Composition, method and use

A quaternary ammonium compound of formula (I) wherein X is a linking group; Y is O, NH or NR1 wherein R1 is H or optionally substituted hydrocarbyl group; Q+ is a moiety that includes a quaternary ammonium cation; A- is an anion; R2 is an optionally substituted alkylene group; R3 is hydrogen or opti...

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Hauptverfasser: Roberts, Martin, Ross, Alan Norman
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Ross, Alan Norman
description A quaternary ammonium compound of formula (I) wherein X is a linking group; Y is O, NH or NR1 wherein R1 is H or optionally substituted hydrocarbyl group; Q+ is a moiety that includes a quaternary ammonium cation; A- is an anion; R2 is an optionally substituted alkylene group; R3 is hydrogen or optionally substituted hydrocarbyl group; and n is 0 or a positive integer, provided than n is not 0 when R3 is hydrogen. A composition comprising the quaternary ammonium compound of formula (I) is also claimed. The use of the quaternary ammonium compound of formula (I) as an additive in fuel, preferably gasoline, or in lubricating compositions; and a method of improving engine performance, comprising combusting a fuel composition comprising a quaternary ammonium compound of formula (I) are also disclosed. Preferably the quaternary ammonium salt is prepared by reacting a hydrocarbyl-substituted dicarboxylic acid or anhydride, most preferably succinic acid or anhydride, with an alcohol of formula R3(OR2)nOH; a reactive alcohol or amine including a tertiary amine, and a quaternising agent. Preferably, X is an optionally substituted alkylene group, most preferably ethylene. The compounds of the invention are useful in reducing and preventing build-up of injector deposits.
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A composition comprising the quaternary ammonium compound of formula (I) is also claimed. The use of the quaternary ammonium compound of formula (I) as an additive in fuel, preferably gasoline, or in lubricating compositions; and a method of improving engine performance, comprising combusting a fuel composition comprising a quaternary ammonium compound of formula (I) are also disclosed. Preferably the quaternary ammonium salt is prepared by reacting a hydrocarbyl-substituted dicarboxylic acid or anhydride, most preferably succinic acid or anhydride, with an alcohol of formula R3(OR2)nOH; a reactive alcohol or amine including a tertiary amine, and a quaternising agent. Preferably, X is an optionally substituted alkylene group, most preferably ethylene. The compounds of the invention are useful in reducing and preventing build-up of injector deposits.</description><language>eng</language><subject>ACYCLIC OR CARBOCYCLIC COMPOUNDS ; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE ORUNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL ; CHEMISTRY ; FIRELIGHTERS ; FUELS ; FUELS NOT OTHERWISE PROVIDED FOR ; LIQUEFIED PETROLEUM GAS ; LUBRICANTS ; LUBRICATING COMPOSITIONS ; METALLURGY ; NATURAL GAS ; ORGANIC CHEMISTRY ; PEAT ; PETROLEUM, GAS OR COKE INDUSTRIES ; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BYSUBCLASSES C10G, C10K ; TECHNICAL GASES CONTAINING CARBON MONOXIDE ; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATINGINGREDIENTS IN A LUBRICATING COMPOSITION</subject><creationdate>2021</creationdate><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&amp;date=20210525&amp;DB=EPODOC&amp;CC=US&amp;NR=11015137B2$$EHTML$$P50$$Gepo$$Hfree_for_read</linktohtml><link.rule.ids>230,308,777,882,25545,76296</link.rule.ids><linktorsrc>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&amp;date=20210525&amp;DB=EPODOC&amp;CC=US&amp;NR=11015137B2$$EView_record_in_European_Patent_Office$$FView_record_in_$$GEuropean_Patent_Office$$Hfree_for_read</linktorsrc></links><search><creatorcontrib>Roberts, Martin</creatorcontrib><creatorcontrib>Ross, Alan Norman</creatorcontrib><title>Composition, method and use</title><description>A quaternary ammonium compound of formula (I) wherein X is a linking group; Y is O, NH or NR1 wherein R1 is H or optionally substituted hydrocarbyl group; Q+ is a moiety that includes a quaternary ammonium cation; A- is an anion; R2 is an optionally substituted alkylene group; R3 is hydrogen or optionally substituted hydrocarbyl group; and n is 0 or a positive integer, provided than n is not 0 when R3 is hydrogen. A composition comprising the quaternary ammonium compound of formula (I) is also claimed. The use of the quaternary ammonium compound of formula (I) as an additive in fuel, preferably gasoline, or in lubricating compositions; and a method of improving engine performance, comprising combusting a fuel composition comprising a quaternary ammonium compound of formula (I) are also disclosed. Preferably the quaternary ammonium salt is prepared by reacting a hydrocarbyl-substituted dicarboxylic acid or anhydride, most preferably succinic acid or anhydride, with an alcohol of formula R3(OR2)nOH; a reactive alcohol or amine including a tertiary amine, and a quaternising agent. Preferably, X is an optionally substituted alkylene group, most preferably ethylene. 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A composition comprising the quaternary ammonium compound of formula (I) is also claimed. The use of the quaternary ammonium compound of formula (I) as an additive in fuel, preferably gasoline, or in lubricating compositions; and a method of improving engine performance, comprising combusting a fuel composition comprising a quaternary ammonium compound of formula (I) are also disclosed. Preferably the quaternary ammonium salt is prepared by reacting a hydrocarbyl-substituted dicarboxylic acid or anhydride, most preferably succinic acid or anhydride, with an alcohol of formula R3(OR2)nOH; a reactive alcohol or amine including a tertiary amine, and a quaternising agent. Preferably, X is an optionally substituted alkylene group, most preferably ethylene. The compounds of the invention are useful in reducing and preventing build-up of injector deposits.</abstract><oa>free_for_read</oa></addata></record>
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subjects ACYCLIC OR CARBOCYCLIC COMPOUNDS
ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE ORUNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL
CHEMISTRY
FIRELIGHTERS
FUELS
FUELS NOT OTHERWISE PROVIDED FOR
LIQUEFIED PETROLEUM GAS
LUBRICANTS
LUBRICATING COMPOSITIONS
METALLURGY
NATURAL GAS
ORGANIC CHEMISTRY
PEAT
PETROLEUM, GAS OR COKE INDUSTRIES
SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BYSUBCLASSES C10G, C10K
TECHNICAL GASES CONTAINING CARBON MONOXIDE
USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATINGINGREDIENTS IN A LUBRICATING COMPOSITION
title Composition, method and use
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