a catalyst or polyester production capable of producing a polyester with high catalytic activity and a process For producing a polyester using the catalyst. The catalyst for polyester production comprises a solid titanium compound which is obtained by dehydro-drying a hydrolyzate obtained by hydrolysis of a titanium halide and which has a molar ratio (OH/Ti) of a hydroxyl group (OH) to titanium (Ti) exceeding 0.09 and less than 4. The present invention also provides a method to obtain a polyester having a small increase of the acetaldehyde content during the molding. This method comprises bringing a polyester, which is obtained by the use of a titanium compound catalyst and in which the reaction has been completed, into contact with a phosphoric ester aqueous solution or the like having a concentration of not less than 10 ppm in terms of phosphorus atom. The present invention further provides a polyester having excellent transparency and tint and molded products of the polyester such as a blow molded article, arm, a sheet and a fiber. The polyester is obtained by polycondensing an aromatic dicarboxylic acid or an ester-forming derivative thereof and an aliphatic diol or an ester-forming derivative thereof in the presence of a catalyst for polyester production which comprises a polycondensation catalyst component comprising a solid titanium compound and a co-catalyst component comprising a magnesium compound. This polyester has a titanium content of 1 to 100 ppm, a magnesium content of 1 to 200 ppm and a weight ratio (Mg/Ti) of magnesium to titanium of not less than 0.01.</description><subject>CHEMISTRY</subject><subject>COMPOSITIONS BASED THEREON</subject><subject>MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONSONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS</subject><subject>METALLURGY</subject><subject>ORGANIC MACROMOLECULAR COMPOUNDS</subject><subject>THEIR PREPARATION OR CHEMICAL WORKING-UP</subject><fulltext>true</fulltext><rsrctype>patent</rsrctype><creationdate>2002</creationdate><recordtype>patent</recordtype><sourceid>EVB</sourceid><recordid>eNrjZJjs7Bji6BMZHKLg5h-kEODvE-kaHOIKZAX5u4Q6h3j6--mA2M6uwcEQFWBxTz93JLWhwSB-iIerAswwHSRZf6cQR08_VxcFp0iwGqhpOgqOfi5Ara7BCv5uEAmYFh4G1rTEnOJUXijNzaDs5hri7KGbWpAfn1pckJicmpdaEh8abGRgYGRobG5hbuloaEycKgCHNELW</recordid><startdate>20020926</startdate><enddate>20020926</enddate><creator>IMUTA JUNICHI</creator><creator>NAKAMACHI KOJI</creator><creator>SAKAI SAYUKI</creator><creator>TOYOTA KAZUO</creator><creator>TSUGAWA MICHIO</creator><creator>FUKUTANI KENZABUROU</creator><creator>NODA SEIJI</creator><creator>ONOGI TAKAYUKI</creator><creator>SHIMIZU AKIVOSHI</creator><creator>OHMATSUZAWA TAKESHI</creator><creator>HIRAOKA SHOJI</creator><creator>MIYAZOE SATORU</creator><creator>HORI HIDESHI</creator><creator>EHARA FUJITO</creator><scope>EVB</scope></search><sort><creationdate>20020926</creationdate><title>CATALYST FOR POLYESTER PRODUCTION, PROCESS FOR PRODUCING POLYESTER USING THE CATALYST, POLYESTER OBTAINED BY THE PROCESS, AND USES OF THE POLYESTER</title><author>IMUTA JUNICHI ; NAKAMACHI KOJI ; SAKAI SAYUKI ; TOYOTA KAZUO ; TSUGAWA MICHIO ; FUKUTANI KENZABUROU ; NODA SEIJI ; ONOGI TAKAYUKI ; SHIMIZU AKIVOSHI ; OHMATSUZAWA TAKESHI ; HIRAOKA SHOJI ; MIYAZOE SATORU ; HORI HIDESHI ; EHARA FUJITO</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-epo_espacenet_US2002137879A13</frbrgroupid><rsrctype>patents</rsrctype><prefilter>patents</prefilter><language>eng</language><creationdate>2002</creationdate><topic>CHEMISTRY</topic><topic>COMPOSITIONS BASED THEREON</topic><topic>MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONSONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS</topic><topic>METALLURGY</topic><topic>ORGANIC MACROMOLECULAR COMPOUNDS</topic><topic>THEIR PREPARATION OR CHEMICAL WORKING-UP</topic><toplevel>online_resources</toplevel><creatorcontrib>IMUTA JUNICHI</creatorcontrib><creatorcontrib>NAKAMACHI KOJI</creatorcontrib><creatorcontrib>SAKAI SAYUKI</creatorcontrib><creatorcontrib>TOYOTA KAZUO</creatorcontrib><creatorcontrib>TSUGAWA MICHIO</creatorcontrib><creatorcontrib>FUKUTANI KENZABUROU</creatorcontrib><creatorcontrib>NODA SEIJI</creatorcontrib><creatorcontrib>ONOGI TAKAYUKI</creatorcontrib><creatorcontrib>SHIMIZU AKIVOSHI</creatorcontrib><creatorcontrib>OHMATSUZAWA TAKESHI</creatorcontrib><creatorcontrib>HIRAOKA SHOJI</creatorcontrib><creatorcontrib>MIYAZOE SATORU</creatorcontrib><creatorcontrib>HORI HIDESHI</creatorcontrib><creatorcontrib>EHARA FUJITO</creatorcontrib><collection>esp@cenet</collection></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext_linktorsrc</fulltext></delivery><addata><au>IMUTA JUNICHI</au><au>NAKAMACHI KOJI</au><au>SAKAI SAYUKI</au><au>TOYOTA KAZUO</au><au>TSUGAWA MICHIO</au><au>FUKUTANI KENZABUROU</au><au>NODA SEIJI</au><au>ONOGI TAKAYUKI</au><au>SHIMIZU AKIVOSHI</au><au>OHMATSUZAWA TAKESHI</au><au>HIRAOKA SHOJI</au><au>MIYAZOE SATORU</au><au>HORI HIDESHI</au><au>EHARA FUJITO</au><format>patent</format><genre>patent</genre><ristype>GEN</ristype><title>CATALYST FOR POLYESTER PRODUCTION, PROCESS FOR PRODUCING POLYESTER USING THE CATALYST, POLYESTER OBTAINED BY THE PROCESS, AND USES OF THE POLYESTER</title><date>2002-09-26</date><risdate>2002</risdate><abstract>The present invention provides a catalyst or polyester production capable of producing a polyester with high catalytic activity and a process For producing a polyester using the catalyst. The catalyst for polyester production comprises a solid titanium compound which is obtained by dehydro-drying a hydrolyzate obtained by hydrolysis of a titanium halide and which has a molar ratio (OH/Ti) of a hydroxyl group (OH) to titanium (Ti) exceeding 0.09 and less than 4. The present invention also provides a method to obtain a polyester having a small increase of the acetaldehyde content during the molding. This method comprises bringing a polyester, which is obtained by the use of a titanium compound catalyst and in which the reaction has been completed, into contact with a phosphoric ester aqueous solution or the like having a concentration of not less than 10 ppm in terms of phosphorus atom. The present invention further provides a polyester having excellent transparency and tint and molded products of the polyester such as a blow molded article, arm, a sheet and a fiber. The polyester is obtained by polycondensing an aromatic dicarboxylic acid or an ester-forming derivative thereof and an aliphatic diol or an ester-forming derivative thereof in the presence of a catalyst for polyester production which comprises a polycondensation catalyst component comprising a solid titanium compound and a co-catalyst component comprising a magnesium compound. This polyester has a titanium content of 1 to 100 ppm, a magnesium content of 1 to 200 ppm and a weight ratio (Mg/Ti) of magnesium to titanium of not less than 0.01.</abstract><edition>7</edition><oa>free_for_read</oa></addata></record>
fulltext fulltext_linktorsrc
identifier
ispartof
issn
language eng
recordid cdi_epo_espacenet_US2002137879A1
source esp@cenet
subjects CHEMISTRY
COMPOSITIONS BASED THEREON
MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONSONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
METALLURGY
ORGANIC MACROMOLECULAR COMPOUNDS
THEIR PREPARATION OR CHEMICAL WORKING-UP
title CATALYST FOR POLYESTER PRODUCTION, PROCESS FOR PRODUCING POLYESTER USING THE CATALYST, POLYESTER OBTAINED BY THE PROCESS, AND USES OF THE POLYESTER
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-19T07%3A24%3A34IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-epo_EVB&rft_val_fmt=info:ofi/fmt:kev:mtx:patent&rft.genre=patent&rft.au=IMUTA%20JUNICHI&rft.date=2002-09-26&rft_id=info:doi/&rft_dat=%3Cepo_EVB%3EUS2002137879A1%3C/epo_EVB%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true